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Information card for entry 4303988
Preview
| Coordinates | 4303988.cif |
|---|---|
| Original paper (by DOI) | HTML |
| External links | PubChem |
| Formula | C36 H88 Ge2 P4 Si8 |
|---|---|
| Calculated formula | C36 H88 Ge2 P4 Si8 |
| SMILES | P12[Ge](C([Si](C)(C)C)[Si](C)(C)C)([C@H](C)P(C1=C)P1C(=C)P2[C@H](C)[Ge]1(C([Si](C)(C)C)[Si](C)(C)C)C([Si](C)(C)C)[Si](C)(C)C)C([Si](C)(C)C)[Si](C)(C)C |
| Title of publication | Unusual Reactivity of Methylphosphaalkyne (P\τbCMe) toward Digermenes and Distannenes: Stepwise Formations of Bridged 2,3,5,6-Tetraphospha-1,4-dimethylidenecyclohexanes |
| Authors of publication | Cameron Jones; Christian Schulten; Andreas Stasch |
| Journal of publication | Inorganic Chemistry |
| Year of publication | 2008 |
| Journal volume | 47 |
| Pages of publication | 1273 - 1278 |
| a | 13.58 ± 0.003 Å |
| b | 16.645 ± 0.003 Å |
| c | 11.978 ± 0.002 Å |
| α | 90° |
| β | 97.6 ± 0.03° |
| γ | 90° |
| Cell volume | 2683.7 ± 0.9 Å3 |
| Cell temperature | 150 ± 2 K |
| Ambient diffraction temperature | 150 ± 2 K |
| Number of distinct elements | 5 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/c 1 |
| Hall space group symbol | -P 2ybc |
| Residual factor for all reflections | 0.0336 |
| Residual factor for significantly intense reflections | 0.028 |
| Weighted residual factors for significantly intense reflections | 0.0662 |
| Weighted residual factors for all reflections included in the refinement | 0.069 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.032 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 301836 (current) | 2025-08-20 | Add cross-references to PubChem compounds in COD range 4/30/ Each referenced PubChem compound corresponds to the full crystal structure. |
4303988.cif |
| 179077 | 2016-03-22 | cif/4/30/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/30/39. |
4303988.cif |
| 120081 | 2014-07-12 | Adding DOIs to range 4/30 structures. | 4303988.cif |
| 34330 | 2012-02-24 | cif/4/ Reorganising CIF range 4 into a prefix tree. |
4303988.cif |
| 1163 | 2010-05-11 | cif/4/: committing data from the Inorg-Chem-2008_01-12/ deposition. | 4303988.cif |
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