#------------------------------------------------------------------------------
#$Date: 2016-03-23 00:22:55 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179107 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/69/4306918.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4306918
loop_
_publ_author_name
'Sean E. Durran'
'Mark R. J. Elsegood'
'Shelly R. Hammond'
'Martin B. Smith'
_publ_section_title
;
Coordination Studies of a New Unsymmetrical
κ4-PNN'N''-Tetradentate Ligand: Stepwise Formation and
Structural Characterization
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2755
_journal_page_last               2766
_journal_paper_doi               10.1021/ic061196s
_journal_volume                  46
_journal_year                    2007
_chemical_formula_sum            'C36 H29 Cl3 N3 O3 P Pt'
_chemical_formula_weight         884.03
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     heavy
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                88.533(2)
_cell_angle_beta                 86.397(2)
_cell_angle_gamma                63.724(2)
_cell_formula_units_Z            2
_cell_length_a                   12.1259(6)
_cell_length_b                   12.3708(6)
_cell_length_c                   12.7204(6)
_cell_measurement_reflns_used    9556
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      28.84
_cell_measurement_theta_min      2.44
_cell_volume                     1707.60(15)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL and local programs'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.872
_diffrn_measurement_device_type  'Bruker SMART 1000 CCD diffractometer'
_diffrn_measurement_method       'ω rotation with narrow frames'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0238
_diffrn_reflns_av_sigmaI/netI    0.0394
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            15289
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         28.97
_diffrn_reflns_theta_min         1.60
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    4.431
_exptl_absorpt_correction_T_max  0.917
_exptl_absorpt_correction_T_min  0.503
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS v2.03, Sheldrick, G.M., (2001)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.719
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             868
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.02
_refine_diff_density_max         1.332
_refine_diff_density_min         -1.319
_refine_diff_density_rms         0.112
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.070
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     424
_refine_ls_number_reflns         7903
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.070
_refine_ls_R_factor_all          0.0331
_refine_ls_R_factor_gt           0.0262
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0273P)²+0.6874P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0581
_refine_ls_wR_factor_ref         0.0612
_reflns_number_gt                7026
_reflns_number_total             7903
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            ic061196ssi20060703_115123_5.cif
_cod_data_source_block           anti-6a.CHCl~3~
_cod_original_cell_volume        1707.60(14)
_cod_database_code               4306918
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.515319(11) 0.865426(11) 0.729106(9) 0.01681(4) Uani 1 1 d . . .
P1 P 0.38785(7) 0.80182(8) 0.81377(6) 0.01843(17) Uani 1 1 d . . .
N1 N 0.3815(2) 1.0176(2) 0.6733(2) 0.0182(5) Uani 1 1 d . . .
N2 N 0.6244(2) 0.9256(2) 0.6485(2) 0.0177(5) Uani 1 1 d . . .
N3 N 0.6784(2) 0.7306(2) 0.7593(2) 0.0223(6) Uani 1 1 d . . .
C1 C 0.2389(3) 0.8688(3) 0.7522(2) 0.0205(7) Uani 1 1 d . . .
C2 C 0.1608(3) 0.8132(3) 0.7646(3) 0.0246(7) Uani 1 1 d . . .
H2 H 0.1874 0.7397 0.8025 0.030 Uiso 1 1 calc R . .
C3 C 0.0454(3) 0.8621(3) 0.7231(3) 0.0297(8) Uani 1 1 d . . .
H3 H -0.0056 0.8221 0.7329 0.036 Uiso 1 1 calc R . .
C4 C 0.0052(3) 0.9682(4) 0.6678(3) 0.0302(8) Uani 1 1 d . . .
H4 H -0.0736 1.0019 0.6392 0.036 Uiso 1 1 calc R . .
C5 C 0.0802(3) 1.0256(3) 0.6542(3) 0.0290(8) Uani 1 1 d . . .
H5 H 0.0516 1.0993 0.6164 0.035 Uiso 1 1 calc R . .
C6 C 0.1984(3) 0.9777(3) 0.6949(3) 0.0211(7) Uani 1 1 d . . .
