#------------------------------------------------------------------------------
#$Date: 2016-03-23 01:32:23 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179145 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/06/4310603.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4310603
loop_
_publ_author_name
'Miguel A. Casado'
'Jesús J. Pérez-Torrente'
'Miguel A. Ciriano'
'Fernando J. Lahoz'
'Luis A. Oro'
_publ_contact_author_address
;
  Dr. Fernando J. Lahoz
  Departamento de Química Inorgánica - I.C.M.A.
  Facultad de Ciencias
  Universidad de Zaragoza - C.S.I.C.
  50009 Zaragoza, Spain
;
_publ_contact_author_email       lahoz@posta.unizar.es
_publ_contact_author_fax         '+34 976 761187'
_publ_contact_author_name        'Dr. Fernando J. Lahoz'
_publ_contact_author_phone       '+34 976 761147'
_publ_section_title
;
 Tetranuclear [Rh4(μ-PyS2)2(diolefin)4] Complexes as Building Blocks for
 New Inorganic Architectures: Synthesis of Coordination Polymers and
 Heteropolynuclear Complexes with Electrophilic d8 and d10 Metal Fragments
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1558
_journal_page_last               1567
_journal_paper_doi               10.1021/ic034893i
_journal_volume                  43
_journal_year                    2004
_chemical_formula_moiety
; C94 H60 Au2 F16 N2 P2 Rh4 S4, 2(Cl O4), 2(C H2 Cl2), C3 H6 O,
  4(C6 H14)
;
_chemical_formula_sum            'C123 H126 Au2 Cl6 F16 N2 O9 P2 Rh4 S4'
_chemical_formula_weight         3288.71
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 115.2690(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   22.7939(12)
_cell_length_b                   21.9335(11)
_cell_length_c                   24.5094(12)
_cell_measurement_reflns_used    5264
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      21.16
_cell_measurement_theta_min      2.46
_cell_volume                     11081.0(10)
_computing_cell_refinement       'SAINT+ v. 6.01 (Bruker AXS, 2000)'
_computing_data_collection       'SMART v. 5.611 (Bruker AXS, 2000)'
_computing_data_reduction        'SAINT+ v. 6.01 (Bruker AXS, 2000)'
_computing_molecular_graphics    'XP program, SHELXTL v6.10,Bruker2000'
_computing_publication_material  'XCIF program, SHELXTLv6.10,BrukerAXS'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 8.26
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker SMART APEX CCD system'
_diffrn_measurement_method       'ω rotations with narrow frames'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0932
_diffrn_reflns_av_sigmaI/netI    0.2019
_diffrn_reflns_limit_h_max       27
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            59718
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.06
_diffrn_reflns_theta_min         1.91
_diffrn_standards_decay_%        'no decay'
_exptl_absorpt_coefficient_mu    3.560
_exptl_absorpt_correction_T_max  0.645
_exptl_absorpt_correction_T_min  0.533
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
; 
 SADABS: Area-Detector Absorption Correction. (1996) Bruker-AXS 
 within SAINT+ package, v. 6.01.
;
_exptl_crystal_colour            'dark violet'
_exptl_crystal_density_diffrn    1.971
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       'irregular block'
_exptl_crystal_F_000             6512
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.12
_refine_diff_density_max         1.760
_refine_diff_density_min         -1.874
_refine_diff_density_rms         0.165
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.830
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1271
_refine_ls_number_reflns         19583
_refine_ls_number_restraints     159
_refine_ls_restrained_S_all      0.832
_refine_ls_R_factor_all          0.1018
_refine_ls_R_factor_gt           0.0548
_refine_ls_shift/su_max          0.018
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0229P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1037
_refine_ls_wR_factor_ref         0.1111
_reflns_number_gt                10069
_reflns_number_total             19583
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic034893isi20030729_034816.cif
_cod_data_source_block           mac36az
_cod_database_code               4310603
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 1.00829(3) 0.35001(2) 0.70572(2) 0.02637(14) Uani 1 1 d . . .
Au2 Au 0.84019(2) 0.49246(2) 0.89619(2) 0.02456(13) Uani 1 1 d . . .
Rh1 Rh 1.07877(5) 0.26131(4) 0.81234(4) 0.0218(2) Uani 1 1 d . . .
Rh2 Rh 0.98753(5) 0.22197(4) 0.86876(4) 0.0192(2) Uani 1 1 d . . .
Rh3 Rh 0.99246(5) 0.31146(4) 0.98145(4) 0.0194(2) Uani 1 1 d . . .
Rh4 Rh 0.85845(5) 0.37011(4) 0.96167(4) 0.0206(2) Uani 1 1 d . . .
S1 S 1.07171(15) 0.29478(12) 0.90111(12) 0.0210(7) Uani 1 1 d . . .
S2 S 0.93412(15) 0.44695(12) 0.96720(12) 0.0216(7) Uani 1 1 d . . .
S3 S 0.96942(16) 0.26692(12) 0.73951(13) 0.0237(8) Uani 1 1 d . . .
S4 S 0.88548(15) 0.29181(12) 0.90916(13) 0.0218(7) Uani 1 1 d . . .
N1 N 0.9203(4) 0.2896(4) 0.8181(4) 0.020(2) Uani 1 1 d . . .
N2 N 1.0021(4) 0.3789(4) 0.9242(4) 0.020(2) Uani 1 1 d . . .
C1 C 0.9178(5) 0.3063(5) 0.7635(5) 0.019(3) Uani 1 1 d U . .
C2 C 0.8758(5) 0.3488(4) 0.7304(5) 0.022(3) Uani 1 1 d U . .
H2 H 0.8745 0.3596 0.6924 0.026 Uiso 1 1 calc R . .
C3 C 0.8342(5) 0.3775(4) 0.7497(5) 0.019(3) Uani 1 1 d U . .
H3 H 0.8034 0.4064 0.7248 0.023 Uiso 1 1 calc R . .
C4 C 0.8387(5) 0.3631(4) 0.8060(5) 0.022(3) Uani 1 1 d . . .
H4 H 0.8131 0.3838 0.8221 0.027 Uiso 1 1 calc R . .
C5 C 0.8812(5) 0.3180(5) 0.8384(5) 0.019(3) Uani 1 1 d U . .
C6 C 0.9750(6) 0.4350(5) 0.9207(5) 0.022(3) Uani 1 1 d U . .
C7 C 0.9832(5) 0.4809(5) 0.8873(4) 0.019(3) Uani 1 1 d U . .
H7 H 0.9665 0.5204 0.8880 0.023 Uiso 1 1 calc R . .
C8 C 1.0170(6) 0.4689(5) 0.8513(5) 0.025(3) Uani 1 1 d . . .
H8 H 1.0198 0.4991 0.8247 0.030 Uiso 1 1 calc R . .
C9 C 1.0462(6) 0.4116(5) 0.8558(5) 0.024(3) Uani 1 1 d . . .
H9 H 1.0723 0.4034 0.8351 0.029 Uiso 1 1 calc R . .
C10 C 1.0362(6) 0.3674(4) 0.8911(5) 0.018(3) Uani 1 1 d . . .
C11 C 1.1730(5) 0.2284(5) 0.8679(5) 0.021(3) Uani 1 1 d . . .
H11 H 1.1700 0.2257 0.9053 0.025 Uiso 1 1 calc R . .
C12 C 1.1791(6) 0.2819(5) 0.8439(5) 0.023(3) Uani 1 1 d . . .
H12 H 1.1826 0.3204 0.8627 0.028 Uiso 1 1 calc R . .
C13 C 1.1796(6) 0.2723(5) 0.7818(5) 0.028(3) Uani 1 1 d . . .
H13 H 1.1828 0.3118 0.7629 0.034 Uiso 1 1 calc R . .
C14 C 1.1174(6) 0.2413(5) 0.7470(5) 0.028(3) Uani 1 1 d U . .
H14 H 1.0850 0.2566 0.7102 0.034 Uiso 1 1 calc R . .
C15 C 1.1113(6) 0.1892(5) 0.7729(5) 0.023(3) Uani 1 1 d . . .
H15 H 1.0733 0.1647 0.7570 0.028 Uiso 1 1 calc R . .
C16 C 1.1715(6) 0.1727(5) 0.8308(5) 0.028(3) Uani 1 1 d . . .
H16 H 1.1671 0.1334 0.8495 0.034 Uiso 1 1 calc R . .
C17 C 1.0252(5) 0.1482(5) 0.9324(5) 0.022(3) Uani 1 1 d U . .
H17 H 1.0482 0.1700 0.9689 0.027 Uiso 1 1 calc R . .
C18 C 1.0478(5) 0.1417(4) 0.8878(4) 0.018(3) Uani 1 1 d U . .
H18 H 1.0879 0.1577 0.8910 0.021 Uiso 1 1 calc R . .
C19 C 1.0001(5) 0.1057(4) 0.8330(4) 0.016(3) Uani 1 1 d U . .
H19 H 1.0154 0.1013 0.8006 0.019 Uiso 1 1 calc R . .
C20 C 0.9407(5) 0.1451(5) 0.8142(5) 0.024(3) Uani 1 1 d . . .
H20 H 0.9204 0.1635 0.7755 0.029 Uiso 1 1 calc R . .
C21 C 0.9177(5) 0.1526(4) 0.8584(4) 0.019(3) Uani 1 1 d . . .
H21 H 0.8808 0.1763 0.8532 0.023 Uiso 1 1 calc R . .
C22 C 0.9604(5) 0.1171(4) 0.9173(5) 0.019(3) Uani 1 1 d . . .
H22 H 0.9450 0.1211 0.9497 0.023 Uiso 1 1 calc R . .
C23 C 1.0622(5) 0.3515(5) 1.0619(4) 0.018(3) Uani 1 1 d U . .
H23 H 1.0632 0.3923 1.0495 0.021 Uiso 1 1 calc R . .
C24 C 1.0915(5) 0.3045(4) 1.0469(4) 0.017(3) Uani 1 1 d U . .
H24 H 1.1139 0.3092 1.0222 0.020 Uiso 1 1 calc R . .
C25 C 1.0848(5) 0.2438(5) 1.0736(4) 0.019(3) Uani 1 1 d . . .
H25 H 1.1070 0.2092 1.0636 0.023 Uiso 1 1 calc R . .
C26 C 1.0124(5) 0.2383(5) 1.0458(4) 0.019(3) Uani 1 1 d U . .
H26 H 0.9897 0.2051 1.0208 0.022 Uiso 1 1 calc R . .
C27 C 0.9820(6) 0.2859(4) 1.0597(4) 0.020(3) Uani 1 1 d . . .
H27 H 0.9361 0.2891 1.0445 0.024 Uiso 1 1 calc R . .
C28 C 1.0273(5) 0.3321(5) 1.1008(4) 0.019(3) Uani 1 1 d . . .
H28 H 1.0048 0.3665 1.1108 0.023 Uiso 1 1 calc R . .
C29 C 0.7617(6) 0.3423(5) 0.9414(5) 0.031(3) Uani 1 1 d . . .
H29 H 0.7465 0.3326 0.8998 0.038 Uiso 1 1 calc R . .
C30 C 0.8066(5) 0.3059(5) 0.9881(5) 0.021(3) Uani 1 1 d . . .
H30 H 0.8252 0.2695 0.9814 0.026 Uiso 1 1 calc R . .
C31 C 0.8221(6) 0.3318(5) 1.0510(5) 0.028(3) Uani 1 1 d . . .
H31 H 0.8542 0.3068 1.0846 0.034 Uiso 1 1 calc R . .
C32 C 0.8495(7) 0.3933(5) 1.0421(5) 0.034(3) Uani 1 1 d . . .
H32 H 0.8933 0.4051 1.0655 0.041 Uiso 1 1 calc R . .
C33 C 0.8059(6) 0.4294(5) 0.9981(5) 0.022(3) Uani 1 1 d . . .
H33 H 0.8155 0.4693 0.9892 0.026 Uiso 1 1 calc R . .
C34 C 0.7399(7) 0.3988(5) 0.9645(5) 0.032(3) Uani 1 1 d . . .
H34 H 0.7081 0.4245 0.9313 0.039 Uiso 1 1 calc R . .
C35 C 1.2359(6) 0.2301(5) 0.7909(5) 0.027(3) Uani 1 1 d . . .
C36 C 1.2887(6) 0.2386(5) 0.7790(5) 0.028(3) Uani 1 1 d . . .
