#------------------------------------------------------------------------------
#$Date: 2016-03-23 00:55:33 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179135 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/97/4309702.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4309702
loop_
_publ_author_name
'Jillian L. Dempsey'
'Arthur J. Esswein'
'David R. Manke'
'Joel Rosenthal'
'Jake D. Soper'
'Daniel G. Nocera'
_publ_contact_author             'Daniel G. Nocera'
_publ_contact_author_email       nocera@mit.edu
_publ_section_title
;
Molecular Chemistry of Consequence to Renewable Energy
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6879
_journal_page_last               6892
_journal_paper_doi               10.1021/ic0509276
_journal_volume                  44
_journal_year                    2005
_chemical_formula_sum            'C63 H68 Au Cl8 N2 P4 Rh'
_chemical_formula_weight         1560.55
_chemical_name_systematic        Au(dppm)Rh(CNtBu)2Cl2
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.00
_cell_angle_beta                 102.282(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   26.651(4)
_cell_length_b                   13.2594(18)
_cell_length_c                   18.991(3)
_cell_measurement_temperature    150(2)
_cell_volume                     6557.4(17)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0634
_diffrn_reflns_av_sigmaI/netI    0.0646
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            30738
_diffrn_reflns_theta_full        23.29
_diffrn_reflns_theta_max         23.29
_diffrn_reflns_theta_min         0.78
_exptl_absorpt_coefficient_mu    2.950
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.581
_exptl_crystal_density_meas      0
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             3120
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.12
_refine_diff_density_max         2.358
_refine_diff_density_min         -2.003
_refine_diff_density_rms         0.177
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.131
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     741
_refine_ls_number_reflns         9425
_refine_ls_number_restraints     685
_refine_ls_restrained_S_all      1.100
_refine_ls_R_factor_all          0.0844
_refine_ls_R_factor_gt           0.0683
_refine_ls_shift/su_max          0.068
_refine_ls_shift/su_mean         0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0563P)²+102.6659P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1595
_refine_ls_wR_factor_ref         0.1661
_reflns_number_gt                7705
_reflns_number_total             9425
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic0509276si20050608_033356_2.cif
_cod_data_source_block           comp2
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_cell_volume        6557.5(16)
_cod_database_code               4309702
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.290924(18) 1.06516(3) 1.03510(2) 0.02315(15) Uani 1 1 d U . .
Rh1 Rh 0.29098(3) 0.90740(5) 0.92774(4) 0.0133(2) Uani 1 1 d U . .
P1 P 0.24635(12) 0.9673(2) 1.10206(14) 0.0219(6) Uani 1 1 d U . .
P2 P 0.24778(11) 0.79618(19) 0.98769(14) 0.0192(6) Uani 1 1 d U . .
P3 P 0.33008(11) 1.17971(19) 0.97203(14) 0.0178(6) Uani 1 1 d U . .
P4 P 0.33327(11) 1.00897(19) 0.85932(13) 0.0166(6) Uani 1 1 d U . .
N1 N 0.1870(4) 1.0132(7) 0.8677(5) 0.035(2) Uani 1 1 d U . .
N2 N 0.3958(4) 0.8309(7) 1.0157(5) 0.030(2) Uani 1 1 d U . .
C1 C 0.2157(4) 0.8610(7) 1.0525(5) 0.0153(14) Uani 1 1 d U . .
H1A H 0.1816 0.8835 1.0257 0.018 Uiso 1 1 calc R . .
H1B H 0.2097 0.8101 1.0880 0.018 Uiso 1 1 calc R . .
C2 C 0.3640(4) 1.1194(7) 0.9098(5) 0.0153(14) Uani 1 1 d U . .
H2A H 0.3982 1.0982 0.9375 0.018 Uiso 1 1 calc R . .
H2B H 0.3698 1.1706 0.8745 0.018 Uiso 1 1 calc R . .
C3 C 0.1919(5) 1.0318(8) 1.1237(6) 0.027(2) Uani 1 1 d U . .
C4 C 0.1526(5) 0.9807(10) 1.1443(8) 0.049(3) Uani 1 1 d U . .
H4 H 0.1539 0.9092 1.1473 0.059 Uiso 1 1 calc R . .
C5 C 0.1105(6) 1.0312(12) 1.1611(10) 0.066(4) Uani 1 1 d U . .