C7 C 0.2661(3) 1.0469(3) 0.6650(3) 0.0241(7) Uani 1 1 d . . .
H7 H 0.2191 1.1240 0.6354 0.029 Uiso 1 1 calc R . .
C8 C 0.4325(3) 1.0952(3) 0.6255(2) 0.0194(6) Uani 1 1 d . . .
C9 C 0.3618(3) 1.2139(3) 0.5941(3) 0.0260(7) Uani 1 1 d . . .
H9 H 0.2749 1.2506 0.6073 0.031 Uiso 1 1 calc R . .
C10 C 0.4182(3) 1.2779(3) 0.5438(3) 0.0277(8) Uani 1 1 d . . .
H10 H 0.3700 1.3583 0.5217 0.033 Uiso 1 1 calc R . .
C11 C 0.5453(3) 1.2250(3) 0.5252(3) 0.0257(7) Uani 1 1 d . . .
H11 H 0.5831 1.2694 0.4894 0.031 Uiso 1 1 calc R . .
C12 C 0.6176(3) 1.1091(3) 0.5578(2) 0.0219(7) Uani 1 1 d . . .
H12 H 0.7046 1.0748 0.5460 0.026 Uiso 1 1 calc R . .
C13 C 0.5624(3) 1.0417(3) 0.6087(2) 0.0180(6) Uani 1 1 d . . .
C14 C 0.7439(3) 0.8477(3) 0.6310(2) 0.0203(7) Uani 1 1 d . . .
O1 O 0.8220(2) 0.8659(2) 0.57545(19) 0.0260(5) Uani 1 1 d . . .
C15 C 0.7792(3) 0.7284(3) 0.6880(3) 0.0258(7) Uani 1 1 d . . .
H15A H 0.8020 0.6633 0.6354 0.031 Uiso 1 1 calc R . .
H15B H 0.8521 0.7104 0.7289 0.031 Uiso 1 1 calc R . .
C16 C 0.7016(3) 0.6490(3) 0.8374(3) 0.0228(7) Uani 1 1 d . . .
O2 O 0.6274(2) 0.6501(2) 0.90718(18) 0.0265(5) Uani 1 1 d . . .
O3 O 0.8208(2) 0.5619(2) 0.83051(19) 0.0292(6) Uani 1 1 d . . .
C17 C 0.8488(3) 0.4705(4) 0.9104(3) 0.0376(10) Uani 1 1 d . . .
H17A H 0.8013 0.4240 0.9012 0.045 Uiso 1 1 calc R . .
H17B H 0.8259 0.5083 0.9811 0.045 Uiso 1 1 calc R . .
C18 C 0.9854(3) 0.3875(3) 0.9007(3) 0.0327(8) Uani 1 1 d . . .
C19 C 1.0286(5) 0.2777(5) 0.9522(5) 0.0739(18) Uani 1 1 d . . .
H19 H 0.9723 0.2548 0.9900 0.089 Uiso 1 1 calc R . .
C20 C 1.1550(5) 0.2002(5) 0.9488(6) 0.086(2) Uani 1 1 d . . .
H20 H 1.1837 0.1252 0.9846 0.103 Uiso 1 1 calc R . .
C21 C 1.2357(4) 0.2309(5) 0.8955(4) 0.0602(15) Uani 1 1 d . . .
H21 H 1.3213 0.1783 0.8944 0.072 Uiso 1 1 calc R . .
C22 C 1.1942(4) 0.3392(5) 0.8422(4) 0.0547(13) Uani 1 1 d . . .
H22 H 1.2511 0.3603 0.8032 0.066 Uiso 1 1 calc R . .
C23 C 1.0684(4) 0.4176(4) 0.8457(3) 0.0428(10) Uani 1 1 d . . .
H23 H 1.0403 0.4925 0.8096 0.051 Uiso 1 1 calc R . .
C24 C 0.4302(3) 0.6414(3) 0.8063(2) 0.0193(6) Uani 1 1 d . . .
C25 C 0.4045(3) 0.5761(3) 0.8868(3) 0.0288(8) Uani 1 1 d . . .
H25 H 0.3645 0.6147 0.9513 0.035 Uiso 1 1 calc R . .