C37 C 1.3365(6) 0.1965(5) 0.7929(5) 0.030(3) Uani 1 1 d . . .
C38 C 1.3316(7) 0.1424(6) 0.8202(6) 0.040(4) Uani 1 1 d U . .
C39 C 1.2773(6) 0.1317(5) 0.8314(5) 0.029(3) Uani 1 1 d . . .
C40 C 1.2300(6) 0.1751(5) 0.8175(5) 0.025(3) Uani 1 1 d U . .
C41 C 0.9861(6) 0.0439(5) 0.8549(5) 0.021(3) Uani 1 1 d U . .
C42 C 0.9935(6) -0.0116(5) 0.8373(5) 0.028(3) Uani 1 1 d . . .
C43 C 0.9792(6) -0.0630(5) 0.8612(5) 0.027(3) Uani 1 1 d . . .
C44 C 0.9568(6) -0.0556(5) 0.9050(5) 0.033(3) Uani 1 1 d . . .
C45 C 0.9495(6) 0.0008(5) 0.9238(5) 0.021(3) Uani 1 1 d . . .
C46 C 0.9643(5) 0.0509(4) 0.8989(5) 0.018(3) Uani 1 1 d U . .
C47 C 1.1070(5) 0.2535(5) 1.1410(5) 0.018(3) Uani 1 1 d U . .
C48 C 1.1524(6) 0.2190(5) 1.1888(5) 0.027(3) Uani 1 1 d . . .
C49 C 1.1701(6) 0.2343(5) 1.2479(5) 0.028(3) Uani 1 1 d U . .
C50 C 1.1429(6) 0.2818(6) 1.2626(6) 0.035(3) Uani 1 1 d U . .
C51 C 1.0961(6) 0.3142(5) 1.2161(5) 0.026(3) Uani 1 1 d . . .
C52 C 1.0794(6) 0.3019(4) 1.1561(5) 0.019(3) Uani 1 1 d . . .
C53 C 0.7597(6) 0.3428(5) 1.0568(5) 0.030(3) Uani 1 1 d . . .
C54 C 0.7420(7) 0.3231(6) 1.1009(6) 0.038(4) Uani 1 1 d . . .
C55 C 0.6853(8) 0.3378(6) 1.1013(7) 0.051(4) Uani 1 1 d . . .
C56 C 0.6418(7) 0.3744(6) 1.0546(6) 0.045(4) Uani 1 1 d . . .
C57 C 0.6560(6) 0.3955(6) 1.0090(6) 0.030(3) Uani 1 1 d . . .
C58 C 0.7157(6) 0.3797(5) 1.0105(5) 0.033(3) Uani 1 1 d . . .
P1 P 1.04057(17) 0.43192(14) 0.67006(14) 0.0271(8) Uani 1 1 d . . .
C59 C 0.9770(7) 0.4630(6) 0.6021(5) 0.032(3) Uani 1 1 d . . .
C60 C 0.9903(6) 0.5097(5) 0.5709(5) 0.032(3) Uani 1 1 d . . .
H60 H 1.0333 0.5248 0.5850 0.039 Uiso 1 1 calc R . .
C61 C 0.9430(8) 0.5340(6) 0.5206(6) 0.049(4) Uani 1 1 d . . .
H61 H 0.9527 0.5654 0.4991 0.059 Uiso 1 1 calc R . .
C62 C 0.8798(8) 0.5121(7) 0.5010(6) 0.066(5) Uani 1 1 d . . .
H62 H 0.8457 0.5294 0.4665 0.079 Uiso 1 1 calc R . .
C63 C 0.8676(8) 0.4674(7) 0.5306(6) 0.071(5) Uani 1 1 d . . .
H63 H 0.8248 0.4514 0.5157 0.085 Uiso 1 1 calc R . .
C64 C 0.9139(8) 0.4438(6) 0.5814(6) 0.058(5) Uani 1 1 d . . .
H64 H 0.9028 0.4135 0.6031 0.070 Uiso 1 1 calc R . .
C65 C 1.0655(6) 0.4948(5) 0.7223(5) 0.023(3) Uani 1 1 d . . .
C66 C 1.1240(6) 0.4891(5) 0.7761(5) 0.031(3) Uani 1 1 d . . .
H66 H 1.1487 0.4526 0.7838 0.037 Uiso 1 1 calc R . .
C67 C 1.1449(7) 0.5367(6) 0.8174(5) 0.039(4) Uani 1 1 d . . .
H67 H 1.1831 0.5329 0.8540 0.046 Uiso 1 1 calc R . .
C68 C 1.1087(7) 0.5899(6) 0.8036(6) 0.033(3) Uani 1 1 d . . .
H68 H 1.1241 0.6241 0.8296 0.040 Uiso 1 1 calc R . .
C69 C 1.0506(7) 0.5941(6) 0.7528(6) 0.042(4) Uani 1 1 d . . .
H69 H 1.0248 0.6299 0.7454 0.050 Uiso 1 1 calc R . .
C70 C 1.0306(6) 0.5459(5) 0.7129(5) 0.030(3) Uani 1 1 d . . .
H70 H 0.9907 0.5490 0.6778 0.036 Uiso 1 1 calc R . .
C71 C 1.1081(6) 0.4122(5) 0.6526(5) 0.028(3) Uani 1 1 d . . .
C72 C 1.1024(7) 0.3565(5) 0.6225(5) 0.042(4) Uani 1 1 d . . .
H72 H 1.0651 0.3316 0.6121 0.051 Uiso 1 1 calc R . .
C73 C 1.1522(8) 0.3389(5) 0.6085(6) 0.051(4) Uani 1 1 d . . .
H73 H 1.1479 0.3024 0.5862 0.061 Uiso 1 1 calc R . .
C74 C 1.2080(7) 0.3724(6) 0.6257(6) 0.044(4) Uani 1 1 d . . .
H74 H 1.2421 0.3590 0.6161 0.052 Uiso 1 1 calc R . .
C75 C 1.2139(7) 0.4261(6) 0.6573(5) 0.041(4) Uani 1 1 d . . .
H75 H 1.2527 0.4492 0.6705 0.050 Uiso 1 1 calc R . .
C76 C 1.1643(6) 0.4456(5) 0.6695(5) 0.033(3) Uani 1 1 d . . .
H76 H 1.1685 0.4832 0.6901 0.039 Uiso 1 1 calc R . .
P2 P 0.75236(17) 0.53512(14) 0.82269(14) 0.0295(9) Uani 1 1 d . . .
C77 C 0.6794(6) 0.4985(5) 0.8176(5) 0.029(3) Uani 1 1 d . . .
C78 C 0.6373(8) 0.5231(6) 0.8345(6) 0.057(4) Uani 1 1 d . . .
H78 H 0.6423 0.5651 0.8449 0.068 Uiso 1 1 calc R . .
C79 C 0.5855(8) 0.4920(7) 0.8382(6) 0.060(5) Uani 1 1 d . . .
H79 H 0.5567 0.5126 0.8507 0.072 Uiso 1 1 calc R . .
C80 C 0.5775(7) 0.4326(8) 0.8238(6) 0.061(5) Uani 1 1 d . . .
H80 H 0.5431 0.4103 0.8265 0.073 Uiso 1 1 calc R . .
C81 C 0.6192(7) 0.4047(6) 0.8052(6) 0.046(4) Uani 1 1 d . . .
H81 H 0.6133 0.3629 0.7939 0.056 Uiso 1 1 calc R . .
C82 C 0.6699(7) 0.4371(6) 0.8029(5) 0.047(4) Uani 1 1 d . . .
H82 H 0.6992 0.4167 0.7908 0.056 Uiso 1 1 calc R . .
C83 C 0.7440(6) 0.6152(5) 0.8345(5) 0.026(3) Uani 1 1 d . . .
C84 C 0.7263(6) 0.6581(5) 0.7873(5) 0.034(3) Uani 1 1 d . . .
H84 H 0.7209 0.6460 0.7482 0.041 Uiso 1 1 calc R . .
C85 C 0.7173(6) 0.7153(5) 0.7983(5) 0.031(3) Uani 1 1 d U . .
H85 H 0.7058 0.7442 0.7666 0.037 Uiso 1 1 calc R . .
C86 C 0.7239(6) 0.7349(5) 0.8542(6) 0.033(3) Uani 1 1 d . . .
H86 H 0.7162 0.7764 0.8599 0.039 Uiso 1 1 calc R . .
C87 C 0.7418(6) 0.6944(5) 0.9018(6) 0.036(3) Uani 1 1 d . . .
H87 H 0.7466 0.7076 0.9404 0.043 Uiso 1 1 calc R . .
C88 C 0.7528(6) 0.6329(5) 0.8916(5) 0.036(4) Uani 1 1 d . . .
H88 H 0.7660 0.6040 0.9236 0.043 Uiso 1 1 calc R . .
C89 C 0.7575(7) 0.5281(5) 0.7511(5) 0.033(3) Uani 1 1 d . . .
C90 C 0.7077(7) 0.5082(5) 0.6982(5) 0.042(4) Uani 1 1 d . . .
H90 H 0.6658 0.5006 0.6962 0.051 Uiso 1 1 calc R . .
C91 C 0.7197(7) 0.4993(6) 0.6480(6) 0.050(4) Uani 1 1 d . . .
H91 H 0.6862 0.4830 0.6124 0.060 Uiso 1 1 calc R . .
C92 C 0.7781(8) 0.5131(6) 0.6475(6) 0.049(4) Uani 1 1 d . . .
H92 H 0.7840 0.5086 0.6116 0.059 Uiso 1 1 calc R . .
C93 C 0.8262(7) 0.5327(5) 0.6975(6) 0.041(4) Uani 1 1 d . . .
H93 H 0.8673 0.5414 0.6980 0.050 Uiso 1 1 calc R . .
C94 C 0.8166(7) 0.5406(5) 0.7498(6) 0.044(4) Uani 1 1 d . . .
H94 H 0.8515 0.5550 0.7854 0.053 Uiso 1 1 calc R . .
F1 F 1.2961(4) 0.2922(3) 0.7546(3) 0.047(2) Uani 1 1 d . . .
F2 F 1.3886(4) 0.2060(3) 0.7826(3) 0.052(2) Uani 1 1 d . . .
F3 F 1.3774(4) 0.0996(3) 0.8346(3) 0.050(2) Uani 1 1 d . . .
F4 F 1.2743(4) 0.0784(3) 0.8572(3) 0.045(2) Uani 1 1 d . . .
F5 F 1.0179(4) -0.0195(3) 0.7952(3) 0.041(2) Uani 1 1 d . . .
F6 F 0.9858(4) -0.1196(3) 0.8422(3) 0.047(2) Uani 1 1 d . . .
F7 F 0.9416(3) -0.1061(3) 0.9289(3) 0.0378(19) Uani 1 1 d U . .
F8 F 0.9289(3) 0.0051(3) 0.9677(3) 0.0294(17) Uani 1 1 d . . .
F9 F 1.1815(3) 0.1688(3) 1.1750(3) 0.0348(18) Uani 1 1 d . . .
F10 F 1.2163(4) 0.2016(3) 1.2912(3) 0.045(2) Uani 1 1 d . . .
F11 F 1.1596(4) 0.2963(3) 1.3196(3) 0.045(2) Uani 1 1 d . . .
F12 F 1.0687(3) 0.3637(3) 1.2305(3) 0.0359(18) Uani 1 1 d . . .
F13 F 0.7850(4) 0.2881(3) 1.1465(3) 0.043(2) Uani 1 1 d . . .
F14 F 0.6704(4) 0.3170(3) 1.1457(3) 0.056(2) Uani 1 1 d . . .
F15 F 0.5847(4) 0.3871(4) 1.0554(3) 0.067(3) Uani 1 1 d . . .
F16 F 0.6130(4) 0.4282(4) 0.9662(3) 0.060(2) Uani 1 1 d . . .
Cl1 Cl 0.71435(18) 0.37039(15) 0.52245(15) 0.0393(9) Uani 1 1 d . . .
O1 O 0.6851(4) 0.3111(4) 0.5137(4) 0.049(3) Uani 1 1 d . . .
O2 O 0.7755(5) 0.3707(4) 0.5726(4) 0.056(3) Uani 1 1 d . . .
O3 O 0.7229(5) 0.3868(4) 0.4703(4) 0.055(3) Uani 1 1 d . . .
