Crystallography Open Database

Information card for entry 4122083

4122082 << 4122083 >> 4122084

Preview

Coordinates	4122083.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C48 H42 Cl Cr O2 P2 Rh
Calculated formula	C48 H42 Cl Cr O2 P2 Rh
Title of publication	Phosphine-Olefin Ligands Based on a Planar-Chiral (π-Arene)chromium Scaffold: Design, Synthesis, and Application in Asymmetric Catalysis.
Authors of publication	Ogasawara, Masamichi; Tseng, Ya-Yi; Arae, Sachie; Morita, Tomotaka; Nakaya, Takeshi; Wu, Wei-Yi; Takahashi, Tamotsu; Kamikawa, Ken
Journal of publication	Journal of the American Chemical Society
Year of publication	2014
Journal volume	136
Journal issue	26
Pages of publication	9377 - 9384
a	33.628 ± 0.013 Å
b	15.646 ± 0.006 Å
c	17.339 ± 0.005 Å
α	90°
β	113.81 ± 0.013°
γ	90°
Cell volume	8346 ± 5 Å³
Cell temperature	296 ± 2 K
Ambient diffraction temperature	296 ± 2 K
Number of distinct elements	7
Space group number	15
Hermann-Mauguin space group symbol	C 1 2/c 1
Hall space group symbol	-C 2yc
Residual factor for all reflections	0.1332
Residual factor for significantly intense reflections	0.0572
Weighted residual factors for significantly intense reflections	0.1407
Weighted residual factors for all reflections included in the refinement	0.1813
Goodness-of-fit parameter for all reflections included in the refinement	0.969
Diffraction radiation wavelength	0.71075 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
179022 (current)	2016-03-22	cif/4/12/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/12/20.	4122083.cif
119116	2014-07-05	cif/ Updating files of 4122083 Original log message: Adding full bibliography for 4122083.cif.	4122083.cif
118009	2014-06-25	cif/ Adding structures of 4122083 via cif-deposit CGI script.	4122083.cif