C26 C 0.4372(4) 0.4544(4) 0.8727(3) 0.0345(9) Uani 1 1 d . . .
H26 H 0.4191 0.4102 0.9277 0.041 Uiso 1 1 calc R . .
C27 C 0.4953(4) 0.3976(4) 0.7802(3) 0.0389(10) Uani 1 1 d . . .
H27 H 0.5166 0.3146 0.7709 0.047 Uiso 1 1 calc R . .
C28 C 0.5232(4) 0.4616(4) 0.6998(3) 0.0396(10) Uani 1 1 d . . .
H28 H 0.5642 0.4222 0.6358 0.048 Uiso 1 1 calc R . .
C29 C 0.4912(3) 0.5828(3) 0.7134(3) 0.0293(8) Uani 1 1 d . . .
H29 H 0.5112 0.6261 0.6588 0.035 Uiso 1 1 calc R . .
C30 C 0.3441(3) 0.8514(3) 0.9507(2) 0.0208(7) Uani 1 1 d . . .
C31 C 0.4205(3) 0.8858(3) 1.0044(3) 0.0232(7) Uani 1 1 d . . .
H31 H 0.4950 0.8802 0.9706 0.028 Uiso 1 1 calc R . .
C32 C 0.3872(3) 0.9284(3) 1.1077(3) 0.0275(8) Uani 1 1 d . . .
H32 H 0.4388 0.9528 1.1437 0.033 Uiso 1 1 calc R . .
C33 C 0.2807(3) 0.9354(4) 1.1577(3) 0.0323(8) Uani 1 1 d . . .
H33 H 0.2588 0.9646 1.2280 0.039 Uiso 1 1 calc R . .
C34 C 0.2049(4) 0.9001(4) 1.1056(3) 0.0396(10) Uani 1 1 d . . .
H34 H 0.1316 0.9040 1.1404 0.048 Uiso 1 1 calc R . .
C35 C 0.2365(4) 0.8589(4) 1.0026(3) 0.0353(9) Uani 1 1 d . . .
H35 H 0.1839 0.8355 0.9670 0.042 Uiso 1 1 calc R . .
C36 C 0.9169(4) 0.3277(4) 0.4921(3) 0.0412(10) Uani 1 1 d . . .
H36 H 0.9941 0.2601 0.4621 0.049 Uiso 1 1 calc R . .
Cl1 Cl 0.95418(17) 0.38419(14) 0.60246(13) 0.0848(5) Uani 1 1 d . . .
Cl2 Cl 0.81193(11) 0.26920(13) 0.52944(11) 0.0614(3) Uani 1 1 d . . .
Cl3 Cl 0.85790(13) 0.43744(12) 0.39349(12) 0.0712(4) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N3 Pt1 N2 81.23(11) . . ?
N3 Pt1 N1 163.62(11) . . ?
N2 Pt1 N1 82.42(10) . . ?
N3 Pt1 P1 100.79(8) . . ?
N2 Pt1 P1 177.57(8) . . ?
N1 Pt1 P1 95.53(8) . . ?
C24 P1 C30 108.97(15) . . ?
C24 P1 C1 102.07(15) . . ?
C30 P1 C1 102.53(14) . . ?
C24 P1 Pt1 116.82(11) . . ?
C30 P1 Pt1 115.45(11) . . ?
C1 P1 Pt1 109.18(11) . . ?
C7 N1 C8 118.9(3) . . ?
C7 N1 Pt1 129.8(2) . . ?
C8 N1 Pt1 110.90(19) . . ?
C14 N2 C13 127.8(3) . . ?
C14 N2 Pt1 117.6(2) . . ?
C13 N2 Pt1 114.3(2) . . ?
C16 N3 C15 120.3(3) . . ?
C16 N3 Pt1 126.7(2) . . ?
C15 N3 Pt1 113.0(2) . . ?
C2 C1 C6 118.3(3) . . ?
C2 C1 P1 119.5(3) . . ?
C6 C1 P1 122.1(2) . . ?
C3 C2 C1 122.0(3) . . ?
C4 C3 C2 120.0(3) . . ?
