#------------------------------------------------------------------------------
#$Date: 2016-03-23 00:53:07 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179133 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/95/4309551.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4309551
loop_
_publ_author_name
'Richard D. Adams'
'Burjor Captain'
'Rolfe H. Herber'
'Mikael Johansson'
'Israel Nowik'
'Jack L. Smith'
'Mark D. Smith'
_publ_section_title
;
Addition of Palladium and Platinum Tri-tert-Butylphosphine Groups to
Re-Sn and Re-Ge Bonds
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6346
_journal_page_last               6358
_journal_paper_doi               10.1021/ic051077x
_journal_volume                  44
_journal_year                    2005
_chemical_formula_moiety         'C44 H47 O8 P Pt Re2 Sn2'
_chemical_formula_sum            'C44 H47 O8 P Pt Re2 Sn2'
_chemical_formula_weight         1539.66
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 102.1550(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.5715(5)
_cell_length_b                   23.1038(10)
_cell_length_c                   17.8097(7)
_cell_measurement_reflns_used    4289
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      26.385
_cell_measurement_theta_min      2.500
_cell_volume                     4654.6(3)
_computing_cell_refinement       'SAINT+ NT V6.22 (Bruker, 2001)'
_computing_data_collection       'SMART NT V5.625 (Bruker, 1998)'
_computing_data_reduction        'SAINT+ NT V6.22'
_computing_molecular_graphics    'SHELXTL V6.1 (Sheldrick, 2000)'
_computing_publication_material  'SHELXTL V6.1'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker SMART APEX CCD diffractometer'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0373
_diffrn_reflns_av_sigmaI/netI    0.1095
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            9518
_diffrn_reflns_theta_full        25.03
_diffrn_reflns_theta_max         25.03
_diffrn_reflns_theta_min         1.46
_diffrn_standards_decay_%        0
_exptl_absorpt_coefficient_mu    9.318
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.5690
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS, Bruker, 2001)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    2.197
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             2872
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.02
_refine_diff_density_max         0.992
_refine_diff_density_min         -1.121
_refine_diff_density_rms         0.200
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.016
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     524
_refine_ls_number_reflns         9569
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.016
_refine_ls_R_factor_all          0.0576
_refine_ls_R_factor_gt           0.0381
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
; calc 
 [0.00000+1.00000exp(3.45(sinθ/λ)²)]/ 
   [σ²(Fo²)+0.0000+0.1000*P+(0.0325P)²+0.0000sinθ/λ] 
 where P = 0.33333Fo² + 0.66667Fc² 
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0745
_refine_ls_wR_factor_ref         0.0828
_reflns_number_gt                7322
_reflns_number_total             9569
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic051077xsi20050630_093837.cif
_cod_data_source_block           re2twin
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4309551
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.42555(4) 0.209800(15) 0.80331(2) 0.01416(9) Uani 1 1 d . . .
Re1 Re 0.55108(4) 0.105778(15) 0.81501(2) 0.01242(9) Uani 1 1 d . . .
Re2 Re 0.60394(4) 0.070090(16) 0.65171(2) 0.01488(10) Uani 1 1 d . . .
Sn1 Sn 0.42305(6) 0.14594(3) 0.67264(4) 0.01338(15) Uani 1 1 d . . .
Sn2 Sn 0.71306(6) 0.02548(3) 0.79096(4) 0.01558(16) Uani 1 1 d . . .
P1 P 0.3391(2) 0.29570(10) 0.83083(15) 0.0159(6) Uani 1 1 d . . .
O11 O 0.3784(7) 0.0001(3) 0.7999(5) 0.0255(18) Uani 1 1 d . . .
O12 O 0.6694(7) 0.0695(3) 0.9794(4) 0.0287(19) Uani 1 1 d . . .
O13 O 0.7284(8) 0.2097(3) 0.8173(5) 0.033(2) Uani 1 1 d . . .
O14 O 0.3736(7) 0.1341(3) 0.9182(4) 0.0242(18) Uani 1 1 d . . .
O21 O 0.4024(7) -0.0228(3) 0.6302(5) 0.0258(18) Uani 1 1 d . . .
O22 O 0.7602(7) -0.0199(3) 0.5930(5) 0.033(2) Uani 1 1 d . . .
O23 O 0.5044(8) 0.1106(3) 0.4851(4) 0.035(2) Uani 1 1 d . . .
O24 O 0.8000(7) 0.1643(3) 0.6728(5) 0.0253(18) Uani 1 1 d . . .
C11 C 0.4412(9) 0.0386(4) 0.8058(6) 0.017(2) Uani 1 1 d . . .
C12 C 0.6285(11) 0.0806(4) 0.9173(6) 0.023(2) Uani 1 1 d . . .
C13 C 0.6613(10) 0.1725(4) 0.8178(6) 0.019(2) Uani 1 1 d . . .
C14 C 0.4298(9) 0.1424(4) 0.8711(6) 0.018(2) Uani 1 1 d . . .
C21 C 0.4766(10) 0.0098(4) 0.6404(6) 0.019(2) Uani 1 1 d . . .
C22 C 0.7066(9) 0.0132(4) 0.6168(6) 0.019(2) Uani 1 1 d . . .
C23 C 0.5383(10) 0.0972(4) 0.5473(6) 0.022(2) Uani 1 1 d . . .
C24 C 0.7291(10) 0.1298(4) 0.6656(6) 0.020(2) Uani 1 1 d . . .
C31 C 0.2511(10) 0.1060(4) 0.6432(6) 0.022(2) Uani 1 1 d . . .
C32 C 0.2090(9) 0.0867(4) 0.5684(6) 0.016(2) Uani 1 1 d . . .
H32 H 0.2545 0.0921 0.5303 0.019 Uiso 1 1 calc R . .
C33 C 0.0989(10) 0.0591(4) 0.5498(6) 0.024(3) Uani 1 1 d . . .
H33 H 0.0687 0.0467 0.4986 0.028 Uiso 1 1 calc R . .
C34 C 0.0354(11) 0.0500(4) 0.6042(7) 0.026(3) Uani 1 1 d . . .
H34 H -0.0382 0.0303 0.5912 0.031 Uiso 1 1 calc R . .