H5 H 0.0832 0.9947 1.1742 0.079 Uiso 1 1 calc R . .
C6 C 0.1097(7) 1.1347(12) 1.1582(9) 0.066(4) Uani 1 1 d U . .
H6 H 0.0813 1.1704 1.1688 0.079 Uiso 1 1 calc R . .
C7 C 0.1496(7) 1.1870(11) 1.1401(9) 0.065(4) Uani 1 1 d U . .
H7 H 0.1497 1.2587 1.1407 0.078 Uiso 1 1 calc R . .
C8 C 0.1890(6) 1.1358(9) 1.1212(8) 0.051(4) Uani 1 1 d U . .
H8 H 0.2153 1.1727 1.1058 0.061 Uiso 1 1 calc R . .
C9 C 0.2853(4) 0.9309(7) 1.1886(6) 0.021(2) Uani 1 1 d U . .
C10 C 0.2681(4) 0.8593(8) 1.2327(6) 0.025(2) Uani 1 1 d U . .
H10 H 0.2370 0.8236 1.2155 0.031 Uiso 1 1 calc R . .
C11 C 0.2969(4) 0.8410(8) 1.3017(6) 0.026(2) Uani 1 1 d U . .
H11 H 0.2855 0.7926 1.3317 0.031 Uiso 1 1 calc R . .
C12 C 0.3415(5) 0.8928(8) 1.3263(6) 0.030(2) Uani 1 1 d U . .
H12 H 0.3606 0.8797 1.3736 0.036 Uiso 1 1 calc R . .
C13 C 0.3594(5) 0.9633(8) 1.2847(6) 0.033(3) Uani 1 1 d U . .
H13 H 0.3906 0.9983 1.3027 0.039 Uiso 1 1 calc R . .
C14 C 0.3307(4) 0.9825(8) 1.2150(6) 0.025(2) Uani 1 1 d U . .
H14 H 0.3424 1.0313 1.1857 0.030 Uiso 1 1 calc R . .
C15 C 0.2853(4) 0.6921(7) 1.0338(6) 0.021(2) Uani 1 1 d U . .
C16 C 0.3107(4) 0.6966(8) 1.1046(6) 0.027(2) Uani 1 1 d U . .
H16 H 0.3080 0.7559 1.1317 0.032 Uiso 1 1 calc R . .
C17 C 0.3399(4) 0.6178(9) 1.1373(6) 0.030(3) Uani 1 1 d U . .
H17 H 0.3572 0.6224 1.1864 0.036 Uiso 1 1 calc R . .
C18 C 0.3439(5) 0.5310(9) 1.0980(7) 0.034(3) Uani 1 1 d U . .
H18 H 0.3637 0.4756 1.1202 0.041 Uiso 1 1 calc R . .
C19 C 0.3194(5) 0.5257(8) 1.0277(7) 0.036(3) Uani 1 1 d U . .
H19 H 0.3226 0.4665 1.0008 0.043 Uiso 1 1 calc R . .
C20 C 0.2897(5) 0.6050(8) 0.9944(6) 0.030(3) Uani 1 1 d U . .
H20 H 0.2726 0.6002 0.9453 0.036 Uiso 1 1 calc R . .
C21 C 0.1951(4) 0.7306(7) 0.9328(5) 0.020(2) Uani 1 1 d U . .
C22 C 0.1644(5) 0.6635(9) 0.9654(7) 0.037(3) Uani 1 1 d U . .
H22 H 0.1717 0.6566 1.0164 0.044 Uiso 1 1 calc R . .
C23 C 0.1256(6) 0.6100(11) 0.9255(8) 0.053(4) Uani 1 1 d U . .
H23 H 0.1066 0.5647 0.9486 0.064 Uiso 1 1 calc R . .
C24 C 0.1132(5) 0.6202(10) 0.8515(8) 0.049(3) Uani 1 1 d U . .
H24 H 0.0857 0.5822 0.8237 0.058 Uiso 1 1 calc R . .
C25 C 0.1405(5) 0.6853(10) 0.8184(7) 0.038(3) Uani 1 1 d U . .
H25 H 0.1316 0.6927 0.7675 0.046 Uiso 1 1 calc R . .
