Crystallography Open Database

Information card for entry 4124456

Preview

Coordinates	4124456.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C175 H198 Ag25 Cl2 P S18
Calculated formula	C175 H198 Ag25 Cl2 P S18
SMILES	[Ag]123456789%10%11[Ag]%12%13%14%15%16%17[Ag]%18%19%20%21%221[Ag]1%23%24%253%13[Ag]3%13%26%272%12[Ag]2%12%28%29%304[Ag]4%31%32%33%345[Ag]5%35%36%376%18[Ag]6%187%1914[Ag]14%10%23%13%28%32[Ag]%24([S]4c4c(cc(cc4)C)C)([S]%25([Ag]4%26[S]%27([Ag]1[S]([Ag]%29[S]%34([Ag]1%33([Ag]%36([S]%18c7c(cc(cc7)C)C)[S]1c1c(cc(cc1)C)C)[S]([Ag]179%12%315[Ag]58%1432([Ag]%11%15%20%351([Ag]([S]%17c1c(cc(cc1)C)C)[S]([Ag]%21[S]%37c1c(cc(cc1)C)C)c1c(cc(cc1)C)C)[S]([Ag]5[S]([Ag]7[S]%30c1c(cc(cc1)C)C)c1c(cc(cc1)C)C)c1c(cc(cc1)C)C)[S]([Ag]%16[S]4c1c(cc(cc1)C)C)c1c(cc(cc1)C)C)c1c(cc(cc1)C)C)c1c(cc(cc1)C)C)c1c(cc(cc1)C)C)c1c(cc(cc1)C)C)c1c(cc(cc1)C)C)[S]([Ag]6[S]%22c1c(cc(cc1)C)C)c1c(cc(cc1)C)C.[P+](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1.ClCCl.C(CCC)CC
Title of publication	[Ag25(SR)18](-): The "Golden" Silver Nanoparticle.
Authors of publication	Joshi, Chakra P.; Bootharaju, Megalamane S.; Alhilaly, Mohammad J.; Bakr, Osman M.
Journal of publication	Journal of the American Chemical Society
Year of publication	2015
Journal volume	137
Journal issue	36
Pages of publication	11578 - 11581
a	19.0634 ± 0.001 Å
b	19.5919 ± 0.001 Å
c	26.7981 ± 0.0014 Å
α	93.424 ± 0.002°
β	90.859 ± 0.002°
γ	104.756 ± 0.002°
Cell volume	9656.7 ± 0.9 Å³
Cell temperature	120 K
Ambient diffraction temperature	120 K
Number of distinct elements	6
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.1536
Residual factor for significantly intense reflections	0.0622
Weighted residual factors for significantly intense reflections	0.1148
Weighted residual factors for all reflections included in the refinement	0.1506
Goodness-of-fit parameter for all reflections included in the refinement	1.029
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
160535 (current)	2015-10-06	cif/ Updating files of 4124456 Original log message: Adding full bibliography for 4124456.cif.	4124456.cif
155828	2015-09-10	cif/ Adding structures of 4124456 via cif-deposit CGI script.	4124456.cif