C35 C 0.0753(10) 0.0687(4) 0.6773(6) 0.022(2) Uani 1 1 d . . .
H35 H 0.0293 0.0621 0.7149 0.027 Uiso 1 1 calc R . .
C36 C 0.1831(9) 0.0974(4) 0.6977(6) 0.016(2) Uani 1 1 d . . .
H36 H 0.2100 0.1110 0.7487 0.019 Uiso 1 1 calc R . .
C37 C 0.4166(10) 0.2198(4) 0.5972(6) 0.022(2) Uani 1 1 d . . .
C38 C 0.3053(10) 0.2362(4) 0.5548(6) 0.017(2) Uani 1 1 d . . .
H38 H 0.2372 0.2142 0.5582 0.021 Uiso 1 1 calc R . .
C39 C 0.2949(11) 0.2849(5) 0.5077(7) 0.031(3) Uani 1 1 d . . .
H39 H 0.2195 0.2966 0.4795 0.037 Uiso 1 1 calc R . .
C40 C 0.3943(12) 0.3159(5) 0.5020(7) 0.034(3) Uani 1 1 d . . .
H40 H 0.3864 0.3492 0.4700 0.041 Uiso 1 1 calc R . .
C41 C 0.5058(11) 0.2997(4) 0.5420(6) 0.026(3) Uani 1 1 d . . .
H41 H 0.5742 0.3209 0.5373 0.031 Uiso 1 1 calc R . .
C42 C 0.5139(11) 0.2508(4) 0.5898(6) 0.024(3) Uani 1 1 d . . .
H42 H 0.5894 0.2389 0.6177 0.029 Uiso 1 1 calc R . .
C43 C 0.6847(10) -0.0643(4) 0.8125(7) 0.022(2) Uani 1 1 d . . .
C44 C 0.7085(10) -0.1061(4) 0.7604(7) 0.027(3) Uani 1 1 d . . .
H44 H 0.7275 -0.0945 0.7133 0.033 Uiso 1 1 calc R . .
C45 C 0.7040(12) -0.1649(5) 0.7781(8) 0.037(3) Uani 1 1 d . . .
H45 H 0.7226 -0.1929 0.7434 0.044 Uiso 1 1 calc R . .
C46 C 0.6738(11) -0.1826(4) 0.8436(8) 0.033(3) Uani 1 1 d . . .
H46 H 0.6690 -0.2227 0.8541 0.039 Uiso 1 1 calc R . .
C47 C 0.6502(11) -0.1425(5) 0.8948(7) 0.033(3) Uani 1 1 d . . .
H47 H 0.6303 -0.1549 0.9413 0.039 Uiso 1 1 calc R . .
C48 C 0.6552(11) -0.0837(4) 0.8792(6) 0.024(3) Uani 1 1 d . . .
H48 H 0.6380 -0.0564 0.9152 0.028 Uiso 1 1 calc R . .
C49 C 0.8963(9) 0.0363(4) 0.8444(6) 0.016(2) Uani 1 1 d . . .
C50 C 0.9535(10) 0.0897(4) 0.8486(6) 0.021(2) Uani 1 1 d . . .
H50 H 0.9119 0.1232 0.8270 0.025 Uiso 1 1 calc R . .
C51 C 1.0723(10) 0.0932(4) 0.8849(6) 0.018(2) Uani 1 1 d . . .
H51 H 1.1108 0.1298 0.8895 0.022 Uiso 1 1 calc R . .
C52 C 1.1341(12) 0.0453(5) 0.9139(7) 0.034(3) Uani 1 1 d . . .
H52 H 1.2155 0.0485 0.9374 0.041 Uiso 1 1 calc R . .
C53 C 1.0788(12) -0.0086(5) 0.9092(8) 0.039(3) Uani 1 1 d . . .
H53 H 1.1218 -0.0422 0.9292 0.046 Uiso 1 1 calc R . .
C54 C 0.9609(11) -0.0121(5) 0.8751(6) 0.027(3) Uani 1 1 d . . .
H54 H 0.9224 -0.0486 0.8724 0.032 Uiso 1 1 calc R . .
C55 C 0.1805(11) 0.3018(5) 0.7743(7) 0.031(3) Uani 1 1 d . . .
C56 C 0.1841(12) 0.3099(6) 0.6886(7) 0.045(4) Uani 1 1 d . . .
H56A H 0.1033 0.3138 0.6583 0.067 Uiso 1 1 calc R . .
H56B H 0.2220 0.2762 0.6706 0.067 Uiso 1 1 calc R . .
H56C H 0.2293 0.3448 0.6826 0.067 Uiso 1 1 calc R . .
C57 C 0.1163(11) 0.2435(5) 0.7795(8) 0.041(4) Uani 1 1 d . . .
H57A H 0.1366 0.2162 0.7422 0.062 Uiso 1 1 calc R . .
H57B H 0.0307 0.2498 0.7681 0.062 Uiso 1 1 calc R . .
H57C H 0.1411 0.2275 0.8314 0.062 Uiso 1 1 calc R . .
C58 C 0.1118(11) 0.3509(5) 0.8009(7) 0.031(3) Uani 1 1 d . . .
H58A H 0.1453 0.3880 0.7895 0.047 Uiso 1 1 calc R . .
H58B H 0.1170 0.3477 0.8564 0.047 Uiso 1 1 calc R . .
H58C H 0.0288 0.3487 0.7741 0.047 Uiso 1 1 calc R . .
C59 C 0.4321(12) 0.3550(4) 0.8000(7) 0.031(3) Uani 1 1 d . . .
C60 C 0.4664(12) 0.3375(4) 0.7254(7) 0.032(3) Uani 1 1 d . . .
H60A H 0.5118 0.3688 0.7082 0.048 Uiso 1 1 calc R . .
H60B H 0.3948 0.3302 0.6861 0.048 Uiso 1 1 calc R . .
H60C H 0.5147 0.3023 0.7337 0.048 Uiso 1 1 calc R . .
C61 C 0.3724(14) 0.4161(4) 0.7896(8) 0.042(4) Uani 1 1 d . . .
H61A H 0.4246 0.4435 0.7709 0.063 Uiso 1 1 calc R . .