C26 C 0.1810(4) 0.7407(8) 0.8578(6) 0.026(2) Uani 1 1 d U . .
H26 H 0.1993 0.7860 0.8337 0.031 Uiso 1 1 calc R . .
C27 C 0.3800(4) 1.2571(7) 1.0252(5) 0.019(2) Uani 1 1 d U . .
C28 C 0.3942(4) 1.2495(8) 1.1003(5) 0.022(2) Uani 1 1 d U . .
H28 H 0.3771 1.2023 1.1247 0.026 Uiso 1 1 calc R . .
C29 C 0.4327(5) 1.3098(8) 1.1397(6) 0.029(2) Uani 1 1 d U . .
H29 H 0.4422 1.3036 1.1907 0.035 Uiso 1 1 calc R . .
C30 C 0.4569(5) 1.3782(9) 1.1044(6) 0.033(3) Uani 1 1 d U . .
H30 H 0.4833 1.4195 1.1312 0.039 Uiso 1 1 calc R . .
C31 C 0.4436(5) 1.3884(8) 1.0311(6) 0.029(2) Uani 1 1 d U . .
H31 H 0.4608 1.4367 1.0078 0.035 Uiso 1 1 calc R . .
C32 C 0.4052(5) 1.3284(8) 0.9902(6) 0.027(2) Uani 1 1 d U . .
H32 H 0.3961 1.3357 0.9393 0.032 Uiso 1 1 calc R . .
C33 C 0.2831(4) 1.2683(7) 0.9223(5) 0.018(2) Uani 1 1 d U . .
C34 C 0.2393(5) 1.2885(8) 0.9507(6) 0.030(3) Uani 1 1 d U . .
H34 H 0.2340 1.2518 0.9914 0.036 Uiso 1 1 calc R . .
C35 C 0.2047(5) 1.3598(10) 0.9204(7) 0.038(3) Uani 1 1 d U . .
H35 H 0.1756 1.3740 0.9402 0.045 Uiso 1 1 calc R . .
C36 C 0.2127(5) 1.4124(9) 0.8593(7) 0.040(3) Uani 1 1 d U . .
H36 H 0.1889 1.4627 0.8376 0.048 Uiso 1 1 calc R . .
C37 C 0.2549(5) 1.3909(9) 0.8309(6) 0.034(3) Uani 1 1 d U . .
H37 H 0.2597 1.4262 0.7893 0.041 Uiso 1 1 calc R . .
C38 C 0.2900(5) 1.3196(8) 0.8614(6) 0.029(3) Uani 1 1 d U . .
H38 H 0.3189 1.3055 0.8411 0.035 Uiso 1 1 calc R . .
C39 C 0.2951(4) 1.0506(7) 0.7733(5) 0.018(2) Uani 1 1 d U . .
C40 C 0.3076(4) 1.1366(8) 0.7381(6) 0.025(2) Uani 1 1 d U . .
H40 H 0.3350 1.1787 0.7611 0.030 Uiso 1 1 calc R . .
C41 C 0.2804(5) 1.1608(9) 0.6703(6) 0.033(3) Uani 1 1 d U . .
H41 H 0.2886 1.2200 0.6469 0.040 Uiso 1 1 calc R . .
C42 C 0.2406(5) 1.0981(10) 0.6362(6) 0.037(3) Uani 1 1 d U . .
H42 H 0.2213 1.1154 0.5897 0.045 Uiso 1 1 calc R . .
C43 C 0.2292(5) 1.0114(9) 0.6693(6) 0.032(3) Uani 1 1 d U . .
H43 H 0.2027 0.9681 0.6454 0.038 Uiso 1 1 calc R . .
C44 C 0.2566(4) 0.9876(8) 0.7376(5) 0.023(2) Uani 1 1 d U . .
H44 H 0.2489 0.9274 0.7603 0.028 Uiso 1 1 calc R . .
C45 C 0.3889(4) 0.9539(7) 0.8324(5) 0.0156(19) Uani 1 1 d U . .
C46 C 0.4234(4) 1.0142(8) 0.8050(6) 0.025(2) Uani 1 1 d U . .
H46 H 0.4190 1.0854 0.8031 0.030 Uiso 1 1 calc R . .
C47 C 0.4632(4) 0.9717(9) 0.7809(6) 0.026(2) Uani 1 1 d U . .