O4 O 0.6718(5) 0.4133(5) 0.5315(5) 0.090(4) Uani 1 1 d . . .
Cl2 Cl 0.7533(3) 0.57838(18) 0.04272(19) 0.096(2) Uani 1 1 d D . .
O5 O 0.7215(7) 0.6358(5) 0.0215(5) 0.154(7) Uani 1 1 d D . .
O6A O 0.7893(14) 0.5797(9) 0.1053(6) 0.055(10) Uiso 0.42(3) 1 d PD . .
O6B O 0.7480(17) 0.5708(10) 0.0978(9) 0.130(11) Uiso 0.58(3) 1 d PD . .
O7A O 0.7161(11) 0.5222(9) 0.0270(15) 0.071(11) Uiso 0.42(3) 1 d PD . .
O7B O 0.7138(8) 0.5388(8) -0.0044(9) 0.063(8) Uiso 0.58(3) 1 d PD . .
O8A O 0.8034(15) 0.5749(16) 0.0191(18) 0.12(2) Uiso 0.42(3) 1 d PD . .
O8B O 0.8137(9) 0.5785(11) 0.0390(13) 0.082(10) Uiso 0.58(3) 1 d PD . .
C1SA C 0.8395(17) 0.0379(9) 0.0280(10) 0.041(12) Uiso 0.51(5) 1 d PD . .
C1SB C 0.8007(18) 0.0614(19) 0.0177(10) 0.108(19) Uiso 0.49(5) 1 d PD . .
Cl3S Cl 0.8295(3) 0.0292(3) 0.0949(3) 0.161(3) Uani 1 1 d D . .
Cl4S Cl 0.8619(4) 0.1153(3) 0.0188(3) 0.162(3) Uani 1 1 d D . .
C2S C 0.1470(10) -0.0174(9) 0.6982(10) 0.090 Uiso 0.693(6) 1 d PD . .
Cl5S Cl 0.2043(3) 0.0354(2) 0.6971(2) 0.0472(17) Uiso 0.693(6) 1 d PD . .
Cl6S Cl 0.1148(3) 0.0242(3) 0.7477(3) 0.076(2) Uiso 0.693(6) 1 d PD . .
C3S C 0.087(2) -0.0089(15) 0.6343(13) 0.090 Uiso 0.307(6) 1 d PD . .
Cl7S Cl 0.1322(11) 0.0516(9) 0.6851(9) 0.139(8) Uiso 0.307(6) 1 d PD . .
Cl8S Cl 0.0956(14) -0.0643(11) 0.6917(11) 0.210(12) Uiso 0.307(6) 1 d PD . .
O1S O 0.9454(5) 0.2685(4) 0.1747(4) 0.067(3) Uiso 1 1 d . . .
C4S C 0.9928(8) 0.2172(7) 0.2646(7) 0.080(5) Uiso 1 1 d . . .
C5S C 0.9471(7) 0.2246(6) 0.2033(6) 0.044(4) Uiso 1 1 d . . .
C6S C 0.8908(8) 0.1784(6) 0.1755(6) 0.066(5) Uiso 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Au1 S3 177.04(12) . . ?
P2 Au2 S2 175.86(11) . . ?
C11 Rh1 C12 36.9(3) . . ?
C11 Rh1 C15 65.6(4) . . ?
C12 Rh1 C15 78.2(4) . . ?
C11 Rh1 C14 77.7(4) . . ?
C12 Rh1 C14 66.5(4) . . ?
C15 Rh1 C14 36.3(3) . . ?
C11 Rh1 S1 87.9(3) . . ?
C12 Rh1 S1 94.8(3) . . ?
C15 Rh1 S1 144.6(3) . . ?
C14 Rh1 S1 161.3(3) . . ?
C11 Rh1 S3 162.4(3) . . ?
C12 Rh1 S3 152.3(3) . . ?
C15 Rh1 S3 98.9(3) . . ?
C14 Rh1 S3 94.7(3) . . ?
S1 Rh1 S3 102.36(11) . . ?
N1 Rh2 C20 98.3(4) . . ?
N1 Rh2 C21 96.6(4) . . ?
C20 Rh2 C21 38.2(3) . . ?
N1 Rh2 C17 156.5(4) . . ?
C20 Rh2 C17 78.4(4) . . ?
C21 Rh2 C17 66.3(4) . . ?
N1 Rh2 C18 159.2(3) . . ?
C20 Rh2 C18 66.0(4) . . ?
C21 Rh2 C18 79.5(4) . . ?
C17 Rh2 C18 37.9(3) . . ?
N1 Rh2 S1 90.2(2) . . ?
C20 Rh2 S1 149.7(3) . . ?
C21 Rh2 S1 168.5(3) . . ?
C17 Rh2 S1 104.5(3) . . ?
C18 Rh2 S1 97.4(3) . . ?
C27 Rh3 N2 151.0(4) . . ?
C27 Rh3 C23 66.2(4) . . ?
N2 Rh3 C23 94.5(4) . . ?
C27 Rh3 C24 78.0(4) . . ?
N2 Rh3 C24 99.9(4) . . ?
C23 Rh3 C24 37.2(3) . . ?
C27 Rh3 C26 37.6(3) . . ?
N2 Rh3 C26 163.0(4) . . ?
C23 Rh3 C26 77.8(4) . . ?
C24 Rh3 C26 64.8(4) . . ?
C27 Rh3 S4 98.7(3) . . ?
N2 Rh3 S4 89.8(3) . . ?
C23 Rh3 S4 153.6(3) . . ?
C24 Rh3 S4 165.4(3) . . ?
C26 Rh3 S4 103.9(3) . . ?
C30 Rh4 C32 65.6(4) . . ?
C30 Rh4 C29 38.9(4) . . ?
C32 Rh4 C29 77.6(4) . . ?
C30 Rh4 C33 78.2(4) . . ?
C32 Rh4 C33 36.8(4) . . ?
C29 Rh4 C33 64.9(4) . . ?
C30 Rh4 S2 160.9(3) . . ?
C32 Rh4 S2 97.6(3) . . ?
C29 Rh4 S2 150.5(3) . . ?
C33 Rh4 S2 93.8(3) . . ?
C30 Rh4 S4 89.6(3) . . ?
C32 Rh4 S4 145.3(3) . . ?
C29 Rh4 S4 98.5(3) . . ?
C33 Rh4 S4 163.3(3) . . ?
S2 Rh4 S4 101.17(10) . . ?
C10 S1 Rh2 107.8(4) . . ?
C10 S1 Rh1 111.2(3) . . ?
Rh2 S1 Rh1 81.12(9) . . ?
C6 S2 Au2 98.7(4) . . ?
C6 S2 Rh4 115.3(4) . . ?
Au2 S2 Rh4 81.25(10) . . ?
C1 S3 Au1 98.4(4) . . ?
C1 S3 Rh1 114.5(4) . . ?
Au1 S3 Rh1 82.59(10) . . ?
C5 S4 Rh3 106.3(4) . . ?
C5 S4 Rh4 111.9(4) . . ?
Rh3 S4 Rh4 83.42(9) . . ?
C5 N1 C1 118.7(9) . . ?
C5 N1 Rh2 122.5(7) . . ?
C1 N1 Rh2 118.8(7) . . ?
C6 N2 C10 119.2(9) . . ?
C6 N2 Rh3 120.1(7) . . ?
C10 N2 Rh3 120.7(7) . . ?
C2 C1 N1 120.1(10) . . ?
C2 C1 S3 123.5(9) . . ?
N1 C1 S3 116.3(8) . . ?
C1 C2 C3 122.1(10) . . ?
C1 C2 H2 119.0 . . ?
C3 C2 H2 119.0 . . ?
C4 C3 C2 118.1(10) . . ?
C4 C3 H3 120.9 . . ?
C2 C3 H3 120.9 . . ?
C3 C4 C5 118.5(10) . . ?
C3 C4 H4 120.7 . . ?
C5 C4 H4 120.7 . . ?
N1 C5 C4 122.3(10) . . ?
N1 C5 S4 116.1(8) . . ?
C4 C5 S4 121.6(9) . . ?
N2 C6 C7 122.2(10) . . ?
N2 C6 S2 116.2(8) . . ?
C7 C6 S2 121.5(8) . . ?
C6 C7 C8 119.1(10) . . ?
C6 C7 H7 120.5 . . ?
C8 C7 H7 120.5 . . ?
C9 C8 C7 118.7(10) . . ?
C9 C8 H8 120.6 . . ?
C7 C8 H8 120.6 . . ?
C10 C9 C8 118.5(10) . . ?
C10 C9 H9 120.7 . . ?
C8 C9 H9 120.7 . . ?
N2 C10 C9 122.1(9) . . ?
N2 C10 S1 115.6(7) . . ?
C9 C10 S1 122.2(8) . . ?
C12 C11 C16 114.9(10) . . ?
C12 C11 Rh1 71.8(7) . . ?
C16 C11 Rh1 97.6(7) . . ?
C12 C11 H11 122.5 . . ?
C16 C11 H11 122.5 . . ?
Rh1 C11 H11 99.7 . . ?
C11 C12 C13 110.9(9) . . ?
C11 C12 Rh1 71.3(7) . . ?
C13 C12 Rh1 94.1(7) . . ?
C11 C12 H12 124.5 . . ?
C13 C12 H12 124.5 . . ?
Rh1 C12 H12 102.7 . . ?
C14 C13 C35 110.4(9) . . ?
C14 C13 C12 102.9(9) . . ?
C35 C13 C12 107.5(9) . . ?
C14 C13 H13 111.9 . . ?
C35 C13 H13 111.9 . . ?
C12 C13 H13 111.9 . . ?
C15 C14 C13 112.7(11) . . ?
C15 C14 Rh1 70.6(6) . . ?
C13 C14 Rh1 94.2(7) . . ?
C15 C14 H14 123.6 . . ?
C13 C14 H14 123.7 . . ?
Rh1 C14 H14 103.5 . . ?
C14 C15 C16 113.9(11) . . ?
C14 C15 Rh1 73.2(6) . . ?
C16 C15 Rh1 95.9(7) . . ?
C14 C15 H15 123.1 . . ?
C16 C15 H15 123.1 . . ?
Rh1 C15 H15 99.9 . . ?
C40 C16 C11 107.9(9) . . ?
C40 C16 C15 108.5(9) . . ?
C11 C16 C15 98.5(9) . . ?
C40 C16 H16 113.6 . . ?
C11 C16 H16 113.6 . . ?
C15 C16 H16 113.6 . . ?
C18 C17 C22 114.0(10) . . ?
C18 C17 Rh2 71.1(6) . . ?
C22 C17 Rh2 96.6(7) . . ?
C18 C17 H17 123.0 . . ?
C22 C17 H17 123.0 . . ?
Rh2 C17 H17 101.0 . . ?
C17 C18 C19 112.0(10) . . ?
C17 C18 Rh2 70.9(6) . . ?
C19 C18 Rh2 94.8(6) . . ?
C17 C18 H18 124.0 . . ?
C19 C18 H18 124.0 . . ?
Rh2 C18 H18 102.6 . . ?
C20 C19 C41 108.5(9) . . ?
C20 C19 C18 100.4(8) . . ?
C41 C19 C18 108.8(8) . . ?
C20 C19 H19 112.8 . . ?
C41 C19 H19 112.8 . . ?
C18 C19 H19 112.8 . . ?
C21 C20 C19 114.6(9) . . ?
C21 C20 Rh2 71.0(6) . . ?
C19 C20 Rh2 96.8(7) . . ?
C21 C20 H20 122.7 . . ?
C19 C20 H20 122.7 . . ?
Rh2 C20 H20 101.0 . . ?
C20 C21 C22 111.5(10) . . ?
C20 C21 Rh2 70.8(6) . . ?
C22 C21 Rh2 96.1(6) . . ?
C20 C21 H21 124.3 . . ?
C22 C21 H21 124.3 . . ?
Rh2 C21 H21 101.4 . . ?
C17 C22 C46 108.9(9) . . ?
C17 C22 C21 99.1(8) . . ?
C46 C22 C21 107.0(8) . . ?
C17 C22 H22 113.6 . . ?
C46 C22 H22 113.6 . . ?
C21 C22 H22 113.6 . . ?
C24 C23 C28 113.7(9) . . ?