C3 C4 C5 119.4(3) . . ?
C4 C5 C6 121.9(3) . . ?
C1 C6 C5 118.3(3) . . ?
C1 C6 C7 128.4(3) . . ?
C5 C6 C7 113.2(3) . . ?
N1 C7 C6 128.6(3) . . ?
C9 C8 C13 120.1(3) . . ?
C9 C8 N1 124.2(3) . . ?
C13 C8 N1 115.7(3) . . ?
C10 C9 C8 119.9(3) . . ?
C9 C10 C11 120.2(3) . . ?
C12 C11 C10 121.0(3) . . ?
C11 C12 C13 119.9(3) . . ?
N2 C13 C12 125.9(3) . . ?
N2 C13 C8 115.3(3) . . ?
C12 C13 C8 118.8(3) . . ?
O1 C14 N2 126.4(3) . . ?
O1 C14 C15 120.5(3) . . ?
N2 C14 C15 113.1(3) . . ?
N3 C15 C14 112.0(3) . . ?
O2 C16 N3 125.6(3) . . ?
O2 C16 O3 122.4(3) . . ?
N3 C16 O3 112.0(3) . . ?
C16 O3 C17 114.0(3) . . ?
O3 C17 C18 108.6(3) . . ?
C23 C18 C19 118.6(4) . . ?
C23 C18 C17 122.9(4) . . ?
C19 C18 C17 118.5(4) . . ?
C18 C19 C20 120.4(5) . . ?
C21 C20 C19 120.6(5) . . ?
C20 C21 C22 119.9(4) . . ?
C21 C22 C23 120.0(5) . . ?
C18 C23 C22 120.5(4) . . ?
C29 C24 C25 119.2(3) . . ?
C29 C24 P1 116.7(2) . . ?
C25 C24 P1 124.1(3) . . ?
C26 C25 C24 120.0(3) . . ?
C27 C26 C25 120.5(3) . . ?
C26 C27 C28 120.0(4) . . ?
C29 C28 C27 119.9(4) . . ?
C28 C29 C24 120.4(3) . . ?
C35 C30 C31 118.8(3) . . ?
C35 C30 P1 122.7(3) . . ?
C31 C30 P1 118.5(2) . . ?
C32 C31 C30 119.9(3) . . ?
C33 C32 C31 120.6(3) . . ?
C32 C33 C34 120.0(3) . . ?
C35 C34 C33 119.8(3) . . ?
C34 C35 C30 120.9(3) . . ?
Cl1 C36 Cl2 110.3(2) . . ?
Cl1 C36 Cl3 112.0(2) . . ?
Cl2 C36 Cl3 110.5(2) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 N3 1.995(3) . ?
Pt1 N2 2.004(3) . ?
Pt1 N1 2.013(3) . ?
Pt1 P1 2.2344(8) . ?
P1 C24 1.821(3) . ?
P1 C30 1.829(3) . ?
P1 C1 1.839(3) . ?
N1 C7 1.291(4) . ?
N1 C8 1.458(4) . ?
N2 C14 1.346(4) . ?
N2 C13 1.393(4) . ?
N3 C16 1.348(4) . ?
N3 C15 1.466(4) . ?
C1 C2 1.396(4) . ?
C1 C6 1.412(5) . ?
C2 C3 1.389(5) . ?
C3 C4 1.373(5) . ?
C4 C5 1.381(5) . ?
C5 C6 1.414(5) . ?
C6 C7 1.456(5) . ?
C8 C9 1.397(5) . ?
C8 C13 1.417(4) . ?
C9 C10 1.379(5) . ?
C10 C11 1.389(5) . ?
C11 C12 1.378(5) . ?
C12 C13 1.404(4) . ?
C14 O1 1.242(4) . ?
C14 C15 1.520(5) . ?
C16 O2 1.219(4) . ?
C16 O3 1.367(4) . ?
O3 C17 1.440(4) . ?
C17 C18 1.513(5) . ?
C18 C23 1.368(6) . ?
C18 C19 1.384(6) . ?
C19 C20 1.400(7) . ?
C20 C21 1.339(8) . ?
C21 C22 1.381(7) . ?