H47 H 0.4865 1.0135 0.7628 0.032 Uiso 1 1 calc R . .
C48 C 0.4699(5) 0.8685(9) 0.7828(6) 0.032(3) Uani 1 1 d U . .
H48 H 0.4976 0.8398 0.7654 0.038 Uiso 1 1 calc R . .
C49 C 0.4368(5) 0.8067(8) 0.8096(6) 0.031(3) Uani 1 1 d U . .
H49 H 0.4417 0.7357 0.8114 0.038 Uiso 1 1 calc R . .
C50 C 0.3962(4) 0.8502(8) 0.8338(6) 0.024(2) Uani 1 1 d U . .
H50 H 0.3729 0.8082 0.8517 0.029 Uiso 1 1 calc R . .
C51 C 0.2247(5) 0.9723(8) 0.8858(6) 0.026(2) Uani 1 1 d U . .
C52 C 0.1380(5) 1.0634(10) 0.8427(8) 0.049(3) Uani 1 1 d U . .
C53 C 0.1483(7) 1.1449(13) 0.7881(9) 0.074(5) Uani 1 1 d U . .
H53A H 0.1172 1.1852 0.7716 0.110 Uiso 1 1 calc R . .
H53B H 0.1578 1.1116 0.7467 0.110 Uiso 1 1 calc R . .
H53C H 0.1764 1.1889 0.8117 0.110 Uiso 1 1 calc R . .
C54 C 0.1027(6) 0.9829(14) 0.8043(11) 0.085(6) Uani 1 1 d U . .
H54A H 0.0954 0.9340 0.8395 0.127 Uiso 1 1 calc R . .
H54B H 0.1191 0.9485 0.7695 0.127 Uiso 1 1 calc R . .
H54C H 0.0705 1.0139 0.7790 0.127 Uiso 1 1 calc R . .
C55 C 0.1215(6) 1.1117(10) 0.9040(8) 0.059(4) Uani 1 1 d U . .
H55A H 0.1152 1.0598 0.9378 0.089 Uiso 1 1 calc R . .
H55B H 0.0898 1.1500 0.8863 0.089 Uiso 1 1 calc R . .
H55C H 0.1485 1.1575 0.9286 0.089 Uiso 1 1 calc R . .
C56 C 0.3564(4) 0.8570(8) 0.9807(6) 0.021(2) Uani 1 1 d U . .
C57 C 0.4451(4) 0.7987(9) 1.0585(6) 0.030(2) Uani 1 1 d U . .
C58 C 0.4877(5) 0.8570(11) 1.0312(8) 0.048(3) Uani 1 1 d U . .
H58A H 0.5215 0.8327 1.0566 0.072 Uiso 1 1 calc R . .
H58B H 0.4848 0.9292 1.0405 0.072 Uiso 1 1 calc R . .
H58C H 0.4839 0.8458 0.9793 0.072 Uiso 1 1 calc R . .
C59 C 0.4493(5) 0.6858(9) 1.0485(8) 0.043(3) Uani 1 1 d U . .
H59A H 0.4201 0.6520 1.0624 0.065 Uiso 1 1 calc R . .
H59B H 0.4814 0.6612 1.0789 0.065 Uiso 1 1 calc R . .
H59C H 0.4491 0.6711 0.9979 0.065 Uiso 1 1 calc R . .
C60 C 0.4452(5) 0.8263(10) 1.1373(7) 0.042(3) Uani 1 1 d U . .
H60A H 0.4165 0.7923 1.1523 0.063 Uiso 1 1 calc R . .
H60B H 0.4414 0.8995 1.1414 0.063 Uiso 1 1 calc R . .
H60C H 0.4776 0.8047 1.1683 0.063 Uiso 1 1 calc R . .
Cl1 Cl 0.57931(11) 0.7977(2) 0.69227(14) 0.0277(6) Uani 1 1 d . . .
Cl2 Cl 0.14316(16) 0.8000(2) 0.6499(2) 0.0531(10) Uani 1 1 d . . .