C24 C23 Rh3 72.3(6) . . ?
C28 C23 Rh3 94.7(6) . . ?
C24 C23 H23 123.2 . . ?
C28 C23 H23 123.2 . . ?
Rh3 C23 H23 101.8 . . ?
C23 C24 C25 113.3(9) . . ?
C23 C24 Rh3 70.6(6) . . ?
C25 C24 Rh3 96.7(7) . . ?
C23 C24 H24 123.4 . . ?
C25 C24 H24 123.4 . . ?
Rh3 C24 H24 101.3 . . ?
C26 C25 C24 99.6(8) . . ?
C26 C25 C47 107.4(8) . . ?
C24 C25 C47 107.3(8) . . ?
C26 C25 H25 113.8 . . ?
C24 C25 H25 113.8 . . ?
C47 C25 H25 113.8 . . ?
C27 C26 C25 113.6(10) . . ?
C27 C26 Rh3 69.2(6) . . ?
C25 C26 Rh3 97.0(6) . . ?
C27 C26 H26 123.2 . . ?
C25 C26 H26 123.2 . . ?
Rh3 C26 H26 102.3 . . ?
C26 C27 C28 113.9(10) . . ?
C26 C27 Rh3 73.2(6) . . ?
C28 C27 Rh3 96.8(7) . . ?
C26 C27 H27 123.0 . . ?
C28 C27 H27 123.0 . . ?
Rh3 C27 H27 99.0 . . ?
C27 C28 C52 111.0(8) . . ?
C27 C28 C23 99.3(8) . . ?
C52 C28 C23 105.1(9) . . ?
C27 C28 H28 113.4 . . ?
C52 C28 H28 113.4 . . ?
C23 C28 H28 113.4 . . ?
C30 C29 C34 113.3(10) . . ?
C30 C29 Rh4 69.7(7) . . ?
C34 C29 Rh4 98.5(8) . . ?
C30 C29 H29 123.4 . . ?
C34 C29 H29 123.4 . . ?
Rh4 C29 H29 100.4 . . ?
C29 C30 C31 112.4(9) . . ?
C29 C30 Rh4 71.4(6) . . ?
C31 C30 Rh4 98.2(7) . . ?
C29 C30 H30 123.8 . . ?
C31 C30 H30 123.8 . . ?
Rh4 C30 H30 99.1 . . ?
C53 C31 C30 109.3(9) . . ?
C53 C31 C32 109.2(10) . . ?
C30 C31 C32 96.6(8) . . ?
C53 C31 H31 113.5 . . ?
C30 C31 H31 113.5 . . ?
C32 C31 H31 113.5 . . ?
C33 C32 C31 114.6(11) . . ?
C33 C32 Rh4 74.4(7) . . ?
C31 C32 Rh4 97.3(6) . . ?
C33 C32 H32 122.7 . . ?
C31 C32 H32 122.7 . . ?
Rh4 C32 H32 97.6 . . ?
C32 C33 C34 112.9(10) . . ?
C32 C33 Rh4 68.8(7) . . ?
C34 C33 Rh4 95.9(7) . . ?
C32 C33 H33 123.6 . . ?
C34 C33 H33 123.6 . . ?
Rh4 C33 H33 103.5 . . ?
C58 C34 C33 107.9(10) . . ?
C58 C34 C29 109.3(9) . . ?
C33 C34 C29 98.9(10) . . ?
C58 C34 H34 113.2 . . ?
C33 C34 H34 113.2 . . ?
C29 C34 H34 113.2 . . ?
C36 C35 C40 118.9(11) . . ?
C36 C35 C13 130.6(11) . . ?
C40 C35 C13 110.4(10) . . ?
C37 C36 F1 117.3(11) . . ?
C37 C36 C35 122.8(12) . . ?
F1 C36 C35 119.9(11) . . ?
F2 C37 C36 122.2(11) . . ?
F2 C37 C38 119.1(12) . . ?
C36 C37 C38 118.6(12) . . ?
F3 C38 C37 120.9(12) . . ?
F3 C38 C39 119.2(12) . . ?
C37 C38 C39 119.9(12) . . ?
F4 C39 C40 122.0(11) . . ?
F4 C39 C38 117.7(11) . . ?
C40 C39 C38 120.3(11) . . ?
C39 C40 C35 119.5(11) . . ?
C39 C40 C16 126.8(11) . . ?
C35 C40 C16 113.6(10) . . ?
C42 C41 C46 119.8(10) . . ?
C42 C41 C19 128.2(10) . . ?
C46 C41 C19 112.0(9) . . ?
C41 C42 F5 120.6(10) . . ?
C41 C42 C43 121.9(11) . . ?
F5 C42 C43 117.5(10) . . ?
F6 C43 C42 121.6(11) . . ?
F6 C43 C44 120.4(10) . . ?
C42 C43 C44 118.0(10) . . ?
C45 C44 F7 120.4(11) . . ?
C45 C44 C43 120.8(11) . . ?
F7 C44 C43 118.9(11) . . ?
C44 C45 F8 118.1(10) . . ?
C44 C45 C46 119.6(11) . . ?
F8 C45 C46 122.3(9) . . ?
C45 C46 C41 120.0(10) . . ?
C45 C46 C22 125.1(10) . . ?
C41 C46 C22 114.9(9) . . ?
C52 C47 C48 117.0(10) . . ?
C52 C47 C25 115.1(10) . . ?
C48 C47 C25 127.9(10) . . ?
C49 C48 F9 119.6(11) . . ?
C49 C48 C47 121.9(11) . . ?
F9 C48 C47 118.5(10) . . ?
C50 C49 F10 120.1(11) . . ?
C50 C49 C48 121.0(12) . . ?
F10 C49 C48 118.9(11) . . ?
F11 C50 C49 121.0(12) . . ?
F11 C50 C51 121.6(12) . . ?
C49 C50 C51 117.5(12) . . ?
F12 C51 C52 118.7(10) . . ?
F12 C51 C50 118.0(10) . . ?
C52 C51 C50 123.1(11) . . ?
C47 C52 C51 119.4(11) . . ?
C47 C52 C28 111.9(10) . . ?
C51 C52 C28 128.4(10) . . ?
C54 C53 C58 117.9(13) . . ?
C54 C53 C31 128.9(12) . . ?
C58 C53 C31 113.1(10) . . ?
C55 C54 F13 119.3(12) . . ?
C55 C54 C53 122.6(14) . . ?
F13 C54 C53 118.1(13) . . ?
C54 C55 F14 120.0(15) . . ?
C54 C55 C56 118.8(13) . . ?
F14 C55 C56 121.2(14) . . ?
F15 C56 C57 120.7(13) . . ?
F15 C56 C55 117.5(12) . . ?
C57 C56 C55 121.8(14) . . ?
F16 C57 C56 119.0(12) . . ?
F16 C57 C58 123.3(11) . . ?
C56 C57 C58 117.7(13) . . ?
C57 C58 C53 121.1(11) . . ?
C57 C58 C34 125.3(12) . . ?
C53 C58 C34 113.6(12) . . ?
C65 P1 C59 104.5(6) . . ?
C65 P1 C71 107.9(6) . . ?
C59 P1 C71 107.4(5) . . ?
C65 P1 Au1 113.0(4) . . ?
C59 P1 Au1 113.0(5) . . ?
C71 P1 Au1 110.6(4) . . ?
C64 C59 C60 117.6(12) . . ?
C64 C59 P1 121.7(10) . . ?
C60 C59 P1 120.6(11) . . ?
C61 C60 C59 121.1(13) . . ?
C61 C60 H60 119.4 . . ?
C59 C60 H60 119.4 . . ?
C60 C61 C62 118.9(13) . . ?
C60 C61 H61 120.6 . . ?
C62 C61 H61 120.6 . . ?
C63 C62 C61 119.7(14) . . ?
C63 C62 H62 120.2 . . ?
C61 C62 H62 120.2 . . ?
C62 C63 C64 121.9(16) . . ?
C62 C63 H63 119.0 . . ?
C64 C63 H63 119.0 . . ?
C63 C64 C59 120.6(13) . . ?
C63 C64 H64 119.7 . . ?
C59 C64 H64 119.7 . . ?
C70 C65 C66 119.0(11) . . ?
C70 C65 P1 122.4(10) . . ?
C66 C65 P1 118.5(9) . . ?
C67 C66 C65 120.2(11) . . ?
C67 C66 H66 119.9 . . ?
C65 C66 H66 119.9 . . ?
C68 C67 C66 118.1(12) . . ?
C68 C67 H67 121.0 . . ?
C66 C67 H67 121.0 . . ?
C69 C68 C67 121.4(12) . . ?
C69 C68 H68 119.3 . . ?
C67 C68 H68 119.3 . . ?
C68 C69 C70 119.1(13) . . ?
C68 C69 H69 120.4 . . ?
C70 C69 H69 120.4 . . ?
C65 C70 C69 121.9(12) . . ?
C65 C70 H70 119.0 . . ?
C69 C70 H70 119.0 . . ?
C76 C71 C72 119.0(12) . . ?
C76 C71 P1 125.1(10) . . ?
C72 C71 P1 115.8(10) . . ?
C73 C72 C71 118.4(13) . . ?
C73 C72 H72 120.8 . . ?
C71 C72 H72 120.8 . . ?
C72 C73 C74 121.9(13) . . ?
C72 C73 H73 119.0 . . ?
C74 C73 H73 119.0 . . ?
C73 C74 C75 119.0(13) . . ?
C73 C74 H74 120.5 . . ?
C75 C74 H74 120.5 . . ?
C76 C75 C74 120.1(14) . . ?
C76 C75 H75 120.0 . . ?
C74 C75 H75 120.0 . . ?
C75 C76 C71 121.4(12) . . ?
C75 C76 H76 119.3 . . ?
C71 C76 H76 119.3 . . ?
C83 P2 C77 106.7(6) . . ?
C83 P2 C89 107.0(5) . . ?
C77 P2 C89 109.5(6) . . ?
C83 P2 Au2 113.3(4) . . ?
C77 P2 Au2 110.5(4) . . ?
C89 P2 Au2 109.7(4) . . ?
C78 C77 C82 115.3(13) . . ?
C78 C77 P2 125.0(10) . . ?
C82 C77 P2 119.1(10) . . ?
C77 C78 C79 124.9(14) . . ?
C77 C78 H78 117.6 . . ?
C79 C78 H78 117.6 . . ?
C80 C79 C78 118.7(14) . . ?
C80 C79 H79 120.6 . . ?
C78 C79 H79 120.6 . . ?
C79 C80 C81 119.2(15) . . ?
C79 C80 H80 120.4 . . ?
C81 C80 H80 120.4 . . ?
C80 C81 C82 120.0(14) . . ?
C80 C81 H81 120.0 . . ?
C82 C81 H81 120.0 . . ?
C81 C82 C77 121.9(14) . . ?
C81 C82 H82 119.1 . . ?
C77 C82 H82 119.1 . . ?
C88 C83 C84 120.8(10) . . ?
C88 C83 P2 117.1(9) . . ?
C84 C83 P2 122.1(9) . . ?
C85 C84 C83 118.8(11) . . ?
C85 C84 H84 120.6 . . ?
C83 C84 H84 120.6 . . ?
C84 C85 C86 122.6(12) . . ?
C84 C85 H85 118.7 . . ?
C86 C85 H85 118.7 . . ?
C87 C86 C85 120.3(11) . . ?
C87 C86 H86 119.8 . . ?
C85 C86 H86 119.8 . . ?
C86 C87 C88 118.5(11) . . ?
C86 C87 H87 120.8 . . ?
C88 C87 H87 120.8 . . ?
C83 C88 C87 119.0(11) . . ?
C83 C88 H88 120.5 . . ?
C87 C88 H88 120.5 . . ?
C90 C89 C94 117.2(12) . . ?
C90 C89 P2 124.7(11) . . ?
C94 C89 P2 118.0(10) . . ?
C91 C90 C89 119.0(14) . . ?
C91 C90 H90 120.5 . . ?
C89 C90 H90 120.5 . . ?
C92 C91 C90 122.5(14) . . ?
C92 C91 H91 118.7 . . ?
C90 C91 H91 118.7 . . ?
C93 C92 C91 119.3(14) . . ?
C93 C92 H92 120.3 . . ?
C91 C92 H92 120.3 . . ?
C92 C93 C94 119.8(14) . . ?