H61B H 0.3581 0.4296 0.8390 0.063 Uiso 1 1 calc R . .
H61C H 0.2970 0.4136 0.7523 0.063 Uiso 1 1 calc R . .
C62 C 0.5498(11) 0.3603(5) 0.8598(7) 0.033(3) Uani 1 1 d . . .
H62A H 0.5863 0.3220 0.8694 0.049 Uiso 1 1 calc R . .
H62B H 0.5341 0.3759 0.9079 0.049 Uiso 1 1 calc R . .
H62C H 0.6034 0.3863 0.8401 0.049 Uiso 1 1 calc R . .
C63 C 0.3389(10) 0.3032(4) 0.9368(6) 0.021(2) Uani 1 1 d . . .
C64 C 0.2415(11) 0.2646(4) 0.9578(7) 0.027(3) Uani 1 1 d . . .
H64A H 0.1971 0.2868 0.9892 0.041 Uiso 1 1 calc R . .
H64B H 0.2777 0.2308 0.9868 0.041 Uiso 1 1 calc R . .
H64C H 0.1876 0.2517 0.9107 0.041 Uiso 1 1 calc R . .
C65 C 0.4569(10) 0.2793(5) 0.9849(6) 0.024(2) Uani 1 1 d . . .
H65A H 0.4532 0.2789 1.0394 0.035 Uiso 1 1 calc R . .
H65B H 0.5223 0.3041 0.9776 0.035 Uiso 1 1 calc R . .
H65C H 0.4696 0.2399 0.9681 0.035 Uiso 1 1 calc R . .
C66 C 0.3206(11) 0.3654(4) 0.9631(6) 0.026(3) Uani 1 1 d . . .
H66A H 0.2377 0.3766 0.9447 0.039 Uiso 1 1 calc R . .
H66B H 0.3716 0.3919 0.9418 0.039 Uiso 1 1 calc R . .
H66C H 0.3407 0.3673 1.0193 0.039 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Re Re -1.0185 7.2310 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C14 Pt1 P1 120.3(3) . . ?
C14 Pt1 Sn1 95.1(3) . . ?
P1 Pt1 Sn1 135.17(7) . . ?
C14 Pt1 Re1 47.7(3) . . ?
P1 Pt1 Re1 163.85(7) . . ?
Sn1 Pt1 Re1 60.939(18) . . ?
C12 Re1 C11 90.2(4) . . ?
C12 Re1 C13 92.4(4) . . ?
C11 Re1 C13 176.7(4) . . ?
C12 Re1 C14 84.0(4) . . ?
C11 Re1 C14 82.6(4) . . ?
C13 Re1 C14 99.7(4) . . ?
C12 Re1 Sn2 75.4(3) . . ?
C11 Re1 Sn2 84.6(3) . . ?
C13 Re1 Sn2 94.1(3) . . ?
C14 Re1 Sn2 155.6(3) . . ?
C12 Re1 Pt1 117.2(3) . . ?
C11 Re1 Pt1 110.6(3) . . ?
C13 Re1 Pt1 69.9(3) . . ?
C14 Re1 Pt1 44.7(3) . . ?
Sn2 Re1 Pt1 159.22(2) . . ?
C12 Re1 Sn1 175.0(3) . . ?
C11 Re1 Sn1 88.7(3) . . ?
C13 Re1 Sn1 88.9(3) . . ?
C14 Re1 Sn1 91.1(3) . . ?
Sn2 Re1 Sn1 109.33(2) . . ?
Pt1 Re1 Sn1 58.782(17) . . ?
C12 Re1 Re2 129.5(3) . . ?
C11 Re1 Re2 88.0(3) . . ?
C13 Re1 Re2 88.8(3) . . ?
C14 Re1 Re2 145.4(3) . . ?
Sn2 Re1 Re2 54.188(18) . . ?
Pt1 Re1 Re2 110.453(17) . . ?
Sn1 Re1 Re2 55.332(17) . . ?
C23 Re2 C22 93.1(4) . . ?
C23 Re2 C24 91.3(5) . . ?
C22 Re2 C24 91.8(4) . . ?
C23 Re2 C21 89.8(4) . . ?
C22 Re2 C21 89.1(4) . . ?
C24 Re2 C21 178.5(4) . . ?
C23 Re2 Sn2 173.8(3) . . ?
C22 Re2 Sn2 80.8(3) . . ?
C24 Re2 Sn2 87.9(3) . . ?
C21 Re2 Sn2 91.1(3) . . ?
C23 Re2 Sn1 77.0(3) . . ?
C22 Re2 Sn1 167.9(3) . . ?
C24 Re2 Sn1 95.4(3) . . ?
C21 Re2 Sn1 83.9(3) . . ?
Sn2 Re2 Sn1 109.19(2) . . ?
C23 Re2 Re1 132.0(3) . . ?
C22 Re2 Re1 134.9(3) . . ?
C24 Re2 Re1 88.9(3) . . ?
C21 Re2 Re1 89.6(3) . . ?
Sn2 Re2 Re1 54.126(18) . . ?
Sn1 Re2 Re1 55.246(18) . . ?
C31 Sn1 C37 106.1(4) . . ?
C31 Sn1 Pt1 106.3(3) . . ?
C37 Sn1 Pt1 95.5(3) . . ?
C31 Sn1 Re1 111.3(3) . . ?
C37 Sn1 Re1 139.8(3) . . ?
Pt1 Sn1 Re1 60.279(18) . . ?
C31 Sn1 Re2 112.1(3) . . ?
C37 Sn1 Re2 109.8(3) . . ?
Pt1 Sn1 Re2 124.78(3) . . ?
Re1 Sn1 Re2 69.42(2) . . ?
C43 Sn2 C49 102.0(4) . . ?
C43 Sn2 Re1 119.5(3) . . ?
C49 Sn2 Re1 119.8(3) . . ?
C43 Sn2 Re2 117.8(3) . . ?
C49 Sn2 Re2 125.6(3) . . ?
Re1 Sn2 Re2 71.69(2) . . ?
C59 P1 C63 110.0(5) . . ?
C59 P1 C55 109.7(6) . . ?
