Crystallography Open Database

Information card for entry 4122093

4122092 << 4122093 >> 4122094

Preview

Coordinates	4122093.cif
Original paper (by DOI)	HTML

Structure parameters

Common name	RhPh2(cod) Li(dme)3
Chemical name	tris(1,2-dimethoxyethane)lithium (h4-1,5-cyclooctadiene)diphenylrhodate(I)
Formula	C32 H52 Li O6 Rh
Calculated formula	C32 H44 Li O6 Rh
Title of publication	Diarylrhodates as promising active catalysts for the arylation of vinyl ethers with grignard reagents.
Authors of publication	Iwasaki, Takanori; Miyata, Yoshinori; Akimoto, Ryo; Fujii, Yuuki; Kuniyasu, Hitoshi; Kambe, Nobuaki
Journal of publication	Journal of the American Chemical Society
Year of publication	2014
Journal volume	136
Journal issue	26
Pages of publication	9260 - 9263
a	15.564 ± 0.004 Å
b	16.3801 ± 0.0016 Å
c	13.74 ± 0.008 Å
α	90°
β	109.64 ± 0.04°
γ	90°
Cell volume	3299 ± 2 Å³
Cell temperature	123 K
Ambient diffraction temperature	123 K
Number of distinct elements	5
Space group number	15
Hermann-Mauguin space group symbol	C 1 2/c 1
Hall space group symbol	-C 2yc
Residual factor for significantly intense reflections	0.0603
Weighted residual factors for all reflections included in the refinement	0.1416
Goodness-of-fit parameter for all reflections included in the refinement	1.004
Diffraction radiation wavelength	0.71075 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
179022 (current)	2016-03-22	cif/4/12/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/12/20.	4122093.cif
119124	2014-07-05	cif/ Updating files of 4122092, 4122093 Original log message: Adding full bibliography for 4122092--4122093.cif.	4122093.cif
118012	2014-06-25	cif/ Adding structures of 4122092, 4122093 via cif-deposit CGI script.	4122093.cif