#------------------------------------------------------------------------------
#$Date: 2016-03-23 01:31:04 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179144 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/05/4310574.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4310574
loop_
_publ_author_name
'Kevin K. Klausmeyer'
'Rodney P. Feazell'
'Joseph H. Reibenspies'
_publ_section_title
;
 Two-, Three-, and Four-Coordinate Ag(I) Coordination Polymers Formed by
 the Novel Phosphinite PPh2(3-OCH2C5H4N)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1130
_journal_page_last               1136
_journal_paper_doi               10.1021/ic035168a
_journal_volume                  43
_journal_year                    2004
_chemical_formula_sum            'C40 H32 Ag2 F6 N2 O6 P2'
_chemical_formula_weight         1028.36
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                96.721(2)
_cell_angle_beta                 95.492(2)
_cell_angle_gamma                105.485(2)
_cell_formula_units_Z            2
_cell_length_a                   8.9906(14)
_cell_length_b                   9.1032(14)
_cell_length_c                   25.965(4)
_cell_measurement_reflns_used    9171
_cell_measurement_temperature    383(2)
_cell_measurement_theta_max      56.15
_cell_measurement_theta_min      4.15
_cell_volume                     2015.9(5)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      383(2)
_diffrn_measured_fraction_theta_full 0.958
_diffrn_measured_fraction_theta_max 0.958
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0358
_diffrn_reflns_av_sigmaI/netI    0.0428
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            27968
_diffrn_reflns_theta_full        27.61
_diffrn_reflns_theta_max         27.61
_diffrn_reflns_theta_min         0.80
_exptl_absorpt_coefficient_mu    1.127
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.694
_exptl_crystal_density_meas      0
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             1024
_exptl_crystal_size_max          .26
_exptl_crystal_size_mid          .22
_exptl_crystal_size_min          .15
_refine_diff_density_max         2.177
_refine_diff_density_min         -2.382
_refine_diff_density_rms         0.141
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.105
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     546
_refine_ls_number_reflns         8965
_refine_ls_number_restraints     125
_refine_ls_restrained_S_all      1.159
_refine_ls_R_factor_all          0.0567
_refine_ls_R_factor_gt           0.0531
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0164P)²+16.1014P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1260
_refine_ls_wR_factor_ref         0.1278
_reflns_number_gt                8222
_reflns_number_total             8965
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic035168asi20031008_035131_3.cif
_cod_data_source_block           kk14
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4310574
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.06134(4) 0.71165(4) 0.034142(15) 0.02088(10) Uani 1 1 d . . .
Ag2 Ag 0.78211(4) 0.92750(4) 0.466414(14) 0.02081(10) Uani 1 1 d . . .
P2 P 0.71940(14) 0.95523(14) 0.37806(5) 0.0169(2) Uani 1 1 d . . .
P1 P 0.03859(14) 0.79282(14) 0.12184(5) 0.0169(2) Uani 1 1 d . . .
O1 O -0.0795(4) 0.9000(4) 0.12977(14) 0.0192(7) Uani 1 1 d . . .
O2 O 0.1528(4) 0.4698(4) 0.01982(15) 0.0258(8) Uani 1 1 d . . .
O3 O 0.2101(5) 0.2600(4) 0.04434(17) 0.0331(9) Uani 1 1 d . A .
O4 O 0.6205(4) 1.0801(4) 0.36907(14) 0.0206(7) Uani 1 1 d . . .
O5 O 1.0325(4) 0.8448(4) 0.48406(15) 0.0247(8) Uani 1 1 d . . .
O6 O 1.2461(5) 0.7958(5) 0.45546(17) 0.0348(10) Uani 1 1 d . B .
N1 N -0.2098(5) 1.1781(5) 0.02461(17) 0.0211(9) Uani 1 1 d . . .
N2 N 0.3355(5) 1.2147(5) 0.47523(17) 0.0227(9) Uani 1 1 d . . .