C1A C 0.0183(14) 0.789(3) 0.702(3) 0.190(13) Uani 0.711(18) 1 d PDU A 1
H1AA H 0.0425 0.8067 0.7471 0.228 Uiso 0.711(18) 1 calc PR A 1
H1AB H 0.0357 0.8067 0.6620 0.228 Uiso 0.711(18) 1 calc PR A 1
Cl1A Cl 0.0110(3) 0.6639(7) 0.7005(7) 0.127(5) Uani 0.711(18) 1 d PDU A 1
Cl2A Cl -0.0323(4) 0.8669(8) 0.6942(8) 0.229(5) Uani 0.711(18) 1 d PDU A 1
C1B C 0.0216(18) 0.803(7) 0.729(8) 0.212(17) Uani 0.289(18) 1 d PDU A 2
H1BA H 0.0371 0.7743 0.6908 0.255 Uiso 0.289(18) 1 calc PR A 2
H1BB H 0.0470 0.8472 0.7603 0.255 Uiso 0.289(18) 1 calc PR A 2
Cl1B Cl 0.0017(12) 0.712(3) 0.778(3) 0.214(15) Uani 0.289(18) 1 d PDU A 2
Cl2B Cl -0.0323(4) 0.8669(8) 0.6942(8) 0.229(5) Uani 0.289(18) 1 d PDU A 2
Cl1C Cl 0.0604(6) 0.8639(11) -0.0531(7) 0.253(6) Uani 0.54(2) 1 d PDU B 1
C1C C 0.0458(13) 0.814(2) 0.013(2) 0.197(8) Uani 0.54(2) 1 d PDU B 1
H1CA H 0.0417 0.8690 0.0472 0.236 Uiso 0.54(2) 1 calc PR B 1
H1CB H 0.0753 0.7728 0.0374 0.236 Uiso 0.54(2) 1 calc PR B 1
Cl2C Cl -0.0046(7) 0.7448(19) 0.0024(13) 0.220(13) Uani 0.54(2) 1 d PDU B 1
Cl1D Cl 0.0604(6) 0.8639(11) -0.0531(7) 0.253(6) Uani 0.46(2) 1 d PDU B 2
C1D C 0.0458(13) 0.814(2) 0.013(2) 0.197(8) Uani 0.46(2) 1 d PDU B 2
H1DA H 0.0762 0.8140 0.0536 0.236 Uiso 0.46(2) 1 calc PR B 2
H1DB H 0.0356 0.7435 0.0017 0.236 Uiso 0.46(2) 1 calc PR B 2
Cl2D Cl -0.0005(9) 0.872(3) 0.0382(15) 0.241(14) Uani 0.46(2) 1 d PDU B 2
C1E C 0.0642(13) 0.492(3) 0.0816(16) 0.197(13) Uani 1 1 d U . .
H1E1 H 0.0902 0.5293 0.1171 0.236 Uiso 1 1 calc R . .
H1E2 H 0.0450 0.5416 0.0470 0.236 Uiso 1 1 calc R . .
Cl1E Cl 0.0242(4) 0.4343(12) 0.1235(6) 0.267(8) Uani 1 1 d U . .
Cl2E Cl 0.0950(4) 0.4055(7) 0.0354(6) 0.196(5) Uani 1 1 d U . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Au1 P3 173.01(10) . . ?
P1 Au1 Rh1 93.35(7) . . ?
P3 Au1 Rh1 92.37(7) . . ?
C56 Rh1 C51 171.6(4) . . ?
C56 Rh1 P2 90.7(3) . . ?
C51 Rh1 P2 88.9(3) . . ?
C56 Rh1 P4 90.0(3) . . ?
C51 Rh1 P4 91.2(3) . . ?
P2 Rh1 P4 174.99(10) . . ?
C56 Rh1 Au1 91.1(3) . . ?
C51 Rh1 Au1 80.6(3) . . ?
P2 Rh1 Au1 92.22(7) . . ?
P4 Rh1 Au1 92.73(7) . . ?
C1 P1 C3 101.1(5) . . ?
C1 P1 C9 112.1(5) . . ?
C3 P1 C9 104.7(5) . . ?
C1 P1 Au1 112.5(3) . . ?
C3 P1 Au1 113.0(4) . . ?
C9 P1 Au1 112.7(4) . . ?
C21 P2 C15 101.3(5) . . ?
C21 P2 C1 101.4(5) . . ?
C15 P2 C1 108.4(5) . . ?
C21 P2 Rh1 115.7(3) . . ?
