Crystallography Open Database

Information card for entry 4306854

Preview

Coordinates	4306854.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C36 H42 Co10 N5 O22 Rh
Calculated formula	C36 H6 Co10 N5 O22 Rh
Title of publication	Mixed Co-Rh Nitrido-Encapsulated Carbonyl Clusters. Synthesis, Solid-State Structure, and Electrochemical/EPR Characterization of the Anions [Co10Rh(N)2(CO)21]3-, [Co10Rh2(N)2(CO)24]2-, and [Co11Rh(N)2(CO)24]2-
Authors of publication	Michela Costa; Roberto Della Pergola; Alessandro Fumagalli; Franco Laschi; Serena Losi; Piero Macchi; Angelo Sironi; Piero Zanello
Journal of publication	Inorganic Chemistry
Year of publication	2007
Journal volume	46
Pages of publication	552 - 560
a	17.223 ± 0.004 Å
b	14.6 ± 0.002 Å
c	22.326 ± 0.006 Å
α	90 ± 0.005°
β	102.22 ± 0.02°
γ	90 ± 0.005°
Cell volume	5487 ± 2 Å³
Cell temperature	293 ± 2 K
Ambient diffraction temperature	293 ± 2 K
Number of distinct elements	6
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/n 1
Hall space group symbol	-P 2yn
Residual factor for all reflections	0.1799
Residual factor for significantly intense reflections	0.0487
Weighted residual factors for significantly intense reflections	0.1224
Weighted residual factors for all reflections included in the refinement	0.163
Goodness-of-fit parameter for all reflections included in the refinement	0.96
Diffraction radiation probe	x-ray
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
179106 (current)	2016-03-23	cif/4/30/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/30/68.	4306854.cif
120081	2014-07-12	Adding DOIs to range 4/30 structures.	4306854.cif
34330	2012-02-24	cif/4/ Reorganising CIF range 4 into a prefix tree.	4306854.cif
1194	2010-06-06	cif/4/ Adding data from Inorg-Chem-2007_01-13/ processing directory.	4306854.cif