C1 C -0.2341(6) 0.8434(6) 0.0995(2) 0.0227(10) Uani 1 1 d . . .
H1B H -0.3098 0.7998 0.1217 0.027 Uiso 1 1 calc R . .
H1C H -0.2347 0.7632 0.0713 0.027 Uiso 1 1 calc R . .
C2 C -0.2766(6) 0.9738(6) 0.0773(2) 0.0194(10) Uani 1 1 d . . .
C3 C -0.1788(6) 1.0606(6) 0.0465(2) 0.0206(10) Uani 1 1 d . . .
H3A H -0.0873 1.0359 0.0407 0.025 Uiso 1 1 calc R . .
C4 C -0.3457(6) 1.2114(6) 0.03267(19) 0.0222(10) Uani 1 1 d . . .
H4A H -0.3687 1.2926 0.0180 0.027 Uiso 1 1 calc R . .
C5 C -0.4501(6) 1.1296(6) 0.0616(2) 0.0242(11) Uani 1 1 d . . .
H5A H -0.5427 1.1540 0.0658 0.029 Uiso 1 1 calc R . .
C6 C -0.4156(6) 1.0098(6) 0.0847(2) 0.0207(10) Uani 1 1 d . . .
H6A H -0.4843 0.9543 0.1048 0.025 Uiso 1 1 calc R . .
C7 C -0.0218(6) 0.6384(6) 0.1605(2) 0.0219(10) Uani 1 1 d . . .
C8 C -0.0516(8) 0.4858(7) 0.1367(3) 0.0352(14) Uani 1 1 d . . .
H8A H -0.0432 0.4646 0.1014 0.042 Uiso 1 1 calc R . .
C9 C -0.0935(9) 0.3660(7) 0.1654(3) 0.0467(18) Uani 1 1 d . . .
H9A H -0.1131 0.2647 0.1494 0.056 Uiso 1 1 calc R . .
C10 C -0.1062(7) 0.3968(7) 0.2180(3) 0.0393(15) Uani 1 1 d . . .
H10A H -0.1339 0.3159 0.2372 0.047 Uiso 1 1 calc R . .
C11 C -0.0778(7) 0.5474(7) 0.2423(2) 0.0317(13) Uani 1 1 d . . .
H11A H -0.0865 0.5675 0.2776 0.038 Uiso 1 1 calc R . .
C12 C -0.0364(7) 0.6683(7) 0.2136(2) 0.0283(12) Uani 1 1 d . . .
H12A H -0.0183 0.7693 0.2298 0.034 Uiso 1 1 calc R . .
C13 C 0.2123(6) 0.9219(6) 0.16142(19) 0.0186(9) Uani 1 1 d . . .
C14 C 0.3078(6) 0.8662(6) 0.1951(2) 0.0250(11) Uani 1 1 d . . .
H14A H 0.2802 0.7622 0.1987 0.030 Uiso 1 1 calc R . .
C15 C 0.4445(7) 0.9662(7) 0.2235(2) 0.0313(13) Uani 1 1 d . . .
H15A H 0.5063 0.9293 0.2466 0.038 Uiso 1 1 calc R . .
C16 C 0.4881(7) 1.1206(7) 0.2172(2) 0.0312(12) Uani 1 1 d . . .
H16A H 0.5791 1.1868 0.2362 0.037 Uiso 1 1 calc R . .
C17 C 0.3961(6) 1.1770(6) 0.1826(2) 0.0255(11) Uani 1 1 d . . .
H17A H 0.4257 1.2803 0.1783 0.031 Uiso 1 1 calc R . .
C18 C 0.2591(6) 1.0772(6) 0.1544(2) 0.0208(10) Uani 1 1 d . . .
H18A H 0.1986 1.1140 0.1309 0.025 Uiso 1 1 calc R . .
C19 C 0.2291(6) 0.3993(6) 0.0452(2) 0.0227(10) Uani 1 1 d . . .