C63 P1 C55 108.5(5) . . ?
C59 P1 Pt1 105.1(4) . . ?
C63 P1 Pt1 112.3(3) . . ?
C55 P1 Pt1 111.2(3) . . ?
O11 C11 Re1 179.4(10) . . ?
O12 C12 Re1 174.5(10) . . ?
O13 C13 Re1 176.6(9) . . ?
O14 C14 Pt1 128.2(8) . . ?
O14 C14 Re1 144.0(8) . . ?
Pt1 C14 Re1 87.6(4) . . ?
O21 C21 Re2 176.2(10) . . ?
O22 C22 Re2 175.9(10) . . ?
O23 C23 Re2 175.8(10) . . ?
O24 C24 Re2 179.3(11) . . ?
C36 C31 C32 119.2(10) . . ?
C36 C31 Sn1 121.5(8) . . ?
C32 C31 Sn1 119.3(7) . . ?
C31 C32 C33 119.3(9) . . ?
C31 C32 H32 120.3 . . ?
C33 C32 H32 120.3 . . ?
C34 C33 C32 120.4(11) . . ?
C34 C33 H33 119.8 . . ?
C32 C33 H33 119.8 . . ?
C33 C34 C35 120.9(11) . . ?
C33 C34 H34 119.6 . . ?
C35 C34 H34 119.6 . . ?
C34 C35 C36 120.4(10) . . ?
C34 C35 H35 119.8 . . ?
C36 C35 H35 119.8 . . ?
C31 C36 C35 119.7(10) . . ?
C31 C36 H36 120.1 . . ?
C35 C36 H36 120.1 . . ?
C42 C37 C38 119.5(9) . . ?
C42 C37 Sn1 123.5(8) . . ?
C38 C37 Sn1 117.1(8) . . ?
C39 C38 C37 119.7(11) . . ?
C39 C38 H38 120.2 . . ?
C37 C38 H38 120.2 . . ?
C40 C39 C38 119.8(11) . . ?
C40 C39 H39 120.1 . . ?
C38 C39 H39 120.1 . . ?
C39 C40 C41 121.5(10) . . ?
C39 C40 H40 119.2 . . ?
C41 C40 H40 119.2 . . ?
C40 C41 C42 117.7(11) . . ?
C40 C41 H41 121.2 . . ?
C42 C41 H41 121.2 . . ?
C37 C42 C41 121.9(11) . . ?
C37 C42 H42 119.1 . . ?
C41 C42 H42 119.1 . . ?
C48 C43 C44 117.7(9) . . ?
C48 C43 Sn2 122.8(7) . . ?
C44 C43 Sn2 119.2(8) . . ?
C45 C44 C43 119.8(11) . . ?
C45 C44 H44 120.1 . . ?
C43 C44 H44 120.1 . . ?
C46 C45 C44 121.2(11) . . ?
C46 C45 H45 119.4 . . ?
C44 C45 H45 119.4 . . ?
C45 C46 C47 119.7(10) . . ?
C45 C46 H46 120.1 . . ?
C47 C46 H46 120.1 . . ?
C46 C47 C48 120.4(11) . . ?
C46 C47 H47 119.8 . . ?
C48 C47 H47 119.8 . . ?
C43 C48 C47 121.2(10) . . ?
C43 C48 H48 119.4 . . ?
C47 C48 H48 119.4 . . ?
C54 C49 C50 118.8(10) . . ?
C54 C49 Sn2 118.6(7) . . ?
C50 C49 Sn2 122.7(8) . . ?
C51 C50 C49 119.2(10) . . ?
C51 C50 H50 120.4 . . ?
C49 C50 H50 120.4 . . ?
C52 C51 C50 121.1(10) . . ?
C52 C51 H51 119.5 . . ?
C50 C51 H51 119.5 . . ?
C51 C52 C53 120.5(12) . . ?
C51 C52 H52 119.8 . . ?
C53 C52 H52 119.8 . . ?
C54 C53 C52 118.7(12) . . ?
C54 C53 H53 120.6 . . ?
C52 C53 H53 120.6 . . ?
C53 C54 C49 121.7(11) . . ?
C53 C54 H54 119.1 . . ?
C49 C54 H54 119.1 . . ?
C58 C55 C56 110.0(10) . . ?
C58 C55 C57 110.0(10) . . ?
C56 C55 C57 106.1(10) . . ?
C58 C55 P1 113.6(8) . . ?
C56 C55 P1 107.9(8) . . ?
C57 C55 P1 109.0(8) . . ?
C55 C56 H56A 109.5 . . ?
C55 C56 H56B 109.5 . . ?
H56A C56 H56B 109.5 . . ?
C55 C56 H56C 109.5 . . ?
H56A C56 H56C 109.5 . . ?
H56B C56 H56C 109.5 . . ?
C55 C57 H57A 109.5 . . ?
C55 C57 H57B 109.5 . . ?
H57A C57 H57B 109.5 . . ?
C55 C57 H57C 109.5 . . ?
H57A C57 H57C 109.5 . . ?
H57B C57 H57C 109.5 . . ?
C55 C58 H58A 109.5 . . ?
C55 C58 H58B 109.5 . . ?
H58A C58 H58B 109.5 . . ?
C55 C58 H58C 109.5 . . ?
H58A C58 H58C 109.5 . . ?
H58B C58 H58C 109.5 . . ?
C60 C59 C62 105.6(11) . . ?
C60 C59 C61 109.1(9) . . ?
C62 C59 C61 108.2(10) . . ?
C60 C59 P1 109.3(7) . . ?
C62 C59 P1 109.2(8) . . ?
C61 C59 P1 115.0(9) . . ?
C59 C60 H60A 109.5 . . ?
C59 C60 H60B 109.5 . . ?
H60A C60 H60B 109.5 . . ?
C59 C60 H60C 109.5 . . ?
H60A C60 H60C 109.5 . . ?
H60B C60 H60C 109.5 . . ?
C59 C61 H61A 109.5 . . ?
C59 C61 H61B 109.5 . . ?
H61A C61 H61B 109.5 . . ?
C59 C61 H61C 109.5 . . ?
H61A C61 H61C 109.5 . . ?
