Crystallography Open Database

Information card for entry 4310461

Preview

Coordinates	4310461.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C32 H48 O12 P4 Rh4
Calculated formula	C32 H48 O12 P4 Rh4
SMILES	[CH]12CC[CH]3[Rh]451([O]=P16O[Rh]789([CH]%10=[CH]7CC[CH]8=[CH]9CC%10)[O]=P7(O[Rh]89%10([CH]%11=[CH]8CC[CH]9=[CH]%10CC%11)[O]=P8(O[Rh]9%10%11([CH]%12=[CH]9CC[CH]%10=[CH]%11CC%12)[O]=P(O5)(O1)O8)O7)O6)[CH]=2CC[CH]=34
Title of publication	Synthesis and Characterization of Cyclotetraphosphato Complexes of Rh(I), Ir(I), Ru(II), and Pd(II)
Authors of publication	Sou Kamimura; Shigeki Kuwata; Masakazu Iwasaki; Youichi Ishii
Journal of publication	Inorganic Chemistry
Year of publication	2004
Journal volume	43
Pages of publication	399 - 401
a	16.451 ± 0.003 Å
b	17.487 ± 0.004 Å
c	15.173 ± 0.004 Å
α	90°
β	121.43 ± 0.01°
γ	90°
Cell volume	3724.5 ± 1.5 Å³
Cell temperature	294.2 K
Number of distinct elements	5
Space group number	15
Hermann-Mauguin space group symbol	C 1 2/c 1
Hall space group symbol	-C 2yc
Residual factor for significantly intense reflections	0.0302
Weighted residual factors for all reflections included in the refinement	0.0304
Goodness-of-fit parameter for all reflections included in the refinement	1.282
Diffraction radiation wavelength	0.7107 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
176467 (current)	2016-02-16	cif/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in range 4.	4310461.cif
120093	2014-07-12	Adding DOIs to range 4/31 structures.	4310461.cif
34330	2012-02-24	cif/4/ Reorganising CIF range 4 into a prefix tree.	4310461.cif
1949	2010-11-07	../uploads/cif-deposit/cod/cif Adding structures of 4310461 via cif-deposit CGI script.	4310461.cif