C92 C93 H93 120.1 . . ?
C94 C93 H93 120.1 . . ?
C89 C94 C93 122.0(13) . . ?
C89 C94 H94 119.0 . . ?
C93 C94 H94 119.0 . . ?
O2 Cl1 O3 108.6(6) . . ?
O2 Cl1 O4 110.1(6) . . ?
O3 Cl1 O4 109.5(6) . . ?
O2 Cl1 O1 111.0(5) . . ?
O3 Cl1 O1 109.2(5) . . ?
O4 Cl1 O1 108.4(6) . . ?
O7B Cl2 O6B 114.9(13) . . ?
O7B Cl2 O8B 104.2(12) . . ?
O6B Cl2 O8B 122.8(16) . . ?
O6A Cl2 O5 110.4(10) . . ?
O7B Cl2 O5 101.3(10) . . ?
O6B Cl2 O5 102.3(11) . . ?
O8B Cl2 O5 109.2(12) . . ?
O6A Cl2 O7A 108.1(13) . . ?
O5 Cl2 O7A 120.2(12) . . ?
O6A Cl2 O8A 103.8(17) . . ?
O5 Cl2 O8A 104.8(15) . . ?
O7A Cl2 O8A 108.2(15) . . ?
C1SB C1SA Cl3S 80.3(17) . . ?
C1SB C1SA Cl4S 75.0(16) . . ?
Cl3S C1SA Cl4S 111.8(10) . . ?
C1SA C1SB Cl4S 74.4(17) . . ?
C1SA C1SB Cl3S 69.1(16) . . ?
Cl4S C1SB Cl3S 107.2(12) . . ?
Cl8S C2S Cl7S 123(2) . . ?
Cl8S C2S C3S 70.9(14) . . ?
Cl7S C2S C3S 70.3(14) . . ?
Cl8S C2S Cl5S 173.6(17) . . ?
Cl7S C2S Cl5S 56.7(10) . . ?
C3S C2S Cl5S 104.2(17) . . ?
Cl8S C2S Cl6S 84.3(12) . . ?
Cl7S C2S Cl6S 63.6(10) . . ?
C3S C2S Cl6S 99(2) . . ?
Cl5S C2S Cl6S 100.7(9) . . ?
Cl7S Cl5S C2S 55.2(9) . . ?
Cl7S Cl6S C2S 49.0(8) . . ?
Cl7S Cl6S Cl8S 80.4(9) . . ?
C2S C3S Cl8S 52.6(13) . . ?
C2S C3S Cl7S 53.8(12) . . ?
Cl8S C3S Cl7S 96.7(17) . . ?
C2S Cl7S Cl5S 68.1(11) . . ?
C2S Cl7S C3S 55.9(16) . . ?
Cl5S Cl7S C3S 102(2) . . ?
C2S Cl7S Cl6S 67.4(9) . . ?
Cl5S Cl7S Cl6S 110.3(12) . . ?
C3S Cl7S Cl6S 94.0(15) . . ?
C2S Cl8S C3S 56.5(17) . . ?
C2S Cl8S Cl6S 54.9(10) . . ?
C3S Cl8S Cl6S 80.0(14) . . ?
O1S C5S C4S 122.9(14) . . ?
O1S C5S C6S 117.4(13) . . ?
C4S C5S C6S 119.0(12) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P1 2.254(3) . ?
Au1 S3 2.328(3) . ?
Au2 P2 2.247(3) . ?
Au2 S2 2.330(3) . ?
Rh1 C11 2.120(11) . ?
Rh1 C12 2.126(11) . ?
Rh1 C15 2.145(10) . ?
Rh1 C14 2.176(10) . ?
Rh1 S1 2.366(3) . ?
Rh1 S3 2.370(3) . ?
Rh2 N1 2.113(8) . ?
Rh2 C20 2.133(10) . ?
Rh2 C21 2.137(10) . ?
Rh2 C17 2.156(10) . ?
Rh2 C18 2.158(10) . ?
Rh2 S1 2.358(3) . ?
Rh3 C27 2.107(9) . ?
Rh3 N2 2.115(8) . ?
Rh3 C23 2.123(10) . ?
Rh3 C24 2.145(10) . ?
Rh3 C26 2.157(10) . ?
Rh3 S4 2.363(3) . ?
Rh4 C30 2.110(10) . ?
Rh4 C32 2.129(10) . ?
Rh4 C29 2.133(12) . ?
Rh4 C33 2.199(10) . ?
Rh4 S2 2.374(3) . ?
Rh4 S4 2.380(3) . ?
S1 C10 1.757(10) . ?
S2 C6 1.774(11) . ?
S3 C1 1.752(11) . ?
S4 C5 1.790(10) . ?
N1 C5 1.344(12) . ?
N1 C1 1.365(11) . ?
N2 C6 1.362(12) . ?
N2 C10 1.364(12) . ?
C1 C2 1.334(13) . ?
C2 C3 1.377(13) . ?
C2 H2 0.9500 . ?
C3 C4 1.375(12) . ?
C3 H3 0.9500 . ?
C4 C5 1.374(13) . ?
C4 H4 0.9500 . ?
C6 C7 1.359(13) . ?
C7 C8 1.422(13) . ?
C7 H7 0.9500 . ?
C8 C9 1.404(13) . ?
C8 H8 0.9500 . ?
C9 C10 1.382(13) . ?
C9 H9 0.9500 . ?
C11 C12 1.345(13) . ?
C11 C16 1.514(13) . ?
C11 H11 0.9500 . ?
C12 C13 1.542(13) . ?
C12 H12 0.9500 . ?
C13 C14 1.472(15) . ?
C13 C35 1.518(15) . ?
C13 H13 1.0000 . ?
C14 C15 1.345(13) . ?
C14 H14 0.9500 . ?
C15 C16 1.536(15) . ?
C15 H15 0.9500 . ?
C16 C40 1.502(15) . ?
C16 H16 1.0000 . ?
C17 C18 1.402(13) . ?
C17 C22 1.522(14) . ?
C17 H17 0.9500 . ?
C18 C19 1.537(13) . ?
C18 H18 0.9500 . ?
C19 C20 1.504(14) . ?
C19 C41 1.540(13) . ?
C19 H19 1.0000 . ?
C20 C21 1.397(13) . ?
C20 H20 0.9500 . ?
C21 C22 1.561(13) . ?
C21 H21 0.9500 . ?
C22 C46 1.532(13) . ?
C22 H22 1.0000 . ?
C23 C24 1.360(13) . ?
C23 C28 1.539(13) . ?
C23 H23 0.9500 . ?
C24 C25 1.521(13) . ?
C24 H24 0.9500 . ?
C25 C26 1.496(14) . ?
C25 C47 1.522(13) . ?
C25 H25 1.0000 . ?
C26 C27 1.376(13) . ?
C26 H26 0.9500 . ?
C27 C28 1.490(13) . ?
C27 H27 0.9500 . ?
C28 C52 1.520(14) . ?
C28 H28 1.0000 . ?
C29 C30 1.413(14) . ?
C29 C34 1.531(14) . ?
C29 H29 0.9500 . ?
C30 C31 1.535(13) . ?
C30 H30 0.9500 . ?
C31 C53 1.507(15) . ?
C31 C32 1.540(14) . ?
C31 H31 1.0000 . ?
C32 C33 1.366(15) . ?
C32 H32 0.9500 . ?
C33 C34 1.527(16) . ?
C33 H33 0.9500 . ?
C34 C58 1.509(14) . ?
C34 H34 1.0000 . ?
C35 C36 1.367(15) . ?
C35 C40 1.405(14) . ?
C36 C37 1.357(15) . ?
C36 F1 1.362(12) . ?
C37 F2 1.331(13) . ?
C37 C38 1.391(15) . ?
C38 F3 1.335(13) . ?
C38 C39 1.397(16) . ?
C39 F4 1.345(11) . ?
C39 C40 1.369(15) . ?
C41 C42 1.327(13) . ?
C41 C46 1.376(13) . ?
C42 F5 1.376(11) . ?
C42 C43 1.374(14) . ?
C43 F6 1.358(11) . ?
C43 C44 1.380(15) . ?
C44 C45 1.354(14) . ?
C44 F7 1.365(11) . ?
C45 F8 1.350(11) . ?
C45 C46 1.367(13) . ?
C47 C52 1.364(13) . ?
C47 C48 1.407(14) . ?
C48 C49 1.370(14) . ?
C48 F9 1.399(11) . ?
C49 C50 1.337(15) . ?
C49 F10 1.341(12) . ?
C50 F11 1.320(12) . ?
C50 C51 1.380(15) . ?
C51 F12 1.374(12) . ?
C51 C52 1.378(13) . ?
C53 C54 1.377(15) . ?
C53 C58 1.406(15) . ?
C54 C55 1.336(18) . ?
C54 F13 1.364(13) . ?
C55 F14 1.350(13) . ?
C55 C56 1.403(18) . ?
C56 F15 1.339(14) . ?
C56 C57 1.371(16) . ?
C57 F16 1.303(13) . ?
C57 C58 1.390(16) . ?
P1 C65 1.800(11) . ?
P1 C59 1.811(12) . ?
P1 C71 1.817(12) . ?
C59 C64 1.372(18) . ?
C59 C60 1.387(14) . ?
C60 C61 1.352(16) . ?
C60 H60 0.9500 . ?
C61 C62 1.394(18) . ?
C61 H61 0.9500 . ?
C62 C63 1.319(16) . ?
C62 H62 0.9500 . ?
C63 C64 1.344(17) . ?
C63 H63 0.9500 . ?
C64 H64 0.9500 . ?
C65 C70 1.337(14) . ?
C65 C66 1.425(15) . ?
C66 C67 1.389(14) . ?
C66 H66 0.9500 . ?
C67 C68 1.385(15) . ?
C67 H67 0.9500 . ?
C68 C69 1.380(16) . ?
C68 H68 0.9500 . ?
C69 C70 1.380(15) . ?
C69 H69 0.9500 . ?
C70 H70 0.9500 . ?
C71 C76 1.379(15) . ?
C71 C72 1.404(14) . ?
C72 C73 1.374(16) . ?
C72 H72 0.9500 . ?
C73 C74 1.369(17) . ?
C73 H73 0.9500 . ?
C74 C75 1.383(15) . ?
C74 H74 0.9500 . ?
C75 C76 1.354(15) . ?
C75 H75 0.9500 . ?
C76 H76 0.9500 . ?
P2 C83 1.804(11) . ?
P2 C77 1.803(13) . ?
P2 C89 1.815(12) . ?
C77 C78 1.311(16) . ?
C77 C82 1.389(15) . ?
C78 C79 1.399(17) . ?
C78 H78 0.9500 . ?
C79 C80 1.342(17) . ?
C79 H79 0.9500 . ?
C80 C81 1.362(17) . ?
C80 H80 0.9500 . ?
C81 C82 1.380(16) . ?
C81 H81 0.9500 . ?
C82 H82 0.9500 . ?
C83 C88 1.383(14) . ?
C83 C84 1.410(14) . ?
C84 C85 1.318(14) . ?
C84 H84 0.9500 . ?
C85 C86 1.380(14) . ?
C85 H85 0.9500 . ?
C86 C87 1.382(14) . ?
C86 H86 0.9500 . ?
C87 C88 1.414(14) . ?
C87 H87 0.9500 . ?
C88 H88 0.9500 . ?
C89 C90 1.380(15) . ?
C89 C94 1.388(16) . ?
C90 C91 1.383(15) . ?
C90 H90 0.9500 . ?
C91 C92 1.370(17) . ?
C91 H91 0.9500 . ?
C92 C93 1.319(16) . ?
C92 H92 0.9500 . ?
C93 C94 1.399(15) . ?
C93 H93 0.9500 . ?
C94 H94 0.9500 . ?
Cl1 O2 1.411(9) . ?
Cl1 O3 1.419(8) . ?
Cl1 O4 1.433(9) . ?
Cl1 O1 1.435(8) . ?
Cl2 O6A 1.397(14) . ?
Cl2 O7B 1.417(12) . ?
Cl2 O6B 1.417(14) . ?
Cl2 O8B 1.419(14) . ?
Cl2 O5 1.435(9) . ?
Cl2 O7A 1.452(14) . ?
Cl2 O8A 1.487(16) . ?
O6A O6B 0.90(3) . ?