C15 P2 Rh1 116.2(4) . . ?
C1 P2 Rh1 112.3(3) . . ?
C27 P3 C2 101.8(5) . . ?
C27 P3 C33 105.4(5) . . ?
C2 P3 C33 109.2(5) . . ?
C27 P3 Au1 116.3(3) . . ?
C2 P3 Au1 112.9(3) . . ?
C33 P3 Au1 110.7(3) . . ?
C39 P4 C45 101.7(5) . . ?
C39 P4 C2 109.2(5) . . ?
C45 P4 C2 99.6(5) . . ?
C39 P4 Rh1 115.7(4) . . ?
C45 P4 Rh1 116.5(3) . . ?
C2 P4 Rh1 112.6(3) . . ?
C51 N1 C52 178.2(13) . . ?
C56 N2 C57 179.3(11) . . ?
P1 C1 P2 119.4(5) . . ?
P3 C2 P4 117.4(5) . . ?
C4 C3 C8 117.5(12) . . ?
C4 C3 P1 122.0(9) . . ?
C8 C3 P1 120.4(10) . . ?
C3 C4 C5 121.7(13) . . ?
C6 C5 C4 118.5(14) . . ?
C7 C6 C5 120.5(14) . . ?
C8 C7 C6 119.8(14) . . ?
C7 C8 C3 122.0(14) . . ?
C14 C9 C10 119.1(10) . . ?
C14 C9 P1 119.0(8) . . ?
C10 C9 P1 121.5(8) . . ?
C11 C10 C9 119.6(11) . . ?
C12 C11 C10 120.0(10) . . ?
C11 C12 C13 121.9(11) . . ?
C12 C13 C14 118.6(11) . . ?
C9 C14 C13 120.7(10) . . ?
C16 C15 C20 118.7(10) . . ?
C16 C15 P2 123.1(8) . . ?
C20 C15 P2 118.2(8) . . ?
C17 C16 C15 121.6(11) . . ?
C16 C17 C18 119.4(11) . . ?
C19 C18 C17 119.7(11) . . ?
C18 C19 C20 121.1(11) . . ?
C19 C20 C15 119.4(11) . . ?
C26 C21 C22 116.4(10) . . ?
C26 C21 P2 123.8(8) . . ?
C22 C21 P2 119.9(8) . . ?
C23 C22 C21 121.6(12) . . ?
C22 C23 C24 120.7(13) . . ?
C25 C24 C23 119.6(12) . . ?
C24 C25 C26 121.1(12) . . ?
C25 C26 C21 120.6(11) . . ?
C28 C27 C32 118.6(10) . . ?
C28 C27 P3 122.3(8) . . ?
C32 C27 P3 119.1(8) . . ?
C29 C28 C27 121.0(10) . . ?
C30 C29 C28 119.3(10) . . ?
C29 C30 C31 121.2(11) . . ?
C30 C31 C32 120.7(11) . . ?
C31 C32 C27 119.2(10) . . ?
C38 C33 C34 119.6(10) . . ?
C38 C33 P3 123.2(8) . . ?
C34 C33 P3 117.2(8) . . ?
C35 C34 C33 120.8(11) . . ?
C34 C35 C36 119.0(12) . . ?
C37 C36 C35 120.0(11) . . ?
C38 C37 C36 121.2(11) . . ?
C37 C38 C33 119.4(11) . . ?
C44 C39 C40 119.0(9) . . ?
C44 C39 P4 118.2(8) . . ?
C40 C39 P4 122.3(8) . . ?
C41 C40 C39 120.5(11) . . ?
C40 C41 C42 119.6(11) . . ?
C43 C42 C41 120.3(11) . . ?
C42 C43 C44 119.8(11) . . ?
C39 C44 C43 120.7(10) . . ?
C50 C45 C46 118.3(10) . . ?
C50 C45 P4 120.6(8) . . ?
C46 C45 P4 120.9(8) . . ?
C47 C46 C45 120.5(10) . . ?
C46 C47 C48 120.5(11) . . ?
C49 C48 C47 120.6(11) . . ?
C48 C49 C50 118.8(11) . . ?
C45 C50 C49 121.3(10) . . ?
N1 C51 Rh1 173.8(10) . . ?