C22 C23 1.397(6) . ?
C24 C29 1.389(5) . ?
C24 C25 1.393(4) . ?
C25 C26 1.390(5) . ?
C26 C27 1.369(6) . ?
C27 C28 1.393(6) . ?
C28 C29 1.384(5) . ?
C30 C35 1.391(5) . ?
C30 C31 1.396(4) . ?
C31 C32 1.396(5) . ?
C32 C33 1.371(5) . ?
C33 C34 1.386(5) . ?
C34 C35 1.386(5) . ?
C36 Cl1 1.753(4) . ?
C36 Cl2 1.758(4) . ?
C36 Cl3 1.759(5) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N3 Pt1 P1 C24 -39.25(15) . . . . ?
N1 Pt1 P1 C24 139.35(14) . . . . ?
N3 Pt1 P1 C30 90.84(15) . . . . ?
N1 Pt1 P1 C30 -90.57(14) . . . . ?
N3 Pt1 P1 C1 -154.33(14) . . . . ?
N1 Pt1 P1 C1 24.26(13) . . . . ?
N3 Pt1 N1 C7 158.0(4) . . . . ?
N2 Pt1 N1 C7 161.5(3) . . . . ?
P1 Pt1 N1 C7 -17.1(3) . . . . ?
N3 Pt1 N1 C8 -14.2(5) . . . . ?
N2 Pt1 N1 C8 -10.63(19) . . . . ?
P1 Pt1 N1 C8 170.70(18) . . . . ?
N3 Pt1 N2 C14 13.1(2) . . . . ?
N1 Pt1 N2 C14 -165.9(2) . . . . ?
N3 Pt1 N2 C13 -172.8(2) . . . . ?
N1 Pt1 N2 C13 8.2(2) . . . . ?
N2 Pt1 N3 C16 161.7(3) . . . . ?
N1 Pt1 N3 C16 165.2(3) . . . . ?
P1 Pt1 N3 C16 -19.7(3) . . . . ?
N2 Pt1 N3 C15 -16.2(2) . . . . ?
N1 Pt1 N3 C15 -12.6(5) . . . . ?
P1 Pt1 N3 C15 162.4(2) . . . . ?
C24 P1 C1 C2 33.3(3) . . . . ?
C30 P1 C1 C2 -79.5(3) . . . . ?
Pt1 P1 C1 C2 157.6(2) . . . . ?
C24 P1 C1 C6 -148.7(3) . . . . ?
C30 P1 C1 C6 98.5(3) . . . . ?
Pt1 P1 C1 C6 -24.4(3) . . . . ?
C6 C1 C2 C3 -0.4(5) . . . . ?
P1 C1 C2 C3 177.6(3) . . . . ?
C1 C2 C3 C4 0.1(5) . . . . ?
C2 C3 C4 C5 -0.1(5) . . . . ?
C3 C4 C5 C6 0.5(6) . . . . ?
C2 C1 C6 C5 0.8(5) . . . . ?
P1 C1 C6 C5 -177.2(2) . . . . ?
C2 C1 C6 C7 -175.0(3) . . . . ?
P1 C1 C6 C7 7.0(5) . . . . ?
C4 C5 C6 C1 -0.9(5) . . . . ?
C4 C5 C6 C7 175.5(3) . . . . ?
C8 N1 C7 C6 172.2(3) . . . . ?
Pt1 N1 C7 C6 0.5(5) . . . . ?
C1 C6 C7 N1 8.9(6) . . . . ?
C5 C6 C7 N1 -167.1(3) . . . . ?
C7 N1 C8 C9 16.8(5) . . . . ?
Pt1 N1 C8 C9 -170.1(3) . . . . ?
C7 N1 C8 C13 -161.3(3) . . . . ?
Pt1 N1 C8 C13 11.8(3) . . . . ?
C13 C8 C9 C10 1.9(5) . . . . ?
N1 C8 C9 C10 -176.1(3) . . . . ?
C8 C9 C10 C11 -0.6(5) . . . . ?
C9 C10 C11 C12 -1.1(5) . . . . ?
C10 C11 C12 C13 1.5(5) . . . . ?