H61B C61 H61C 109.5 . . ?
C59 C62 H62A 109.5 . . ?
C59 C62 H62B 109.5 . . ?
H62A C62 H62B 109.5 . . ?
C59 C62 H62C 109.5 . . ?
H62A C62 H62C 109.5 . . ?
H62B C62 H62C 109.5 . . ?
C66 C63 C64 108.1(8) . . ?
C66 C63 C65 109.0(9) . . ?
C64 C63 C65 105.3(9) . . ?
C66 C63 P1 114.6(7) . . ?
C64 C63 P1 110.0(7) . . ?
C65 C63 P1 109.4(7) . . ?
C63 C64 H64A 109.5 . . ?
C63 C64 H64B 109.5 . . ?
H64A C64 H64B 109.5 . . ?
C63 C64 H64C 109.5 . . ?
H64A C64 H64C 109.5 . . ?
H64B C64 H64C 109.5 . . ?
C63 C65 H65A 109.5 . . ?
C63 C65 H65B 109.5 . . ?
H65A C65 H65B 109.5 . . ?
C63 C65 H65C 109.5 . . ?
H65A C65 H65C 109.5 . . ?
H65B C65 H65C 109.5 . . ?
C63 C66 H66A 109.5 . . ?
C63 C66 H66B 109.5 . . ?
H66A C66 H66B 109.5 . . ?
C63 C66 H66C 109.5 . . ?
H66A C66 H66C 109.5 . . ?
H66B C66 H66C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C14 1.966(10) . ?
Pt1 P1 2.321(2) . ?
Pt1 Sn1 2.7505(8) . ?
Pt1 Re1 2.7932(5) . ?
Re1 C12 1.943(11) . ?
Re1 C11 1.992(10) . ?
Re1 C13 1.995(11) . ?
Re1 C14 2.067(10) . ?
Re1 Sn2 2.7343(8) . ?
Re1 Sn1 2.8113(8) . ?
Re1 Re2 3.2034(6) . ?
Re2 C23 1.957(12) . ?
Re2 C22 1.959(10) . ?
Re2 C24 1.978(10) . ?
Re2 C21 2.007(11) . ?
Re2 Sn2 2.7364(9) . ?
Re2 Sn1 2.8143(8) . ?
Sn1 C31 2.156(11) . ?
Sn1 C37 2.165(10) . ?
Sn2 C43 2.148(10) . ?
Sn2 C49 2.148(10) . ?
P1 C59 1.894(11) . ?
P1 C63 1.896(11) . ?
P1 C55 1.904(12) . ?
O11 C11 1.139(11) . ?
O12 C12 1.137(13) . ?
O13 C13 1.160(12) . ?
O14 C14 1.180(12) . ?
O21 C21 1.128(12) . ?
O22 C22 1.122(12) . ?
O23 C23 1.138(13) . ?
O24 C24 1.132(12) . ?
C31 C36 1.387(14) . ?
C31 C32 1.393(14) . ?
C32 C33 1.400(15) . ?
C32 H32 0.9500 . ?
C33 C34 1.350(15) . ?
C33 H33 0.9500 . ?
C34 C35 1.356(16) . ?
C34 H34 0.9500 . ?
C35 C36 1.392(15) . ?
C35 H35 0.9500 . ?
C36 H36 0.9500 . ?
C37 C42 1.364(15) . ?
C37 C38 1.400(15) . ?
C38 C39 1.394(13) . ?
C38 H38 0.9500 . ?
C39 C40 1.376(17) . ?
C39 H39 0.9500 . ?
C40 C41 1.388(17) . ?
C40 H40 0.9500 . ?
C41 C42 1.405(14) . ?
C41 H41 0.9500 . ?
C42 H42 0.9500 . ?
C43 C48 1.378(15) . ?
C43 C44 1.406(15) . ?
C44 C45 1.396(14) . ?
C44 H44 0.9500 . ?
C45 C46 1.350(17) . ?
C45 H45 0.9500 . ?
C46 C47 1.367(16) . ?
C46 H46 0.9500 . ?
C47 C48 1.390(14) . ?
C47 H47 0.9500 . ?
C48 H48 0.9500 . ?
C49 C54 1.392(14) . ?
C49 C50 1.394(13) . ?
C50 C51 1.393(16) . ?
C50 H50 0.9500 . ?
C51 C52 1.360(15) . ?
C51 H51 0.9500 . ?
C52 C53 1.393(17) . ?
C52 H52 0.9500 . ?
C53 C54 1.374(17) . ?
C53 H53 0.9500 . ?
C54 H54 0.9500 . ?
C55 C58 1.517(14) . ?
C55 C56 1.547(17) . ?
C55 C57 1.550(16) . ?
C56 H56A 0.9800 . ?
C56 H56B 0.9800 . ?
C56 H56C 0.9800 . ?
C57 H57A 0.9800 . ?
C57 H57B 0.9800 . ?
C57 H57C 0.9800 . ?
C58 H58A 0.9800 . ?
C58 H58B 0.9800 . ?
C58 H58C 0.9800 . ?
C59 C60 1.519(15) . ?
C59 C62 1.548(18) . ?
C59 C61 1.566(15) . ?
C60 H60A 0.9800 . ?
C60 H60B 0.9800 . ?
C60 H60C 0.9800 . ?
C61 H61A 0.9800 . ?
C61 H61B 0.9800 . ?
C61 H61C 0.9800 . ?
C62 H62A 0.9800 . ?
C62 H62B 0.9800 . ?
C62 H62C 0.9800 . ?
C63 C66 1.540(13) . ?
C63 C64 1.544(15) . ?
C63 C65 1.552(15) . ?
C64 H64A 0.9800 . ?
C64 H64B 0.9800 . ?
C64 H64C 0.9800 . ?
C65 H65A 0.9800 . ?
C65 H65B 0.9800 . ?
C65 H65C 0.9800 . ?
C66 H66A 0.9800 . ?
C66 H66B 0.9800 . ?
C66 H66C 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C14 Pt1 Re1 C12 -46.5(6) . . . . ?
P1 Pt1 Re1 C12 -0.3(5) . . . . ?
Sn1 Pt1 Re1 C12 -176.6(4) . . . . ?
