Crystallography Open Database

Information card for entry 4123088

Preview

Coordinates	4123088.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C56 H65 Co N2 P Si
Calculated formula	C56 H65 Co N2 P Si
Title of publication	Regio- and Stereoselective Hydrosilylation of Alkynes Catalyzed by Three-Coordinate Cobalt(I) Alkyl and Silyl Complexes.
Authors of publication	Mo, Zhenbo; Xiao, Jie; Gao, Yafei; Deng, Liang
Journal of publication	Journal of the American Chemical Society
Year of publication	2014
Pages of publication	141209075314002
a	10.378 ± 0.002 Å
b	13.095 ± 0.003 Å
c	18.259 ± 0.004 Å
α	81.92 ± 0.004°
β	78.351 ± 0.004°
γ	73.214 ± 0.004°
Cell volume	2317.8 ± 0.9 Å³
Cell temperature	140 ± 2 K
Ambient diffraction temperature	140 ± 2 K
Number of distinct elements	6
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.1466
Residual factor for significantly intense reflections	0.0686
Weighted residual factors for significantly intense reflections	0.1624
Weighted residual factors for all reflections included in the refinement	0.2326
Goodness-of-fit parameter for all reflections included in the refinement	1.064
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
179032 (current)	2016-03-22	cif/4/12/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/12/30.	4123088.cif
128637	2014-12-13	cif/ Adding structures of 4123086, 4123087, 4123088, 4123089 via cif-deposit CGI script.	4123088.cif