Crystallography Open Database

Information card for entry 4125713

Preview

Coordinates	4125713.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C25 H52 Co N4 Si4
Calculated formula	C25 H52 Co N4 Si4
SMILES	[Co](N([Si](C)(C)C)[Si](C)(C)C)(N([Si](C)(C)C)[Si](C)(C)C)=C1N(C=CN1c1c(cc(cc1C)C)C)C
Title of publication	Mode of Activation of Cobalt(II) Amides for Catalytic Hydrosilylation of Alkenes with Tertiary Silanes.
Authors of publication	Liu, Yang; Deng, Liang
Journal of publication	Journal of the American Chemical Society
Year of publication	2017
Journal volume	139
Journal issue	5
Pages of publication	1798 - 1801
a	8.8549 ± 0.0009 Å
b	10.1984 ± 0.001 Å
c	20.531 ± 0.002 Å
α	81.077 ± 0.002°
β	86.856 ± 0.002°
γ	66.166 ± 0.002°
Cell volume	1675.4 ± 0.3 Å³
Cell temperature	130 K
Ambient diffraction temperature	130 K
Number of distinct elements	5
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0566
Residual factor for significantly intense reflections	0.0368
Weighted residual factors for significantly intense reflections	0.0847
Weighted residual factors for all reflections included in the refinement	0.0926
Goodness-of-fit parameter for all reflections included in the refinement	1.038
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
193094 (current)	2017-03-04	cif/ Adding structures of 4125713, 4125714, 4125715 via cif-deposit CGI script.	4125713.cif