C21 C 0.6793(6) 1.2311(6) 0.4013(2) 0.0233(10) Uani 1 1 d . . .
H21A H 0.7294 1.3069 0.3804 0.028 Uiso 1 1 calc R . .
H21B H 0.7556 1.2276 0.4298 0.028 Uiso 1 1 calc R . .
C22 C 0.5446(6) 1.2756(6) 0.4227(2) 0.0202(10) Uani 1 1 d . . .
C23 C 0.4582(6) 1.1846(6) 0.4555(2) 0.0205(10) Uani 1 1 d . . .
H23A H 0.4876 1.0990 0.4641 0.025 Uiso 1 1 calc R . .
C24 C 0.2967(6) 1.3425(7) 0.4639(2) 0.0266(11) Uani 1 1 d . . .
H24A H 0.2116 1.3645 0.4774 0.032 Uiso 1 1 calc R . .
C25 C 0.3778(7) 1.4409(7) 0.4334(2) 0.0293(12) Uani 1 1 d . . .
H25A H 0.3496 1.5291 0.4272 0.035 Uiso 1 1 calc R . .
C26 C 0.5035(6) 1.4064(6) 0.4118(2) 0.0260(11) Uani 1 1 d . . .
H26A H 0.5586 1.4701 0.3904 0.031 Uiso 1 1 calc R . .
C27 C 0.5870(6) 0.7898(6) 0.3354(2) 0.0197(10) Uani 1 1 d . . .
C28 C 0.6367(7) 0.7041(7) 0.2963(2) 0.0305(12) Uani 1 1 d . . .
H28A H 0.7408 0.7317 0.2910 0.037 Uiso 1 1 calc R . .
C29 C 0.5317(7) 0.5768(8) 0.2647(3) 0.0394(15) Uani 1 1 d . . .
H29A H 0.5662 0.5204 0.2385 0.047 Uiso 1 1 calc R . .
C30 C 0.3765(7) 0.5341(7) 0.2723(3) 0.0345(13) Uani 1 1 d . . .
H30A H 0.3060 0.4507 0.2509 0.041 Uiso 1 1 calc R . .
C31 C 0.3274(7) 0.6169(7) 0.3122(2) 0.0324(13) Uani 1 1 d . . .
H31A H 0.2236 0.5876 0.3177 0.039 Uiso 1 1 calc R . .
C32 C 0.4313(6) 0.7434(7) 0.3441(2) 0.0254(11) Uani 1 1 d . . .
H32A H 0.3972 0.7970 0.3711 0.031 Uiso 1 1 calc R . .
C33 C 0.8872(6) 1.0119(6) 0.3430(2) 0.0195(10) Uani 1 1 d . . .
C34 C 1.0346(6) 1.0221(8) 0.3686(2) 0.0315(13) Uani 1 1 d . . .
H34A H 1.0457 1.0037 0.4030 0.038 Uiso 1 1 calc R . .
C35 C 1.1656(7) 1.0600(8) 0.3422(2) 0.0360(14) Uani 1 1 d . . .
H35A H 1.2628 1.0620 0.3586 0.043 Uiso 1 1 calc R . .
C36 C 1.1504(7) 1.0943(7) 0.2919(2) 0.0314(13) Uani 1 1 d . . .
H36A H 1.2380 1.1233 0.2750 0.038 Uiso 1 1 calc R . .
C37 C 1.0056(7) 1.0855(7) 0.2668(2) 0.0309(12) Uani 1 1 d . . .
H37A H 0.9959 1.1066 0.2327 0.037 Uiso 1 1 calc R . .
C38 C 0.8742(7) 1.0458(7) 0.2917(2) 0.0276(11) Uani 1 1 d . . .
H38A H 0.7773 1.0416 0.2744 0.033 Uiso 1 1 calc R . .
C39 C 1.1056(6) 0.7700(6) 0.4573(2) 0.0231(10) Uani 1 1 d . . .