O7A O7B 0.83(2) . ?
C1SA C1SB 0.96(4) . ?
C1SA Cl3S 1.758(15) . ?
C1SA Cl4S 1.815(16) . ?
C1SB Cl4S 1.820(19) . ?
C1SB Cl3S 1.856(19) . ?
C2S Cl8S 1.52(3) . ?
C2S Cl7S 1.55(2) . ?
C2S C3S 1.59(4) . ?
C2S Cl5S 1.754(16) . ?
C2S Cl6S 1.899(16) . ?
Cl5S Cl7S 1.58(2) . ?
Cl6S Cl7S 1.841(19) . ?
Cl6S Cl8S 2.31(3) . ?
C3S Cl8S 1.804(19) . ?
C3S Cl7S 1.811(19) . ?
O1S C5S 1.182(13) . ?
C4S C5S 1.426(18) . ?
C5S C6S 1.547(18) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 Rh2 S1 C10 19.8(4) . . . . ?
C20 Rh2 S1 C10 126.8(7) . . . . ?
C21 Rh2 S1 C10 -106.2(15) . . . . ?
C17 Rh2 S1 C10 -141.6(5) . . . . ?
C18 Rh2 S1 C10 -179.6(4) . . . . ?
N1 Rh2 S1 Rh1 -89.7(2) . . . . ?
C20 Rh2 S1 Rh1 17.2(6) . . . . ?
C21 Rh2 S1 Rh1 144.2(15) . . . . ?
C17 Rh2 S1 Rh1 108.9(3) . . . . ?
C18 Rh2 S1 Rh1 70.8(3) . . . . ?
C11 Rh1 S1 C10 138.0(5) . . . . ?
C12 Rh1 S1 C10 101.7(5) . . . . ?
C15 Rh1 S1 C10 178.0(7) . . . . ?
C14 Rh1 S1 C10 98.6(10) . . . . ?
S3 Rh1 S1 C10 -56.4(4) . . . . ?
C11 Rh1 S1 Rh2 -116.2(3) . . . . ?
C12 Rh1 S1 Rh2 -152.5(3) . . . . ?
C15 Rh1 S1 Rh2 -76.2(6) . . . . ?
C14 Rh1 S1 Rh2 -155.6(9) . . . . ?
S3 Rh1 S1 Rh2 49.39(10) . . . . ?
C30 Rh4 S2 C6 135.8(10) . . . . ?
C32 Rh4 S2 C6 163.3(6) . . . . ?
C29 Rh4 S2 C6 -118.4(7) . . . . ?
C33 Rh4 S2 C6 -159.9(5) . . . . ?
S4 Rh4 S2 C6 12.6(4) . . . . ?
C30 Rh4 S2 Au2 -128.7(9) . . . . ?
C32 Rh4 S2 Au2 -101.1(4) . . . . ?
C29 Rh4 S2 Au2 -22.9(6) . . . . ?
C33 Rh4 S2 Au2 -64.4(3) . . . . ?
S4 Rh4 S2 Au2 108.16(9) . . . . ?
C11 Rh1 S3 C1 136.6(10) . . . . ?
C12 Rh1 S3 C1 -115.0(7) . . . . ?
C15 Rh1 S3 C1 163.5(5) . . . . ?
C14 Rh1 S3 C1 -160.2(5) . . . . ?
S1 Rh1 S3 C1 12.0(4) . . . . ?
C11 Rh1 S3 Au1 -127.5(10) . . . . ?
C12 Rh1 S3 Au1 -19.1(6) . . . . ?
C15 Rh1 S3 Au1 -100.6(3) . . . . ?
C14 Rh1 S3 Au1 -64.3(3) . . . . ?
S1 Rh1 S3 Au1 107.88(9) . . . . ?
C27 Rh3 S4 C5 174.4(5) . . . . ?
N2 Rh3 S4 C5 22.2(4) . . . . ?
C23 Rh3 S4 C5 122.0(7) . . . . ?
C24 Rh3 S4 C5 -109.6(11) . . . . ?
C26 Rh3 S4 C5 -147.6(5) . . . . ?
C27 Rh3 S4 Rh4 63.4(3) . . . . ?
N2 Rh3 S4 Rh4 -88.7(2) . . . . ?
C23 Rh3 S4 Rh4 11.0(6) . . . . ?
C24 Rh3 S4 Rh4 139.5(11) . . . . ?
C26 Rh3 S4 Rh4 101.5(3) . . . . ?
C30 Rh4 S4 C5 139.8(5) . . . . ?
C32 Rh4 S4 C5 -177.6(7) . . . . ?
C29 Rh4 S4 C5 101.8(5) . . . . ?
C33 Rh4 S4 C5 97.0(11) . . . . ?
S2 Rh4 S4 C5 -56.1(4) . . . . ?
C30 Rh4 S4 Rh3 -115.3(3) . . . . ?
C32 Rh4 S4 Rh3 -72.7(6) . . . . ?
C29 Rh4 S4 Rh3 -153.3(3) . . . . ?
C33 Rh4 S4 Rh3 -158.1(10) . . . . ?
S2 Rh4 S4 Rh3 48.77(10) . . . . ?
C20 Rh2 N1 C5 110.0(9) . . . . ?
C21 Rh2 N1 C5 71.5(9) . . . . ?
C17 Rh2 N1 C5 30.2(14) . . . . ?
C18 Rh2 N1 C5 149.2(10) . . . . ?
S1 Rh2 N1 C5 -99.1(8) . . . . ?
C20 Rh2 N1 C1 -71.7(8) . . . . ?
C21 Rh2 N1 C1 -110.2(8) . . . . ?
C17 Rh2 N1 C1 -151.5(9) . . . . ?
C18 Rh2 N1 C1 -32.5(15) . . . . ?
S1 Rh2 N1 C1 79.1(8) . . . . ?
C27 Rh3 N2 C6 -29.5(13) . . . . ?
C23 Rh3 N2 C6 -75.5(9) . . . . ?
C24 Rh3 N2 C6 -112.6(8) . . . . ?
C26 Rh3 N2 C6 -137.6(12) . . . . ?
S4 Rh3 N2 C6 78.4(8) . . . . ?
C27 Rh3 N2 C10 149.4(9) . . . . ?
C23 Rh3 N2 C10 103.3(9) . . . . ?
C24 Rh3 N2 C10 66.2(9) . . . . ?
C26 Rh3 N2 C10 41.2(17) . . . . ?
S4 Rh3 N2 C10 -102.8(8) . . . . ?
C5 N1 C1 C2 -1.8(15) . . . . ?
Rh2 N1 C1 C2 179.9(8) . . . . ?
C5 N1 C1 S3 -179.3(8) . . . . ?
Rh2 N1 C1 S3 2.4(11) . . . . ?
Au1 S3 C1 C2 47.3(10) . . . . ?
Rh1 S3 C1 C2 132.9(9) . . . . ?
Au1 S3 C1 N1 -135.3(8) . . . . ?
Rh1 S3 C1 N1 -49.7(9) . . . . ?
N1 C1 C2 C3 0.4(17) . . . . ?
S3 C1 C2 C3 177.7(8) . . . . ?
C1 C2 C3 C4 2.7(16) . . . . ?
C2 C3 C4 C5 -4.3(15) . . . . ?
C1 N1 C5 C4 0.1(16) . . . . ?
Rh2 N1 C5 C4 178.3(8) . . . . ?
C1 N1 C5 S4 178.0(8) . . . . ?
Rh2 N1 C5 S4 -3.8(12) . . . . ?
C3 C4 C5 N1 3.0(16) . . . . ?
C3 C4 C5 S4 -174.8(8) . . . . ?
Rh3 S4 C5 N1 62.6(9) . . . . ?
Rh4 S4 C5 N1 151.9(7) . . . . ?
Rh3 S4 C5 C4 -119.5(9) . . . . ?
Rh4 S4 C5 C4 -30.1(10) . . . . ?
C10 N2 C6 C7 -2.8(17) . . . . ?
Rh3 N2 C6 C7 176.0(8) . . . . ?
C10 N2 C6 S2 -177.8(8) . . . . ?
Rh3 N2 C6 S2 1.1(12) . . . . ?
Au2 S2 C6 N2 -133.8(8) . . . . ?
Rh4 S2 C6 N2 -49.4(10) . . . . ?
Au2 S2 C6 C7 51.2(10) . . . . ?
Rh4 S2 C6 C7 135.6(9) . . . . ?
N2 C6 C7 C8 4.6(17) . . . . ?
S2 C6 C7 C8 179.3(9) . . . . ?
C6 C7 C8 C9 -5.9(17) . . . . ?
C7 C8 C9 C10 5.5(17) . . . . ?
C6 N2 C10 C9 2.4(17) . . . . ?
Rh3 N2 C10 C9 -176.4(8) . . . . ?
C6 N2 C10 S1 177.6(8) . . . . ?
Rh3 N2 C10 S1 -1.3(12) . . . . ?
C8 C9 C10 N2 -3.8(17) . . . . ?
C8 C9 C10 S1 -178.7(8) . . . . ?
Rh2 S1 C10 N2 62.6(9) . . . . ?
Rh1 S1 C10 N2 149.8(7) . . . . ?
Rh2 S1 C10 C9 -122.3(9) . . . . ?
Rh1 S1 C10 C9 -35.1(11) . . . . ?
C15 Rh1 C11 C12 103.2(7) . . . . ?
C14 Rh1 C11 C12 67.1(7) . . . . ?
S1 Rh1 C11 C12 -100.9(6) . . . . ?
S3 Rh1 C11 C12 132.7(9) . . . . ?
C12 Rh1 C11 C16 -113.8(9) . . . . ?
C15 Rh1 C11 C16 -10.6(6) . . . . ?
C14 Rh1 C11 C16 -46.8(7) . . . . ?
S1 Rh1 C11 C16 145.3(6) . . . . ?
S3 Rh1 C11 C16 18.9(14) . . . . ?
C16 C11 C12 C13 2.8(15) . . . . ?
Rh1 C11 C12 C13 -87.2(9) . . . . ?
C16 C11 C12 Rh1 90.0(9) . . . . ?
C15 Rh1 C12 C11 -64.9(6) . . . . ?
C14 Rh1 C12 C11 -101.1(7) . . . . ?
S1 Rh1 C12 C11 80.0(6) . . . . ?
S3 Rh1 C12 C11 -151.5(5) . . . . ?
C11 Rh1 C12 C13 110.7(9) . . . . ?
C15 Rh1 C12 C13 45.8(6) . . . . ?
C14 Rh1 C12 C13 9.7(6) . . . . ?
S1 Rh1 C12 C13 -169.3(6) . . . . ?
S3 Rh1 C12 C13 -40.8(10) . . . . ?
C11 C12 C13 C14 58.0(12) . . . . ?
Rh1 C12 C13 C14 -13.5(8) . . . . ?
C11 C12 C13 C35 -58.5(13) . . . . ?
Rh1 C12 C13 C35 -130.1(8) . . . . ?
C35 C13 C14 C15 57.0(13) . . . . ?
C12 C13 C14 C15 -57.5(12) . . . . ?
C35 C13 C14 Rh1 127.7(8) . . . . ?
C12 C13 C14 Rh1 13.2(8) . . . . ?
C11 Rh1 C14 C15 65.4(8) . . . . ?
C12 Rh1 C14 C15 102.5(8) . . . . ?
S1 Rh1 C14 C15 105.8(10) . . . . ?
S3 Rh1 C14 C15 -98.6(7) . . . . ?
C11 Rh1 C14 C13 -47.3(7) . . . . ?
C12 Rh1 C14 C13 -10.1(6) . . . . ?
C15 Rh1 C14 C13 -112.6(11) . . . . ?
S1 Rh1 C14 C13 -6.8(15) . . . . ?
S3 Rh1 C14 C13 148.8(6) . . . . ?
C13 C14 C15 C16 -2.7(14) . . . . ?
Rh1 C14 C15 C16 -89.0(8) . . . . ?
C13 C14 C15 Rh1 86.3(8) . . . . ?
C11 Rh1 C15 C14 -102.8(8) . . . . ?
C12 Rh1 C15 C14 -66.1(8) . . . . ?
S1 Rh1 C15 C14 -147.7(6) . . . . ?
S3 Rh1 C15 C14 85.8(7) . . . . ?
C11 Rh1 C15 C16 10.4(6) . . . . ?