C14 Pt1 Re1 C11 54.9(5) . . . . ?
P1 Pt1 Re1 C11 101.1(4) . . . . ?
Sn1 Pt1 Re1 C11 -75.1(3) . . . . ?
C14 Pt1 Re1 C13 -128.6(5) . . . . ?
P1 Pt1 Re1 C13 -82.4(4) . . . . ?
Sn1 Pt1 Re1 C13 101.4(3) . . . . ?
P1 Pt1 Re1 C14 46.2(5) . . . . ?
Sn1 Pt1 Re1 C14 -130.1(4) . . . . ?
C14 Pt1 Re1 Sn2 -170.3(4) . . . . ?
P1 Pt1 Re1 Sn2 -124.1(2) . . . . ?
Sn1 Pt1 Re1 Sn2 59.60(7) . . . . ?
C14 Pt1 Re1 Sn1 130.1(4) . . . . ?
P1 Pt1 Re1 Sn1 176.3(2) . . . . ?
C14 Pt1 Re1 Re2 150.7(4) . . . . ?
P1 Pt1 Re1 Re2 -163.1(2) . . . . ?
Sn1 Pt1 Re1 Re2 20.62(2) . . . . ?
C12 Re1 Re2 C23 -175.0(6) . . . . ?
C11 Re1 Re2 C23 96.3(5) . . . . ?
C13 Re1 Re2 C23 -83.0(5) . . . . ?
C14 Re1 Re2 C23 22.3(6) . . . . ?
Sn2 Re1 Re2 C23 -179.0(4) . . . . ?
Pt1 Re1 Re2 C23 -15.0(4) . . . . ?
Sn1 Re1 Re2 C23 6.5(4) . . . . ?
C12 Re1 Re2 C22 7.3(6) . . . . ?
C11 Re1 Re2 C22 -81.4(5) . . . . ?
C13 Re1 Re2 C22 99.3(5) . . . . ?
C14 Re1 Re2 C22 -155.4(6) . . . . ?
Sn2 Re1 Re2 C22 3.3(4) . . . . ?
Pt1 Re1 Re2 C22 167.3(4) . . . . ?
Sn1 Re1 Re2 C22 -171.2(4) . . . . ?
C12 Re1 Re2 C24 -84.2(5) . . . . ?
C11 Re1 Re2 C24 -172.9(4) . . . . ?
C13 Re1 Re2 C24 7.8(4) . . . . ?
C14 Re1 Re2 C24 113.1(6) . . . . ?
Sn2 Re1 Re2 C24 -88.2(3) . . . . ?
Pt1 Re1 Re2 C24 75.8(3) . . . . ?
Sn1 Re1 Re2 C24 97.3(3) . . . . ?
C12 Re1 Re2 C21 95.5(5) . . . . ?
C11 Re1 Re2 C21 6.9(4) . . . . ?
C13 Re1 Re2 C21 -172.4(4) . . . . ?
C14 Re1 Re2 C21 -67.1(5) . . . . ?
Sn2 Re1 Re2 C21 91.6(3) . . . . ?
Pt1 Re1 Re2 C21 -104.4(3) . . . . ?
Sn1 Re1 Re2 C21 -82.9(3) . . . . ?
C12 Re1 Re2 Sn2 3.9(4) . . . . ?
C11 Re1 Re2 Sn2 -84.7(3) . . . . ?
C13 Re1 Re2 Sn2 96.0(3) . . . . ?
C14 Re1 Re2 Sn2 -158.7(5) . . . . ?
Pt1 Re1 Re2 Sn2 164.03(3) . . . . ?
Sn1 Re1 Re2 Sn2 -174.49(3) . . . . ?
C12 Re1 Re2 Sn1 178.4(4) . . . . ?
C11 Re1 Re2 Sn1 89.8(3) . . . . ?
C13 Re1 Re2 Sn1 -89.5(3) . . . . ?
C14 Re1 Re2 Sn1 15.8(5) . . . . ?
Sn2 Re1 Re2 Sn1 174.49(3) . . . . ?
Pt1 Re1 Re2 Sn1 -21.48(2) . . . . ?
C14 Pt1 Sn1 C31 70.9(4) . . . . ?
P1 Pt1 Sn1 C31 -73.0(3) . . . . ?
Re1 Pt1 Sn1 C31 105.6(3) . . . . ?
C14 Pt1 Sn1 C37 179.4(4) . . . . ?
P1 Pt1 Sn1 C37 35.5(3) . . . . ?
Re1 Pt1 Sn1 C37 -145.9(3) . . . . ?
C14 Pt1 Sn1 Re1 -34.6(3) . . . . ?
P1 Pt1 Sn1 Re1 -178.53(10) . . . . ?
C14 Pt1 Sn1 Re2 -61.8(3) . . . . ?
P1 Pt1 Sn1 Re2 154.26(10) . . . . ?
Re1 Pt1 Sn1 Re2 -27.22(2) . . . . ?
C11 Re1 Sn1 C31 18.1(4) . . . . ?
C13 Re1 Sn1 C31 -164.2(4) . . . . ?
C14 Re1 Sn1 C31 -64.5(4) . . . . ?
Sn2 Re1 Sn1 C31 101.8(3) . . . . ?
Pt1 Re1 Sn1 C31 -97.1(3) . . . . ?
Re2 Re1 Sn1 C31 106.5(3) . . . . ?
C11 Re1 Sn1 C37 174.8(5) . . . . ?
C13 Re1 Sn1 C37 -7.4(5) . . . . ?
C14 Re1 Sn1 C37 92.2(5) . . . . ?
Sn2 Re1 Sn1 C37 -101.4(4) . . . . ?
Pt1 Re1 Sn1 C37 59.7(4) . . . . ?
Re2 Re1 Sn1 C37 -96.7(4) . . . . ?
C11 Re1 Sn1 Pt1 115.2(3) . . . . ?
C13 Re1 Sn1 Pt1 -67.1(3) . . . . ?
C14 Re1 Sn1 Pt1 32.6(3) . . . . ?
Sn2 Re1 Sn1 Pt1 -161.08(2) . . . . ?
Re2 Re1 Sn1 Pt1 -156.34(2) . . . . ?
