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Information card for entry 4306961
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| Coordinates | 4306961.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Common name | (dimethylfluorosilyl)(dimethylbromosilyl)niobocene hydrid |
|---|---|
| Chemical name | bis(cyclopentadienyl)(dimethylfluorosilyl) (dimethylbromosilyl)(hydrido) niobium (V) |
| Formula | C14 H23 Br1.08 F0.92 Nb Si2 |
| Calculated formula | C14 H23 Br F0.953 Nb Si2 |
| Title of publication | Syntheses and Structures of Asymmetric Bis(silyl) Niobocene Hydrides |
| Authors of publication | Konstantin Yu. Dorogov; Muhammed Yousufuddin; Nam-Nhat Ho; Andrei V. Churakov; Lyudmila G. Kuzmina; Arthur J. Schultz; Sax A. Mason; Judith A. K. Howard; Dmitry A. Lemenovskii; Robert Bau; Georgii I. Nikonov |
| Journal of publication | Inorganic Chemistry |
| Year of publication | 2007 |
| Journal volume | 46 |
| Pages of publication | 147 - 160 |
| a | 14.994 ± 0.0004 Å |
| b | 8.9459 ± 0.0002 Å |
| c | 25.9221 ± 0.0007 Å |
| α | 90° |
| β | 99.387 ± 0.001° |
| γ | 90° |
| Cell volume | 3430.5 ± 0.15 Å3 |
| Cell temperature | 120 ± 2 K |
| Ambient diffraction temperature | 120 ± 2 K |
| Number of distinct elements | 6 |
| Space group number | 15 |
| Hermann-Mauguin space group symbol | C 1 2/c 1 |
| Hall space group symbol | -C 2yc |
| Residual factor for all reflections | 0.0534 |
| Residual factor for significantly intense reflections | 0.0442 |
| Weighted residual factors for significantly intense reflections | 0.096 |
| Weighted residual factors for all reflections included in the refinement | 0.1002 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.077 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 179107 (current) | 2016-03-23 | cif/4/30/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/30/69. |
4306961.cif |
| 120081 | 2014-07-12 | Adding DOIs to range 4/30 structures. | 4306961.cif |
| 34330 | 2012-02-24 | cif/4/ Reorganising CIF range 4 into a prefix tree. |
4306961.cif |
| 1194 | 2010-06-06 | cif/4/ Adding data from Inorg-Chem-2007_01-13/ processing directory. |
4306961.cif |
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Users of the data should acknowledge the original authors of the
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