C12 Rh1 C15 C16 47.1(7) . . . . ?
C14 Rh1 C15 C16 113.2(11) . . . . ?
S1 Rh1 C15 C16 -34.5(10) . . . . ?
S3 Rh1 C15 C16 -161.0(6) . . . . ?
C12 C11 C16 C40 52.9(13) . . . . ?
Rh1 C11 C16 C40 126.3(8) . . . . ?
C12 C11 C16 C15 -59.7(12) . . . . ?
Rh1 C11 C16 C15 13.7(8) . . . . ?
C14 C15 C16 C40 -51.4(12) . . . . ?
Rh1 C15 C16 C40 -125.6(8) . . . . ?
C14 C15 C16 C11 60.7(11) . . . . ?
Rh1 C15 C16 C11 -13.5(8) . . . . ?
N1 Rh2 C17 C18 149.6(8) . . . . ?
C20 Rh2 C17 C18 65.7(7) . . . . ?
C21 Rh2 C17 C18 103.9(7) . . . . ?
S1 Rh2 C17 C18 -83.4(6) . . . . ?
N1 Rh2 C17 C22 36.5(13) . . . . ?
C20 Rh2 C17 C22 -47.4(6) . . . . ?
C21 Rh2 C17 C22 -9.2(6) . . . . ?
C18 Rh2 C17 C22 -113.1(9) . . . . ?
S1 Rh2 C17 C22 163.5(5) . . . . ?
C22 C17 C18 C19 1.5(12) . . . . ?
Rh2 C17 C18 C19 -87.4(7) . . . . ?
C22 C17 C18 Rh2 88.9(8) . . . . ?
N1 Rh2 C18 C17 -145.4(9) . . . . ?
C20 Rh2 C18 C17 -102.3(7) . . . . ?
C21 Rh2 C18 C17 -64.7(7) . . . . ?
S1 Rh2 C18 C17 104.1(6) . . . . ?
N1 Rh2 C18 C19 -33.8(14) . . . . ?
C20 Rh2 C18 C19 9.4(6) . . . . ?
C21 Rh2 C18 C19 47.0(6) . . . . ?
C17 Rh2 C18 C19 111.7(9) . . . . ?
S1 Rh2 C18 C19 -144.2(5) . . . . ?
C17 C18 C19 C20 58.9(10) . . . . ?
Rh2 C18 C19 C20 -12.5(7) . . . . ?
C17 C18 C19 C41 -54.9(11) . . . . ?
Rh2 C18 C19 C41 -126.3(7) . . . . ?
C41 C19 C20 C21 54.4(12) . . . . ?
C18 C19 C20 C21 -59.6(11) . . . . ?
C41 C19 C20 Rh2 126.6(7) . . . . ?
C18 C19 C20 Rh2 12.6(7) . . . . ?
N1 Rh2 C20 C21 -90.1(7) . . . . ?
C17 Rh2 C20 C21 66.3(7) . . . . ?
C18 Rh2 C20 C21 104.1(7) . . . . ?
S1 Rh2 C20 C21 165.1(5) . . . . ?
N1 Rh2 C20 C19 156.1(6) . . . . ?
C21 Rh2 C20 C19 -113.8(9) . . . . ?
C17 Rh2 C20 C19 -47.5(6) . . . . ?
C18 Rh2 C20 C19 -9.7(6) . . . . ?
S1 Rh2 C20 C19 51.3(9) . . . . ?
C19 C20 C21 C22 -0.3(13) . . . . ?
Rh2 C20 C21 C22 -89.1(8) . . . . ?
C19 C20 C21 Rh2 88.8(8) . . . . ?
N1 Rh2 C21 C20 95.0(7) . . . . ?
C17 Rh2 C21 C20 -101.7(7) . . . . ?
C18 Rh2 C21 C20 -64.3(7) . . . . ?
S1 Rh2 C21 C20 -139.4(13) . . . . ?
N1 Rh2 C21 C22 -154.3(6) . . . . ?
C20 Rh2 C21 C22 110.6(9) . . . . ?
C17 Rh2 C21 C22 9.0(6) . . . . ?
C18 Rh2 C21 C22 46.4(6) . . . . ?
S1 Rh2 C21 C22 -28.8(19) . . . . ?
C18 C17 C22 C46 51.1(12) . . . . ?
Rh2 C17 C22 C46 123.3(7) . . . . ?
C18 C17 C22 C21 -60.5(11) . . . . ?
Rh2 C17 C22 C21 11.7(7) . . . . ?
C20 C21 C22 C17 59.9(10) . . . . ?
Rh2 C21 C22 C17 -11.8(7) . . . . ?
C20 C21 C22 C46 -53.2(11) . . . . ?
Rh2 C21 C22 C46 -124.9(7) . . . . ?
C27 Rh3 C23 C24 102.0(7) . . . . ?
N2 Rh3 C23 C24 -100.5(6) . . . . ?
C26 Rh3 C23 C24 64.2(6) . . . . ?
S4 Rh3 C23 C24 160.9(5) . . . . ?
C27 Rh3 C23 C28 -11.4(6) . . . . ?
N2 Rh3 C23 C28 146.2(6) . . . . ?
C24 Rh3 C23 C28 -113.4(9) . . . . ?
C26 Rh3 C23 C28 -49.2(6) . . . . ?
S4 Rh3 C23 C28 47.5(10) . . . . ?
C28 C23 C24 C25 -1.7(13) . . . . ?
Rh3 C23 C24 C25 -89.1(8) . . . . ?
C28 C23 C24 Rh3 87.3(8) . . . . ?
C27 Rh3 C24 C23 -66.1(6) . . . . ?
N2 Rh3 C24 C23 84.4(6) . . . . ?
C26 Rh3 C24 C23 -103.5(7) . . . . ?
S4 Rh3 C24 C23 -144.8(9) . . . . ?
C27 Rh3 C24 C25 46.2(6) . . . . ?
N2 Rh3 C24 C25 -163.3(6) . . . . ?
C23 Rh3 C24 C25 112.4(9) . . . . ?
C26 Rh3 C24 C25 8.9(6) . . . . ?
S4 Rh3 C24 C25 -32.5(15) . . . . ?
C23 C24 C25 C26 59.9(11) . . . . ?
Rh3 C24 C25 C26 -11.8(7) . . . . ?
C23 C24 C25 C47 -51.8(12) . . . . ?
Rh3 C24 C25 C47 -123.5(7) . . . . ?
C24 C25 C26 C27 -58.6(10) . . . . ?
C47 C25 C26 C27 53.0(11) . . . . ?
C24 C25 C26 Rh3 11.7(7) . . . . ?
C47 C25 C26 Rh3 123.4(7) . . . . ?
N2 Rh3 C26 C27 130.9(12) . . . . ?
C23 Rh3 C26 C27 66.7(7) . . . . ?
C24 Rh3 C26 C27 103.6(7) . . . . ?
S4 Rh3 C26 C27 -86.3(7) . . . . ?
C27 Rh3 C26 C25 -112.6(10) . . . . ?
N2 Rh3 C26 C25 18.3(16) . . . . ?
C23 Rh3 C26 C25 -46.0(6) . . . . ?
C24 Rh3 C26 C25 -9.0(6) . . . . ?
S4 Rh3 C26 C25 161.1(6) . . . . ?
C25 C26 C27 C28 -1.5(12) . . . . ?
Rh3 C26 C27 C28 -90.1(8) . . . . ?
C25 C26 C27 Rh3 88.6(8) . . . . ?
N2 Rh3 C27 C26 -152.9(8) . . . . ?
C23 Rh3 C27 C26 -101.2(8) . . . . ?
C24 Rh3 C27 C26 -64.0(7) . . . . ?
S4 Rh3 C27 C26 101.5(7) . . . . ?
N2 Rh3 C27 C28 -40.0(12) . . . . ?
C23 Rh3 C27 C28 11.8(6) . . . . ?
C24 Rh3 C27 C28 49.0(6) . . . . ?
C26 Rh3 C27 C28 113.0(10) . . . . ?
S4 Rh3 C27 C28 -145.5(6) . . . . ?
C26 C27 C28 C52 -50.8(12) . . . . ?
Rh3 C27 C28 C52 -125.3(8) . . . . ?
C26 C27 C28 C23 59.4(10) . . . . ?
Rh3 C27 C28 C23 -15.1(8) . . . . ?
C24 C23 C28 C27 -57.7(11) . . . . ?
Rh3 C23 C28 C27 15.0(8) . . . . ?
C24 C23 C28 C52 57.2(11) . . . . ?
Rh3 C23 C28 C52 129.9(7) . . . . ?
C32 Rh4 C29 C30 -66.3(7) . . . . ?
C33 Rh4 C29 C30 -102.9(7) . . . . ?
S2 Rh4 C29 C30 -149.8(5) . . . . ?
S4 Rh4 C29 C30 78.6(6) . . . . ?
C30 Rh4 C29 C34 111.7(9) . . . . ?
C32 Rh4 C29 C34 45.4(7) . . . . ?
C33 Rh4 C29 C34 8.8(6) . . . . ?
S2 Rh4 C29 C34 -38.1(10) . . . . ?
S4 Rh4 C29 C34 -169.6(6) . . . . ?
C34 C29 C30 C31 0.6(14) . . . . ?
Rh4 C29 C30 C31 91.4(8) . . . . ?
C34 C29 C30 Rh4 -90.8(9) . . . . ?
C32 Rh4 C30 C29 100.8(8) . . . . ?
C33 Rh4 C30 C29 64.3(7) . . . . ?
S2 Rh4 C30 C29 131.1(9) . . . . ?
S4 Rh4 C30 C29 -104.2(6) . . . . ?
C32 Rh4 C30 C31 -10.2(7) . . . . ?
C29 Rh4 C30 C31 -111.0(10) . . . . ?
C33 Rh4 C30 C31 -46.7(7) . . . . ?
S2 Rh4 C30 C31 20.1(14) . . . . ?
S4 Rh4 C30 C31 144.8(7) . . . . ?
C29 C30 C31 C53 52.8(12) . . . . ?
Rh4 C30 C31 C53 126.0(8) . . . . ?
C29 C30 C31 C32 -60.3(12) . . . . ?
Rh4 C30 C31 C32 12.9(9) . . . . ?
C53 C31 C32 C33 -49.8(12) . . . . ?
C30 C31 C32 C33 63.3(12) . . . . ?
C53 C31 C32 Rh4 -126.0(8) . . . . ?
C30 C31 C32 Rh4 -12.8(9) . . . . ?
C30 Rh4 C32 C33 -103.5(8) . . . . ?
C29 Rh4 C32 C33 -64.3(7) . . . . ?
S2 Rh4 C32 C33 86.1(7) . . . . ?
S4 Rh4 C32 C33 -151.4(6) . . . . ?
C30 Rh4 C32 C31 10.1(7) . . . . ?
C29 Rh4 C32 C31 49.3(8) . . . . ?
C33 Rh4 C32 C31 113.6(11) . . . . ?
S2 Rh4 C32 C31 -160.3(7) . . . . ?
S4 Rh4 C32 C31 -37.8(12) . . . . ?
C31 C32 C33 C34 -3.4(13) . . . . ?
Rh4 C32 C33 C34 87.5(8) . . . . ?
C31 C32 C33 Rh4 -91.0(8) . . . . ?
C30 Rh4 C33 C32 64.8(7) . . . . ?
C29 Rh4 C33 C32 103.5(8) . . . . ?
S2 Rh4 C33 C32 -97.6(7) . . . . ?
S4 Rh4 C33 C32 108.7(11) . . . . ?
C30 Rh4 C33 C34 -47.5(7) . . . . ?
C32 Rh4 C33 C34 -112.3(10) . . . . ?
C29 Rh4 C33 C34 -8.8(6) . . . . ?
S2 Rh4 C33 C34 150.1(6) . . . . ?
S4 Rh4 C33 C34 -3.5(15) . . . . ?
C32 C33 C34 C58 55.5(13) . . . . ?
Rh4 C33 C34 C58 125.0(8) . . . . ?
C32 C33 C34 C29 -58.2(11) . . . . ?
Rh4 C33 C34 C29 11.3(8) . . . . ?
C30 C29 C34 C58 -52.9(14) . . . . ?
Rh4 C29 C34 C58 -124.4(9) . . . . ?
C30 C29 C34 C33 59.8(11) . . . . ?