C20 C 0.3590(6) 0.5002(4) 0.0853(2) 0.0460(18) Uani 0.626(11) 1 d PD A 1
F1 F 0.3252(7) 0.4905(7) 0.1342(2) 0.0455(16) Uani 0.626(11) 1 d PD A 1
F2 F 0.3881(14) 0.6526(5) 0.0859(5) 0.0455(16) Uani 0.626(11) 1 d PD A 1
F3 F 0.4927(6) 0.4613(8) 0.0880(3) 0.0455(16) Uani 0.626(11) 1 d PD A 1
C20A C 0.3590(6) 0.5002(4) 0.0853(2) 0.0460(18) Uani 0.374(11) 1 d PD A 2
F1A F 0.4685(11) 0.5256(13) 0.0531(4) 0.090(5) Uani 0.374(11) 1 d PD A 2
F2A F 0.380(3) 0.6529(6) 0.0932(11) 0.090(5) Uani 0.374(11) 1 d PD A 2
F3A F 0.4573(18) 0.4512(14) 0.1164(7) 0.090(5) Uani 0.374(11) 1 d PD A 2
C40 C 0.9974(5) 0.6219(5) 0.42442(18) 0.0336(13) Uani 0.33 1 d PD B 1
F4 F 0.9081(14) 0.5286(11) 0.4527(4) 0.041(2) Uani 0.33 1 d PD B 1
F5 F 0.8876(12) 0.6450(15) 0.3902(4) 0.041(2) Uani 0.33 1 d PD B 1
F6 F 1.061(2) 0.5232(15) 0.3987(6) 0.041(2) Uani 0.33 1 d PD B 1
C40A C 0.9974(5) 0.6219(5) 0.42442(18) 0.0336(13) Uani 0.33 1 d PD B 2
F4A F 0.9684(13) 0.5109(9) 0.4549(4) 0.0340(18) Uani 0.33 1 d PD B 2
F5A F 1.0651(17) 0.5537(15) 0.3886(5) 0.0340(18) Uani 0.33 1 d PD B 2
F6A F 0.8524(8) 0.6228(16) 0.4071(6) 0.0340(18) Uani 0.33 1 d PD B 2
C40B C 0.9974(5) 0.6219(5) 0.42442(18) 0.0336(13) Uani 0.33 1 d PD B 3
F4B F 0.8461(7) 0.586(2) 0.4303(7) 0.068(3) Uani 0.33 1 d PD B 3
F5B F 0.9943(18) 0.6630(14) 0.3765(3) 0.068(3) Uani 0.33 1 d PD B 3
F6B F 1.055(2) 0.5002(14) 0.4197(7) 0.068(3) Uani 0.33 1 d PD B 3
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag1 P1 133.36(11) 2_575 . ?
N1 Ag1 O2 103.06(15) 2_575 2_565 ?
P1 Ag1 O2 119.72(10) . 2_565 ?
N1 Ag1 O2 91.60(14) 2_575 . ?
P1 Ag1 O2 114.52(10) . . ?
O2 Ag1 O2 76.48(13) 2_565 . ?
N2 Ag2 P2 136.26(12) 2_676 . ?
N2 Ag2 O5 107.22(15) 2_676 2_776 ?
P2 Ag2 O5 112.73(10) . 2_776 ?
N2 Ag2 O5 92.18(14) 2_676 . ?
P2 Ag2 O5 113.91(9) . . ?
O5 Ag2 O5 75.88(14) 2_776 . ?
O4 P2 C27 97.8(2) . . ?
O4 P2 C33 105.2(2) . . ?
C27 P2 C33 104.5(2) . . ?
O4 P2 Ag2 115.24(14) . . ?
C27 P2 Ag2 117.52(17) . . ?
C33 P2 Ag2 114.52(17) . . ?
O1 P1 C7 105.9(2) . . ?
O1 P1 C13 98.6(2) . . ?
C7 P1 C13 103.6(2) . . ?
