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Information card for entry 4310005
Preview
| Coordinates | 4310005.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C44 H42 O8 P2 Rh2 |
|---|---|
| Calculated formula | C44 H42 O8 P2 Rh2 |
| SMILES | [Rh]1234([Rh]([P](c5c4cccc5)(c4ccccc4)c4ccccc4)([O]=C(O2)C)(OC(=[O]3)C)([O]=C(O)C)c2c([P]1(c1ccccc1)c1ccccc1)cccc2)[O]=C(O)C |
| Title of publication | Chiral Organometallic Triangles with Rh-Rh Bonds. 2. Compounds Prepared from Enantiopure cis-Rh2(C6H4PPh2)2(OAc)2(HOAc)2 and Their Catalytic Potentials |
| Authors of publication | F. Albert Cotton; Carlos A. Murillo; Salah E. Stiriba; Xiaoping Wang; Rongmin Yu |
| Journal of publication | Inorganic Chemistry |
| Year of publication | 2005 |
| Journal volume | 44 |
| Pages of publication | 8223 - 8233 |
| a | 10.667 ± 0.003 Å |
| b | 15.152 ± 0.004 Å |
| c | 25.053 ± 0.006 Å |
| α | 90° |
| β | 90° |
| γ | 90° |
| Cell volume | 4049.2 ± 1.8 Å3 |
| Cell temperature | 213 ± 2 K |
| Ambient diffraction temperature | 213 ± 2 K |
| Number of distinct elements | 5 |
| Space group number | 19 |
| Hermann-Mauguin space group symbol | P 21 21 21 |
| Hall space group symbol | P 2ac 2ab |
| Residual factor for all reflections | 0.0198 |
| Residual factor for significantly intense reflections | 0.0184 |
| Weighted residual factors for significantly intense reflections | 0.0456 |
| Weighted residual factors for all reflections included in the refinement | 0.0466 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.073 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 179139 (current) | 2016-03-23 | cif/4/31/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/31/00. |
4310005.cif |
| 120093 | 2014-07-12 | Adding DOIs to range 4/31 structures. | 4310005.cif |
| 34330 | 2012-02-24 | cif/4/ Reorganising CIF range 4 into a prefix tree. |
4310005.cif |
| 1526 | 2010-09-26 | cif/4/ Adding new CIFs from Inorg. Chem. 2005 deposited via Web deposition site to the COD test database (and transferede to the main COD database after renaming). |
4310005.cif |
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Users of the data should acknowledge the original authors of the
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