Crystallography Open Database

Information card for entry 4308867

Preview

Coordinates	4308867.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C33.5 H28 Br4 Cl4.5 N6 O6 Os
Calculated formula	C33.5 H25 Br4 Cl4.5 N6 O6 Os
Title of publication	Chiral Osmium Complexes with Sterically Bulky Schiff-Base Ligands. Crystal Structures of Os(IV) Derivatives and the Reactivity and Catalytic Cyclopropanation of Alkenes with EDA
Authors of publication	Jing Zhang; Jiang-Lin Liang; Xian-Ru Sun; Hai-Bing Zhou; Nian-Yong Zhu; Zhong-Yuan Zhou; Philip Wai Hong Chan; Chi-Ming Che
Journal of publication	Inorganic Chemistry
Year of publication	2005
Journal volume	44
Pages of publication	3942 - 3954
a	12.574 ± 0.003 Å
b	17.4 ± 0.004 Å
c	19.254 ± 0.004 Å
α	90°
β	104.25 ± 0.03°
γ	90°
Cell volume	4082.9 ± 1.7 Å³
Cell temperature	253 ± 2 K
Ambient diffraction temperature	253 ± 2 K
Number of distinct elements	7
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/n 1
Hall space group symbol	-P 2yn
Residual factor for all reflections	0.092
Residual factor for significantly intense reflections	0.0505
Weighted residual factors for significantly intense reflections	0.1225
Weighted residual factors for all reflections included in the refinement	0.1534
Goodness-of-fit parameter for all reflections included in the refinement	0.941
Diffraction radiation wavelength	0.71069 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
176467 (current)	2016-02-16	cif/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in range 4.	4308867.cif
120081	2014-07-12	Adding DOIs to range 4/30 structures.	4308867.cif
34330	2012-02-24	cif/4/ Reorganising CIF range 4 into a prefix tree.	4308867.cif
1526	2010-09-26	cif/4/ Adding new CIFs from Inorg. Chem. 2005 deposited via Web deposition site to the COD test database (and transferede to the main COD database after renaming).	4308867.cif