N1 C52 C55 109.9(12) . . ?
N1 C52 C54 105.1(11) . . ?
C55 C52 C54 115.4(15) . . ?
N1 C52 C53 105.1(12) . . ?
C55 C52 C53 110.4(12) . . ?
C54 C52 C53 110.4(14) . . ?
N2 C56 Rh1 176.1(10) . . ?
N2 C57 C59 107.6(10) . . ?
N2 C57 C60 106.8(10) . . ?
C59 C57 C60 111.8(11) . . ?
N2 C57 C58 107.9(10) . . ?
C59 C57 C58 111.7(11) . . ?
C60 C57 C58 110.9(10) . . ?
Cl2A C1A Cl1A 121(2) . . ?
Cl1C C1C Cl2C 119(3) . . ?
Cl1E C1E Cl2E 111(2) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P1 2.314(3) . ?
Au1 P3 2.316(3) . ?
Au1 Rh1 2.9214(9) . ?
Rh1 C56 1.937(11) . ?
Rh1 C51 1.975(12) . ?
Rh1 P2 2.314(3) . ?
Rh1 P4 2.323(3) . ?
P1 C1 1.792(10) . ?
P1 C3 1.806(11) . ?
P1 C9 1.812(11) . ?
P2 C21 1.786(11) . ?
P2 C15 1.815(10) . ?
P2 C1 1.853(9) . ?
P3 C27 1.809(10) . ?
P3 C2 1.819(9) . ?
P3 C33 1.827(10) . ?
P4 C39 1.816(10) . ?
P4 C45 1.822(10) . ?
P4 C2 1.844(10) . ?
N1 C51 1.128(14) . ?
N1 C52 1.452(16) . ?
N2 C56 1.170(14) . ?
N2 C57 1.452(15) . ?
C3 C4 1.373(17) . ?
C3 C8 1.382(17) . ?
C4 C5 1.399(19) . ?
C5 C6 1.37(2) . ?
C6 C7 1.37(2) . ?
C7 C8 1.36(2) . ?
C9 C14 1.387(15) . ?
C9 C10 1.406(15) . ?
C10 C11 1.393(15) . ?
C11 C12 1.365(16) . ?
C12 C13 1.374(16) . ?
C13 C14 1.403(16) . ?
C15 C16 1.374(15) . ?
C15 C20 1.394(15) . ?
C16 C17 1.370(16) . ?
C17 C18 1.388(17) . ?
C18 C19 1.358(17) . ?
C19 C20 1.384(17) . ?
C21 C26 1.399(15) . ?
C21 C22 1.436(15) . ?
C22 C23 1.347(18) . ?
C23 C24 1.38(2) . ?
C24 C25 1.366(19) . ?
C25 C26 1.386(16) . ?
C27 C28 1.400(14) . ?
C27 C32 1.405(15) . ?
C28 C29 1.388(16) . ?
C29 C30 1.369(17) . ?
C30 C31 1.368(16) . ?
C31 C32 1.395(16) . ?
C33 C38 1.388(15) . ?
C33 C34 1.410(15) . ?
C34 C35 1.360(16) . ?
C35 C36 1.409(18) . ?
C36 C37 1.377(18) . ?
C37 C38 1.370(16) . ?
C39 C44 1.383(15) . ?
C39 C40 1.398(14) . ?
C40 C41 1.373(15) . ?
C41 C42 1.393(17) . ?
C42 C43 1.375(17) . ?
C43 C44 1.383(15) . ?
C45 C50 1.387(14) . ?
C45 C46 1.398(14) . ?
C46 C47 1.363(15) . ?
C47 C48 1.379(17) . ?
C48 C49 1.378(17) . ?
C49 C50 1.390(16) . ?
C52 C55 1.477(19) . ?
C52 C54 1.51(2) . ?
C52 C53 1.56(2) . ?
C57 C59 1.517(17) . ?
C57 C60 1.540(17) . ?
C57 C58 1.552(17) . ?
C1A Cl2A 1.68(3) . ?
C1A Cl1A 1.68(4) . ?
C1B Cl1B 1.67(4) . ?
Cl1C C1C 1.54(3) . ?
C1C Cl2C 1.61(3) . ?
C1E Cl1E 1.65(3) . ?
C1E Cl2E 1.75(3) . ?
