Crystallography Open Database

Information card for entry 4125589

Preview

Coordinates	4125589.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C23 H26 N2 O Si
Calculated formula	C23 H26 N2 O Si
Title of publication	Asymmetric Copper Hydride-Catalyzed Markovnikov Hydrosilylation of Vinylarenes and Vinyl Heterocycles.
Authors of publication	Gribble, Jr, Michael W; Pirnot, Michael T.; Bandar, Jeffrey S.; Liu, Richard Y.; Buchwald, Stephen L.
Journal of publication	Journal of the American Chemical Society
Year of publication	2017
Journal volume	139
Journal issue	6
Pages of publication	2192 - 2195
a	9.5002 ± 0.0002 Å
b	12.7386 ± 0.0003 Å
c	16.6006 ± 0.0004 Å
α	90°
β	90.605 ± 0.001°
γ	90°
Cell volume	2008.88 ± 0.08 Å³
Cell temperature	100 ± 2 K
Ambient diffraction temperature	100 ± 2 K
Number of distinct elements	5
Space group number	4
Hermann-Mauguin space group symbol	P 1 21 1
Hall space group symbol	P 2yb
Residual factor for all reflections	0.0308
Residual factor for significantly intense reflections	0.0307
Weighted residual factors for significantly intense reflections	0.0834
Weighted residual factors for all reflections included in the refinement	0.0835
Goodness-of-fit parameter for all reflections included in the refinement	1.034
Diffraction radiation wavelength	1.54178 Å
Diffraction radiation type	CuKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
193513 (current)	2017-03-04	cif/ Updating files of 4125589 Original log message: Adding full bibliography for 4125589.cif.	4125589.cif
192635	2017-03-01	cif/ Adding structures of 4125589 via cif-deposit CGI script.	4125589.cif