O1 P1 Ag1 115.01(14) . . ?
C7 P1 Ag1 115.05(18) . . ?
C13 P1 Ag1 116.66(16) . . ?
C1 O1 P1 116.8(3) . . ?
C19 O2 Ag1 109.2(3) . 2_565 ?
C19 O2 Ag1 138.6(3) . . ?
Ag1 O2 Ag1 103.52(13) 2_565 . ?
C21 O4 P2 116.6(3) . . ?
C39 O5 Ag2 108.5(3) . 2_776 ?
C39 O5 Ag2 135.3(3) . . ?
Ag2 O5 Ag2 104.12(13) 2_776 . ?
C3 N1 C4 117.6(4) . . ?
C3 N1 Ag1 120.4(3) . 2_575 ?
C4 N1 Ag1 121.2(3) . 2_575 ?
C23 N2 C24 117.9(5) . . ?
C23 N2 Ag2 120.2(3) . 2_676 ?
C24 N2 Ag2 121.5(3) . 2_676 ?
O1 C1 C2 109.5(4) . . ?
O1 C1 H1B 109.8 . . ?
C2 C1 H1B 109.8 . . ?
O1 C1 H1C 109.8 . . ?
C2 C1 H1C 109.8 . . ?
H1B C1 H1C 108.2 . . ?
C3 C2 C6 117.6(5) . . ?
C3 C2 C1 120.0(4) . . ?
C6 C2 C1 122.3(5) . . ?
N1 C3 C2 123.6(5) . . ?
N1 C3 H3A 118.2 . . ?
C2 C3 H3A 118.2 . . ?
N1 C4 C5 122.5(5) . . ?
N1 C4 H4A 118.7 . . ?
C5 C4 H4A 118.7 . . ?
C4 C5 C6 119.3(5) . . ?
C4 C5 H5A 120.3 . . ?
C6 C5 H5A 120.3 . . ?
C5 C6 C2 119.3(5) . . ?
C5 C6 H6A 120.3 . . ?
C2 C6 H6A 120.3 . . ?
C8 C7 C12 119.1(5) . . ?
C8 C7 P1 119.1(4) . . ?
C12 C7 P1 121.8(4) . . ?
C9 C8 C7 120.4(6) . . ?
C9 C8 H8A 119.8 . . ?
C7 C8 H8A 119.8 . . ?
C8 C9 C10 120.1(6) . . ?
C8 C9 H9A 120.0 . . ?
C10 C9 H9A 120.0 . . ?
C9 C10 C11 120.4(6) . . ?
C9 C10 H10A 119.8 . . ?
C11 C10 H10A 119.8 . . ?
C10 C11 C12 119.9(6) . . ?
C10 C11 H11A 120.1 . . ?
C12 C11 H11A 120.1 . . ?
C11 C12 C7 120.1(6) . . ?
C11 C12 H12A 119.9 . . ?
C7 C12 H12A 119.9 . . ?
C14 C13 C18 119.3(5) . . ?
C14 C13 P1 121.1(4) . . ?
C18 C13 P1 119.4(4) . . ?
C13 C14 C15 120.2(5) . . ?
C13 C14 H14A 119.9 . . ?
C15 C14 H14A 119.9 . . ?
C16 C15 C14 120.1(5) . . ?
C16 C15 H15A 120.0 . . ?
C14 C15 H15A 120.0 . . ?
C15 C16 C17 120.3(5) . . ?
C15 C16 H16A 119.8 . . ?
C17 C16 H16A 119.8 . . ?
C18 C17 C16 119.6(5) . . ?
C18 C17 H17A 120.2 . . ?
C16 C17 H17A 120.2 . . ?
C17 C18 C13 120.5(5) . . ?
C17 C18 H18A 119.8 . . ?
C13 C18 H18A 119.8 . . ?
O3 C19 O2 130.1(5) . . ?
O3 C19 C20 114.8(4) . . ?
