Crystallography Open Database

Information card for entry 4123152

Preview

Coordinates	4123152.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C38.5 H82 P6 Si3 W2
Calculated formula	C38.5 H82 P6 Si3 W2
Title of publication	σ-Silane, Disilanyl, and [W(μ-H)Si(μ-H)W] Bridging Silylene Complexes via the Reactions of W(PMe3)4(η(2)-CH2PMe2)H with Phenylsilanes.
Authors of publication	Zuzek, Ashley A.; Neary, Michelle C.; Parkin, Gerard
Journal of publication	Journal of the American Chemical Society
Year of publication	2014
Pages of publication	141217070549000
a	11.276 ± 0.002 Å
b	13.112 ± 0.002 Å
c	18.316 ± 0.003 Å
α	75.844 ± 0.003°
β	81.307 ± 0.003°
γ	84.182 ± 0.003°
Cell volume	2589.8 ± 0.7 Å³
Cell temperature	130 ± 2 K
Ambient diffraction temperature	130 ± 2 K
Number of distinct elements	5
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0857
Residual factor for significantly intense reflections	0.0411
Weighted residual factors for significantly intense reflections	0.056
Weighted residual factors for all reflections included in the refinement	0.0648
Goodness-of-fit parameter for all reflections included in the refinement	1.012
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
176467 (current)	2016-02-16	cif/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in range 4.	4123152.cif
128943	2014-12-21	cif/ Adding structures of 4123152 via cif-deposit CGI script.	4123152.cif