C11 Re1 Sn1 Re2 -88.5(3) . . . . ?
C13 Re1 Sn1 Re2 89.3(3) . . . . ?
C14 Re1 Sn1 Re2 -171.1(3) . . . . ?
Sn2 Re1 Sn1 Re2 -4.73(2) . . . . ?
Pt1 Re1 Sn1 Re2 156.34(2) . . . . ?
C23 Re2 Sn1 C31 79.6(5) . . . . ?
C22 Re2 Sn1 C31 43.5(14) . . . . ?
C24 Re2 Sn1 C31 169.7(5) . . . . ?
C21 Re2 Sn1 C31 -11.7(4) . . . . ?
Sn2 Re2 Sn1 C31 -100.7(3) . . . . ?
Re1 Re2 Sn1 C31 -105.4(3) . . . . ?
C23 Re2 Sn1 C37 -38.0(5) . . . . ?
C22 Re2 Sn1 C37 -74.0(14) . . . . ?
C24 Re2 Sn1 C37 52.1(5) . . . . ?
C21 Re2 Sn1 C37 -129.3(4) . . . . ?
Sn2 Re2 Sn1 C37 141.7(3) . . . . ?
Re1 Re2 Sn1 C37 137.0(3) . . . . ?
C23 Re2 Sn1 Pt1 -149.9(3) . . . . ?
C22 Re2 Sn1 Pt1 174.1(14) . . . . ?
C24 Re2 Sn1 Pt1 -59.8(3) . . . . ?
C21 Re2 Sn1 Pt1 118.8(3) . . . . ?
Sn2 Re2 Sn1 Pt1 29.83(4) . . . . ?
Re1 Re2 Sn1 Pt1 25.10(2) . . . . ?
C23 Re2 Sn1 Re1 -175.0(3) . . . . ?
C22 Re2 Sn1 Re1 149.0(14) . . . . ?
C24 Re2 Sn1 Re1 -84.9(3) . . . . ?
C21 Re2 Sn1 Re1 93.7(3) . . . . ?
Sn2 Re2 Sn1 Re1 4.72(2) . . . . ?
C12 Re1 Sn2 C43 70.9(5) . . . . ?
C11 Re1 Sn2 C43 -20.7(5) . . . . ?
C13 Re1 Sn2 C43 162.3(5) . . . . ?
C14 Re1 Sn2 C43 37.8(8) . . . . ?
Pt1 Re1 Sn2 C43 -158.8(4) . . . . ?
Sn1 Re1 Sn2 C43 -107.4(4) . . . . ?
Re2 Re1 Sn2 C43 -112.2(4) . . . . ?
C12 Re1 Sn2 C49 -55.8(4) . . . . ?
C11 Re1 Sn2 C49 -147.4(4) . . . . ?
C13 Re1 Sn2 C49 35.6(4) . . . . ?
C14 Re1 Sn2 C49 -88.9(8) . . . . ?
Pt1 Re1 Sn2 C49 74.5(3) . . . . ?
Sn1 Re1 Sn2 C49 125.9(3) . . . . ?
Re2 Re1 Sn2 C49 121.1(3) . . . . ?
C12 Re1 Sn2 Re2 -176.9(3) . . . . ?
C11 Re1 Sn2 Re2 91.5(3) . . . . ?
C13 Re1 Sn2 Re2 -85.5(3) . . . . ?
C14 Re1 Sn2 Re2 150.0(7) . . . . ?
Pt1 Re1 Sn2 Re2 -46.62(7) . . . . ?
Sn1 Re1 Sn2 Re2 4.80(2) . . . . ?
C22 Re2 Sn2 C43 -63.3(4) . . . . ?
C24 Re2 Sn2 C43 -155.5(4) . . . . ?
C21 Re2 Sn2 C43 25.5(4) . . . . ?
Sn1 Re2 Sn2 C43 109.5(3) . . . . ?
Re1 Re2 Sn2 C43 114.3(3) . . . . ?
C22 Re2 Sn2 C49 68.3(4) . . . . ?
C24 Re2 Sn2 C49 -23.8(4) . . . . ?
C21 Re2 Sn2 C49 157.2(4) . . . . ?
Sn1 Re2 Sn2 C49 -118.8(3) . . . . ?
Re1 Re2 Sn2 C49 -114.0(3) . . . . ?
C22 Re2 Sn2 Re1 -177.6(3) . . . . ?
C24 Re2 Sn2 Re1 90.2(3) . . . . ?
C21 Re2 Sn2 Re1 -88.7(3) . . . . ?
Sn1 Re2 Sn2 Re1 -4.79(2) . . . . ?
C14 Pt1 P1 C59 144.4(6) . . . . ?
Sn1 Pt1 P1 C59 -78.4(4) . . . . ?
Re1 Pt1 P1 C59 106.3(5) . . . . ?
C14 Pt1 P1 C63 24.8(5) . . . . ?
Sn1 Pt1 P1 C63 162.0(4) . . . . ?
Re1 Pt1 P1 C63 -13.4(5) . . . . ?
C14 Pt1 P1 C55 -96.9(6) . . . . ?
Sn1 Pt1 P1 C55 40.3(4) . . . . ?
Re1 Pt1 P1 C55 -135.1(5) . . . . ?
P1 Pt1 C14 O14 16.5(12) . . . . ?
Sn1 Pt1 C14 O14 -134.7(10) . . . . ?
Re1 Pt1 C14 O14 -176.9(13) . . . . ?
P1 Pt1 C14 Re1 -166.56(14) . . . . ?
Sn1 Pt1 C14 Re1 42.2(3) . . . . ?
C12 Re1 C14 O14 -44.6(15) . . . . ?
C11 Re1 C14 O14 46.5(15) . . . . ?
C13 Re1 C14 O14 -136.0(15) . . . . ?
Sn2 Re1 C14 O14 -12(2) . . . . ?
Pt1 Re1 C14 O14 175.9(17) . . . . ?
Sn1 Re1 C14 O14 135.0(15) . . . . ?
Re2 Re1 C14 O14 122.0(13) . . . . ?
C12 Re1 C14 Pt1 139.6(4) . . . . ?