O2 C19 C20 115.0(4) . . ?
O4 C21 C22 108.8(4) . . ?
O4 C21 H21A 109.9 . . ?
C22 C21 H21A 109.9 . . ?
O4 C21 H21B 109.9 . . ?
C22 C21 H21B 109.9 . . ?
H21A C21 H21B 108.3 . . ?
C26 C22 C23 118.0(5) . . ?
C26 C22 C21 122.3(5) . . ?
C23 C22 C21 119.7(4) . . ?
N2 C23 C22 123.3(5) . . ?
N2 C23 H23A 118.4 . . ?
C22 C23 H23A 118.4 . . ?
N2 C24 C25 122.8(5) . . ?
N2 C24 H24A 118.6 . . ?
C25 C24 H24A 118.6 . . ?
C24 C25 C26 119.0(5) . . ?
C24 C25 H25A 120.5 . . ?
C26 C25 H25A 120.5 . . ?
C22 C26 C25 119.1(5) . . ?
C22 C26 H26A 120.5 . . ?
C25 C26 H26A 120.5 . . ?
C28 C27 C32 119.0(5) . . ?
C28 C27 P2 122.3(4) . . ?
C32 C27 P2 118.6(4) . . ?
C27 C28 C29 120.6(5) . . ?
C27 C28 H28A 119.7 . . ?
C29 C28 H28A 119.7 . . ?
C30 C29 C28 120.2(6) . . ?
C30 C29 H29A 119.9 . . ?
C28 C29 H29A 119.9 . . ?
C31 C30 C29 119.3(5) . . ?
C31 C30 H30A 120.3 . . ?
C29 C30 H30A 120.3 . . ?
C30 C31 C32 120.9(5) . . ?
C30 C31 H31A 119.5 . . ?
C32 C31 H31A 119.5 . . ?
C31 C32 C27 119.9(5) . . ?
C31 C32 H32A 120.1 . . ?
C27 C32 H32A 120.1 . . ?
C34 C33 C38 119.0(5) . . ?
C34 C33 P2 118.3(4) . . ?
C38 C33 P2 122.7(4) . . ?
C33 C34 C35 119.9(5) . . ?
C33 C34 H34A 120.1 . . ?
C35 C34 H34A 120.1 . . ?
C36 C35 C34 120.1(6) . . ?
C36 C35 H35A 119.9 . . ?
C34 C35 H35A 119.9 . . ?
C37 C36 C35 120.0(5) . . ?
C37 C36 H36A 120.0 . . ?
C35 C36 H36A 120.0 . . ?
C36 C37 C38 120.9(5) . . ?
C36 C37 H37A 119.5 . . ?
C38 C37 H37A 119.5 . . ?
C37 C38 C33 120.0(5) . . ?
C37 C38 H38A 120.0 . . ?
C33 C38 H38A 120.0 . . ?
O6 C39 O5 129.9(5) . . ?
O6 C39 C40 117.5(5) . . ?
O5 C39 C40 112.5(4) . . ?
F3 C20 F2 109.9(6) . . ?
F3 C20 F1 100.7(5) . . ?
F2 C20 F1 99.6(7) . . ?
F3 C20 C19 115.8(5) . . ?
F2 C20 C19 116.6(7) . . ?
F1 C20 C19 111.8(5) . . ?
F6 C40 F5 106.9(10) . . ?
F6 C40 F4 100.7(8) . . ?
F5 C40 F4 100.4(8) . . ?
F6 C40 C39 118.6(9) . . ?
F5 C40 C39 114.5(7) . . ?
F4 C40 C39 113.5(6) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N1 2.269(4) 2_575 ?
Ag1 P1 2.3556(13) . ?
Ag1 O2 2.375(4) 2_565 ?
Ag1 O2 2.549(4) . ?
Ag2 N2 2.264(5) 2_676 ?
Ag2 P2 2.3681(13) . ?
Ag2 O5 2.419(4) 2_776 ?