C14 N2 C13 C12 -12.7(5) . . . . ?
Pt1 N2 C13 C12 173.9(2) . . . . ?
C14 N2 C13 C8 169.5(3) . . . . ?
Pt1 N2 C13 C8 -3.8(3) . . . . ?
C11 C12 C13 N2 -177.8(3) . . . . ?
C11 C12 C13 C8 -0.2(5) . . . . ?
C9 C8 C13 N2 176.4(3) . . . . ?
N1 C8 C13 N2 -5.5(4) . . . . ?
C9 C8 C13 C12 -1.5(5) . . . . ?
N1 C8 C13 C12 176.6(3) . . . . ?
C13 N2 C14 O1 0.3(5) . . . . ?
Pt1 N2 C14 O1 173.4(3) . . . . ?
C13 N2 C14 C15 -180.0(3) . . . . ?
Pt1 N2 C14 C15 -6.8(4) . . . . ?
C16 N3 C15 C14 -160.9(3) . . . . ?
Pt1 N3 C15 C14 17.1(3) . . . . ?
O1 C14 C15 N3 173.0(3) . . . . ?
N2 C14 C15 N3 -6.8(4) . . . . ?
C15 N3 C16 O2 172.1(3) . . . . ?
Pt1 N3 C16 O2 -5.6(5) . . . . ?
C15 N3 C16 O3 -7.9(4) . . . . ?
Pt1 N3 C16 O3 174.4(2) . . . . ?
O2 C16 O3 C17 2.0(5) . . . . ?
N3 C16 O3 C17 -178.0(3) . . . . ?
C16 O3 C17 C18 -174.4(3) . . . . ?
O3 C17 C18 C23 16.9(6) . . . . ?
O3 C17 C18 C19 -165.1(4) . . . . ?
C23 C18 C19 C20 0.7(9) . . . . ?
C17 C18 C19 C20 -177.4(6) . . . . ?
C18 C19 C20 C21 -0.2(11) . . . . ?
C19 C20 C21 C22 -0.8(10) . . . . ?
C20 C21 C22 C23 1.3(8) . . . . ?
C19 C18 C23 C22 -0.2(7) . . . . ?
C17 C18 C23 C22 177.8(4) . . . . ?
C21 C22 C23 C18 -0.8(7) . . . . ?
C30 P1 C24 C29 -166.3(3) . . . . ?
C1 P1 C24 C29 85.7(3) . . . . ?
Pt1 P1 C24 C29 -33.3(3) . . . . ?
C30 P1 C24 C25 14.1(3) . . . . ?
C1 P1 C24 C25 -93.9(3) . . . . ?
Pt1 P1 C24 C25 147.2(3) . . . . ?
C29 C24 C25 C26 -1.5(5) . . . . ?
P1 C24 C25 C26 178.1(3) . . . . ?
C24 C25 C26 C27 0.3(6) . . . . ?
C25 C26 C27 C28 0.7(6) . . . . ?
C26 C27 C28 C29 -0.5(7) . . . . ?
C27 C28 C29 C24 -0.7(6) . . . . ?
C25 C24 C29 C28 1.7(5) . . . . ?
P1 C24 C29 C28 -177.9(3) . . . . ?
C24 P1 C30 C35 -70.0(4) . . . . ?
C1 P1 C30 C35 37.6(4) . . . . ?
Pt1 P1 C30 C35 156.2(3) . . . . ?
C24 P1 C30 C31 111.5(3) . . . . ?
C1 P1 C30 C31 -140.8(3) . . . . ?
Pt1 P1 C30 C31 -22.2(3) . . . . ?
C35 C30 C31 C32 -0.9(5) . . . . ?
P1 C30 C31 C32 177.6(3) . . . . ?
C30 C31 C32 C33 0.9(5) . . . . ?
C31 C32 C33 C34 0.0(6) . . . . ?
C32 C33 C34 C35 -0.7(7) . . . . ?
C33 C34 C35 C30 0.6(7) . . . . ?
C31 C30 C35 C34 0.2(6) . . . . ?
P1 C30 C35 C34 -178.2(3) . . . . ?