C11 Re1 C14 Pt1 -129.4(4) . . . . ?
C13 Re1 C14 Pt1 48.1(4) . . . . ?
Sn2 Re1 C14 Pt1 171.7(4) . . . . ?
Sn1 Re1 C14 Pt1 -40.9(3) . . . . ?
Re2 Re1 C14 Pt1 -53.8(6) . . . . ?
C37 Sn1 C31 C36 -123.6(8) . . . . ?
Pt1 Sn1 C31 C36 -22.8(9) . . . . ?
Re1 Sn1 C31 C36 41.0(9) . . . . ?
Re2 Sn1 C31 C36 116.6(8) . . . . ?
C37 Sn1 C31 C32 58.7(9) . . . . ?
Pt1 Sn1 C31 C32 159.5(7) . . . . ?
Re1 Sn1 C31 C32 -136.7(7) . . . . ?
Re2 Sn1 C31 C32 -61.1(8) . . . . ?
C36 C31 C32 C33 0.2(15) . . . . ?
Sn1 C31 C32 C33 178.0(7) . . . . ?
C31 C32 C33 C34 -1.6(15) . . . . ?
C32 C33 C34 C35 1.7(16) . . . . ?
C33 C34 C35 C36 -0.3(16) . . . . ?
C32 C31 C36 C35 1.1(15) . . . . ?
Sn1 C31 C36 C35 -176.5(7) . . . . ?
C34 C35 C36 C31 -1.1(15) . . . . ?
C31 Sn1 C37 C42 -169.2(9) . . . . ?
Pt1 Sn1 C37 C42 82.1(9) . . . . ?
Re1 Sn1 C37 C42 33.3(11) . . . . ?
Re2 Sn1 C37 C42 -47.9(9) . . . . ?
C31 Sn1 C37 C38 11.4(9) . . . . ?
Pt1 Sn1 C37 C38 -97.3(8) . . . . ?
Re1 Sn1 C37 C38 -146.1(6) . . . . ?
Re2 Sn1 C37 C38 132.7(7) . . . . ?
C42 C37 C38 C39 -2.1(15) . . . . ?
Sn1 C37 C38 C39 177.4(8) . . . . ?
C37 C38 C39 C40 1.1(16) . . . . ?
C38 C39 C40 C41 0.4(18) . . . . ?
C39 C40 C41 C42 -1.0(18) . . . . ?
C38 C37 C42 C41 1.5(16) . . . . ?
Sn1 C37 C42 C41 -177.9(8) . . . . ?
C40 C41 C42 C37 0.0(17) . . . . ?
C49 Sn2 C43 C48 86.1(10) . . . . ?
Re1 Sn2 C43 C48 -48.6(11) . . . . ?
Re2 Sn2 C43 C48 -132.3(9) . . . . ?
C49 Sn2 C43 C44 -87.3(9) . . . . ?
Re1 Sn2 C43 C44 138.1(8) . . . . ?
Re2 Sn2 C43 C44 54.4(10) . . . . ?
C48 C43 C44 C45 -1.3(17) . . . . ?
Sn2 C43 C44 C45 172.4(9) . . . . ?
C43 C44 C45 C46 2(2) . . . . ?
C44 C45 C46 C47 -2(2) . . . . ?
C45 C46 C47 C48 1(2) . . . . ?
C44 C43 C48 C47 0.6(18) . . . . ?
Sn2 C43 C48 C47 -172.9(9) . . . . ?
C46 C47 C48 C43 -0.5(19) . . . . ?
C43 Sn2 C49 C54 4.5(9) . . . . ?
Re1 Sn2 C49 C54 139.0(7) . . . . ?
Re2 Sn2 C49 C54 -133.1(7) . . . . ?
C43 Sn2 C49 C50 -176.3(8) . . . . ?
Re1 Sn2 C49 C50 -41.8(9) . . . . ?
Re2 Sn2 C49 C50 46.1(10) . . . . ?
C54 C49 C50 C51 -1.5(15) . . . . ?
Sn2 C49 C50 C51 179.3(7) . . . . ?
C49 C50 C51 C52 2.2(15) . . . . ?
C50 C51 C52 C53 -1.4(17) . . . . ?
C51 C52 C53 C54 -0.2(19) . . . . ?
C52 C53 C54 C49 0.9(19) . . . . ?
C50 C49 C54 C53 -0.1(17) . . . . ?
Sn2 C49 C54 C53 179.2(9) . . . . ?
C59 P1 C55 C58 -75.4(10) . . . . ?
C63 P1 C55 C58 44.8(10) . . . . ?
Pt1 P1 C55 C58 168.8(8) . . . . ?
C59 P1 C55 C56 46.9(9) . . . . ?
C63 P1 C55 C56 167.1(8) . . . . ?
Pt1 P1 C55 C56 -69.0(8) . . . . ?
C59 P1 C55 C57 161.6(8) . . . . ?
C63 P1 C55 C57 -78.2(9) . . . . ?
Pt1 P1 C55 C57 45.7(9) . . . . ?
C63 P1 C59 C60 160.7(8) . . . . ?
C55 P1 C59 C60 -80.1(10) . . . . ?
Pt1 P1 C59 C60 39.6(9) . . . . ?
C63 P1 C59 C62 45.6(9) . . . . ?
C55 P1 C59 C62 164.9(7) . . . . ?
Pt1 P1 C59 C62 -75.5(8) . . . . ?
C63 P1 C59 C61 -76.2(10) . . . . ?
C55 P1 C59 C61 43.0(11) . . . . ?
Pt1 P1 C59 C61 162.7(8) . . . . ?
C59 P1 C63 C66 44.7(10) . . . . ?
C55 P1 C63 C66 -75.2(9) . . . . ?
Pt1 P1 C63 C66 161.5(7) . . . . ?
C59 P1 C63 C64 166.8(7) . . . . ?
C55 P1 C63 C64 46.8(8) . . . . ?
Pt1 P1 C63 C64 -76.5(7) . . . . ?
C59 P1 C63 C65 -78.0(8) . . . . ?
C55 P1 C63 C65 162.0(7) . . . . ?
Pt1 P1 C63 C65 38.7(8) . . . . ?