Ag2 O5 2.576(4) . ?
P2 O4 1.643(4) . ?
P2 C27 1.820(5) . ?
P2 C33 1.824(5) . ?
P1 O1 1.634(4) . ?
P1 C7 1.817(5) . ?
P1 C13 1.818(5) . ?
O1 C1 1.459(6) . ?
O2 C19 1.252(6) . ?
O2 Ag1 2.375(4) 2_565 ?
O3 C19 1.230(7) . ?
O4 C21 1.459(6) . ?
O5 C39 1.262(6) . ?
O5 Ag2 2.419(4) 2_776 ?
O6 C39 1.228(7) . ?
N1 C3 1.347(7) . ?
N1 C4 1.363(7) . ?
N1 Ag1 2.269(4) 2_575 ?
N2 C23 1.338(6) . ?
N2 C24 1.355(7) . ?
N2 Ag2 2.264(4) 2_676 ?
C1 C2 1.499(7) . ?
C1 H1B 0.9700 . ?
C1 H1C 0.9700 . ?
C2 C3 1.397(7) . ?
C2 C6 1.398(7) . ?
C3 H3A 0.9300 . ?
C4 C5 1.377(8) . ?
C4 H4A 0.9300 . ?
C5 C6 1.393(7) . ?
C5 H5A 0.9300 . ?
C6 H6A 0.9300 . ?
C7 C8 1.397(8) . ?
C7 C12 1.401(8) . ?
C8 C9 1.382(9) . ?
C8 H8A 0.9300 . ?
C9 C10 1.383(10) . ?
C9 H9A 0.9300 . ?
C10 C11 1.386(9) . ?
C10 H10A 0.9300 . ?
C11 C12 1.388(8) . ?
C11 H11A 0.9300 . ?
C12 H12A 0.9300 . ?
C13 C14 1.397(7) . ?
C13 C18 1.403(7) . ?
C14 C15 1.398(8) . ?
C14 H14A 0.9300 . ?
C15 C16 1.388(9) . ?
C15 H15A 0.9300 . ?
C16 C17 1.397(8) . ?
C16 H16A 0.9300 . ?
C17 C18 1.396(7) . ?
C17 H17A 0.9300 . ?
C18 H18A 0.9300 . ?
C19 C20 1.503(7) . ?
C21 C22 1.509(7) . ?
C21 H21A 0.9700 . ?
C21 H21B 0.9700 . ?
C22 C26 1.389(7) . ?
C22 C23 1.402(7) . ?
C23 H23A 0.9300 . ?
C24 C25 1.375(8) . ?
C24 H24A 0.9300 . ?
C25 C26 1.400(8) . ?
C25 H25A 0.9300 . ?
C26 H26A 0.9300 . ?
C27 C28 1.389(8) . ?
C27 C32 1.398(7) . ?
C28 C29 1.396(8) . ?
C28 H28A 0.9300 . ?
C29 C30 1.385(9) . ?
C29 H29A 0.9300 . ?
C30 C31 1.384(9) . ?
C30 H30A 0.9300 . ?
C31 C32 1.393(8) . ?
C31 H31A 0.9300 . ?
C32 H32A 0.9300 . ?
C33 C34 1.400(7) . ?
C33 C38 1.403(7) . ?
C34 C35 1.403(8) . ?
C34 H34A 0.9300 . ?
C35 C36 1.379(9) . ?
C35 H35A 0.9300 . ?
C36 C37 1.378(9) . ?
C36 H36A 0.9300 . ?
C37 C38 1.384(8) . ?
C37 H37A 0.9300 . ?
C38 H38A 0.9300 . ?
C39 C40 1.538(7) . ?
C20 F3 1.3390(11) . ?
C20 F2 1.3391(11) . ?
C20 F1 1.3417(11) . ?
C40 F6 1.3397(11) . ?
C40 F5 1.3400(11) . ?
C40 F4 1.3406(11) . ?
