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Information card for entry 4308735
Preview
| Coordinates | 4308735.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C12 H60 N14 O18 Pt2 Rh2 S6 |
|---|---|
| Calculated formula | C12 H48 N14 O18 Pt2 Rh2 S6 |
| SMILES | C1[S]2[Pt]([NH3])([NH3])[S]3CC[NH2][Rh]453([NH2]CC[S]5[Pt]([NH3])([NH3])[S]3CC[NH2][Rh]523([NH2]C1)[NH2]CCS5)[NH2]CCS4.N(=O)(=O)[O-].O=N(=O)[O-].O.O.O.N(=O)(=O)[O-].N(=O)(=O)[O-].O.O.O |
| Title of publication | Two Stereoisomers of an S-Bridged RhIII2PtII2 Tetranuclear Complex [{Pt(NH3)2}2{Rh(aet)3}2]4+ That Lead to a Discrete and a 1D RhIII2PtII2AgI Structures by Reacting with AgI (aet = 2-Aminoethanethiolate) |
| Authors of publication | Yu Chikamoto; Tatsuya Kawamoto; Asako Igashira-Kamiyama; Takumi Konno |
| Journal of publication | Inorganic Chemistry |
| Year of publication | 2005 |
| Journal volume | 44 |
| Pages of publication | 1601 - 1610 |
| a | 8.7663 ± 0.0015 Å |
| b | 9.0333 ± 0.0015 Å |
| c | 14.4 ± 0.003 Å |
| α | 78.994 ± 0.016° |
| β | 83.479 ± 0.016° |
| γ | 71.503 ± 0.013° |
| Cell volume | 1059.8 ± 0.3 Å3 |
| Cell temperature | 296 ± 2 K |
| Ambient diffraction temperature | 296 ± 2 K |
| Number of distinct elements | 7 |
| Space group number | 2 |
| Hermann-Mauguin space group symbol | P -1 |
| Hall space group symbol | -P 1 |
| Residual factor for all reflections | 0.0473 |
| Residual factor for significantly intense reflections | 0.0296 |
| Weighted residual factors for significantly intense reflections | 0.0739 |
| Weighted residual factors for all reflections included in the refinement | 0.0806 |
| Goodness-of-fit parameter for all reflections included in the refinement | 0.95 |
| Diffraction radiation wavelength | 0.71069 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 288183 (current) | 2023-12-08 | cod/ Corrected misspelt data names in multiple entries using the 'cif_correct_tags' program and a data names replacement file from cod-tools revision 9827. This change affected only the misspelt variants of the '_atom_site_symmetry_multiplicity' data name. |
4308735.cif |
| 179125 | 2016-03-23 | cif/4/30/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/30/87. |
4308735.cif |
| 120081 | 2014-07-12 | Adding DOIs to range 4/30 structures. | 4308735.cif |
| 34330 | 2012-02-24 | cif/4/ Reorganising CIF range 4 into a prefix tree. |
4308735.cif |
| 17004 | 2011-03-31 | cif/ Commiting CIFs, that were updated with the 'cif_fix_values' script, using options '--fix-misspelled replacement_values.lst', '--fix-temperature' and '--fix-enums' with built-in table of enum values. The following cmd was used: > (set -x; find ? -name \*.cif | sort | xargs -i sh -c 'if !( > cif_fix_values --fix-misspelled ~/../inputs/replacament_values.lst {} | > cif_filter --add-cif-header {} | > sponge {} ) 2>&1 | grep NOTE; then svn revert {}; > fi' ) & |
4308735.cif |
| 1526 | 2010-09-26 | cif/4/ Adding new CIFs from Inorg. Chem. 2005 deposited via Web deposition site to the COD test database (and transferede to the main COD database after renaming). |
4308735.cif |
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