Rh4 C29 C34 C33 -11.7(8) . . . . ?
C14 C13 C35 C36 127.3(13) . . . . ?
C12 C13 C35 C36 -121.1(13) . . . . ?
C14 C13 C35 C40 -54.7(13) . . . . ?
C12 C13 C35 C40 56.9(12) . . . . ?
C40 C35 C36 C37 -1.2(18) . . . . ?
C13 C35 C36 C37 176.7(11) . . . . ?
C40 C35 C36 F1 -178.4(10) . . . . ?
C13 C35 C36 F1 -0.6(19) . . . . ?
F1 C36 C37 F2 -0.8(17) . . . . ?
C35 C36 C37 F2 -178.1(11) . . . . ?
F1 C36 C37 C38 177.4(10) . . . . ?
C35 C36 C37 C38 0.1(19) . . . . ?
F2 C37 C38 F3 -1.8(18) . . . . ?
C36 C37 C38 F3 179.9(11) . . . . ?
F2 C37 C38 C39 179.9(10) . . . . ?
C36 C37 C38 C39 1.6(18) . . . . ?
F3 C38 C39 F4 0.8(17) . . . . ?
C37 C38 C39 F4 179.1(10) . . . . ?
F3 C38 C39 C40 179.5(10) . . . . ?
C37 C38 C39 C40 -2.2(18) . . . . ?
F4 C39 C40 C35 179.7(10) . . . . ?
C38 C39 C40 C35 1.0(17) . . . . ?
F4 C39 C40 C16 3.6(18) . . . . ?
C38 C39 C40 C16 -175.1(11) . . . . ?
C36 C35 C40 C39 0.6(17) . . . . ?
C13 C35 C40 C39 -177.6(10) . . . . ?
C36 C35 C40 C16 177.3(10) . . . . ?
C13 C35 C40 C16 -1.0(14) . . . . ?
C11 C16 C40 C39 122.9(12) . . . . ?
C15 C16 C40 C39 -131.4(12) . . . . ?
C11 C16 C40 C35 -53.5(13) . . . . ?
C15 C16 C40 C35 52.2(13) . . . . ?
C20 C19 C41 C42 127.6(13) . . . . ?
C18 C19 C41 C42 -124.1(13) . . . . ?
C20 C19 C41 C46 -53.4(12) . . . . ?
C18 C19 C41 C46 54.9(13) . . . . ?
C46 C41 C42 F5 -177.2(10) . . . . ?
C19 C41 C42 F5 2(2) . . . . ?
C46 C41 C42 C43 0.7(19) . . . . ?
C19 C41 C42 C43 179.7(11) . . . . ?
C41 C42 C43 F6 178.8(11) . . . . ?
F5 C42 C43 F6 -3.2(18) . . . . ?
C41 C42 C43 C44 -0.2(19) . . . . ?
F5 C42 C43 C44 177.8(11) . . . . ?
F6 C43 C44 C45 -179.3(11) . . . . ?
C42 C43 C44 C45 -0.3(19) . . . . ?
F6 C43 C44 F7 0.3(18) . . . . ?
C42 C43 C44 F7 179.3(10) . . . . ?
F7 C44 C45 F8 2.1(17) . . . . ?
C43 C44 C45 F8 -178.4(11) . . . . ?
F7 C44 C45 C46 -179.4(10) . . . . ?
C43 C44 C45 C46 0.2(19) . . . . ?
C44 C45 C46 C41 0.4(18) . . . . ?
F8 C45 C46 C41 178.9(10) . . . . ?
C44 C45 C46 C22 -177.9(11) . . . . ?
F8 C45 C46 C22 0.5(18) . . . . ?
C42 C41 C46 C45 -0.8(19) . . . . ?
C19 C41 C46 C45 -179.9(10) . . . . ?
C42 C41 C46 C22 177.6(11) . . . . ?
C19 C41 C46 C22 -1.5(14) . . . . ?
C17 C22 C46 C45 126.8(12) . . . . ?
C21 C22 C46 C45 -126.9(11) . . . . ?
C17 C22 C46 C41 -51.6(13) . . . . ?
C21 C22 C46 C41 54.7(13) . . . . ?
C26 C25 C47 C52 -55.6(12) . . . . ?
C24 C25 C47 C52 50.7(12) . . . . ?
C26 C25 C47 C48 124.7(12) . . . . ?
C24 C25 C47 C48 -129.0(11) . . . . ?
C52 C47 C48 C49 -2.4(17) . . . . ?
C25 C47 C48 C49 177.2(10) . . . . ?
C52 C47 C48 F9 179.7(9) . . . . ?
C25 C47 C48 F9 -0.7(17) . . . . ?
F9 C48 C49 C50 -179.5(11) . . . . ?
C47 C48 C49 C50 2.6(19) . . . . ?
F9 C48 C49 F10 1.6(16) . . . . ?
C47 C48 C49 F10 -176.3(10) . . . . ?
F10 C49 C50 F11 -1.6(19) . . . . ?
C48 C49 C50 F11 179.5(10) . . . . ?
F10 C49 C50 C51 179.3(10) . . . . ?
C48 C49 C50 C51 0.4(19) . . . . ?
F11 C50 C51 F12 2.0(17) . . . . ?
C49 C50 C51 F12 -178.8(10) . . . . ?
F11 C50 C51 C52 177.3(10) . . . . ?
C49 C50 C51 C52 -3.6(19) . . . . ?
C48 C47 C52 C51 -0.7(16) . . . . ?
C25 C47 C52 C51 179.6(9) . . . . ?
C48 C47 C52 C28 -175.2(9) . . . . ?
C25 C47 C52 C28 5.1(13) . . . . ?
F12 C51 C52 C47 178.9(10) . . . . ?
C50 C51 C52 C47 3.8(17) . . . . ?
F12 C51 C52 C28 -7.5(17) . . . . ?
C50 C51 C52 C28 177.3(11) . . . . ?
C27 C28 C52 C47 48.1(12) . . . . ?
C23 C28 C52 C47 -58.3(11) . . . . ?
C27 C28 C52 C51 -125.8(12) . . . . ?
C23 C28 C52 C51 127.8(11) . . . . ?
C30 C31 C53 C54 127.4(13) . . . . ?
C32 C31 C53 C54 -128.0(13) . . . . ?
C30 C31 C53 C58 -54.3(13) . . . . ?
C32 C31 C53 C58 50.3(13) . . . . ?
C58 C53 C54 C55 0(2) . . . . ?
C31 C53 C54 C55 178.1(12) . . . . ?
C58 C53 C54 F13 -178.9(10) . . . . ?
C31 C53 C54 F13 -0.6(19) . . . . ?
F13 C54 C55 F14 -1(2) . . . . ?
C53 C54 C55 F14 179.8(11) . . . . ?
F13 C54 C55 C56 179.2(11) . . . . ?
C53 C54 C55 C56 1(2) . . . . ?
C54 C55 C56 F15 178.4(12) . . . . ?
F14 C55 C56 F15 -1(2) . . . . ?
C54 C55 C56 C57 0(2) . . . . ?
F14 C55 C56 C57 -179.5(12) . . . . ?
F15 C56 C57 F16 0(2) . . . . ?
C55 C56 C57 F16 178.5(12) . . . . ?
F15 C56 C57 C58 -179.0(11) . . . . ?
C55 C56 C57 C58 0(2) . . . . ?
F16 C57 C58 C53 -178.1(11) . . . . ?
C56 C57 C58 C53 0.8(19) . . . . ?
F16 C57 C58 C34 1(2) . . . . ?
C56 C57 C58 C34 -179.8(12) . . . . ?
C54 C53 C58 C57 -0.5(18) . . . . ?
C31 C53 C58 C57 -179.0(11) . . . . ?
C54 C53 C58 C34 -180.0(11) . . . . ?
C31 C53 C58 C34 1.5(15) . . . . ?
C33 C34 C58 C57 125.9(13) . . . . ?
C29 C34 C58 C57 -127.5(13) . . . . ?
C33 C34 C58 C53 -54.7(13) . . . . ?
C29 C34 C58 C53 52.0(14) . . . . ?
C65 P1 C59 C64 -113.6(12) . . . . ?
C71 P1 C59 C64 131.9(11) . . . . ?
Au1 P1 C59 C64 9.7(13) . . . . ?
C65 P1 C59 C60 63.0(10) . . . . ?
C71 P1 C59 C60 -51.4(11) . . . . ?
Au1 P1 C59 C60 -173.6(8) . . . . ?
C64 C59 C60 C61 -2.1(18) . . . . ?
P1 C59 C60 C61 -178.9(10) . . . . ?
C59 C60 C61 C62 1(2) . . . . ?
C60 C61 C62 C63 -2(2) . . . . ?
C61 C62 C63 C64 3(3) . . . . ?
C62 C63 C64 C59 -4(3) . . . . ?
C60 C59 C64 C63 4(2) . . . . ?
P1 C59 C64 C63 -179.7(12) . . . . ?
C59 P1 C65 C70 14.2(11) . . . . ?
C71 P1 C65 C70 128.3(10) . . . . ?
Au1 P1 C65 C70 -109.1(9) . . . . ?
C59 P1 C65 C66 -167.3(9) . . . . ?
C71 P1 C65 C66 -53.2(10) . . . . ?
Au1 P1 C65 C66 69.3(10) . . . . ?
C70 C65 C66 C67 -1.7(17) . . . . ?
P1 C65 C66 C67 179.8(8) . . . . ?
C65 C66 C67 C68 -2.1(17) . . . . ?
C66 C67 C68 C69 5.1(18) . . . . ?
C67 C68 C69 C70 -4.5(18) . . . . ?
C66 C65 C70 C69 2.5(17) . . . . ?
P1 C65 C70 C69 -179.0(9) . . . . ?
C68 C69 C70 C65 0.5(18) . . . . ?
C65 P1 C71 C76 -8.8(11) . . . . ?
C59 P1 C71 C76 103.4(11) . . . . ?
Au1 P1 C71 C76 -132.9(9) . . . . ?
C65 P1 C71 C72 167.4(9) . . . . ?
C59 P1 C71 C72 -80.5(10) . . . . ?
Au1 P1 C71 C72 43.3(9) . . . . ?
C76 C71 C72 C73 -3.1(17) . . . . ?
P1 C71 C72 C73 -179.5(9) . . . . ?
C71 C72 C73 C74 3.4(19) . . . . ?
C72 C73 C74 C75 -1(2) . . . . ?
C73 C74 C75 C76 -1.6(19) . . . . ?
C74 C75 C76 C71 1.9(19) . . . . ?
C72 C71 C76 C75 0.5(17) . . . . ?
P1 C71 C76 C75 176.5(9) . . . . ?
C83 P2 C77 C78 -15.4(13) . . . . ?
C89 P2 C77 C78 -130.9(12) . . . . ?
Au2 P2 C77 C78 108.1(12) . . . . ?
C83 P2 C77 C82 174.0(9) . . . . ?
C89 P2 C77 C82 58.6(11) . . . . ?
Au2 P2 C77 C82 -62.4(10) . . . . ?
C82 C77 C78 C79 0(2) . . . . ?
P2 C77 C78 C79 -170.8(11) . . . . ?
C77 C78 C79 C80 0(2) . . . . ?
C78 C79 C80 C81 -1(2) . . . . ?
C79 C80 C81 C82 2(2) . . . . ?
C80 C81 C82 C77 -2(2) . . . . ?
C78 C77 C82 C81 0.7(19) . . . . ?
P2 C77 C82 C81 172.1(10) . . . . ?
C77 P2 C83 C88 76.0(11) . . . . ?
C89 P2 C83 C88 -166.9(10) . . . . ?
Au2 P2 C83 C88 -45.9(11) . . . . ?
C77 P2 C83 C84 -101.0(10) . . . . ?
C89 P2 C83 C84 16.2(12) . . . . ?
Au2 P2 C83 C84 137.2(9) . . . . ?
C88 C83 C84 C85 -0.8(18) . . . . ?
P2 C83 C84 C85 176.0(10) . . . . ?
C83 C84 C85 C86 -0.7(19) . . . . ?
C84 C85 C86 C87 1(2) . . . . ?
C85 C86 C87 C88 -0.2(18) . . . . ?
C84 C83 C88 C87 1.8(19) . . . . ?
P2 C83 C88 C87 -175.2(10) . . . . ?
C86 C87 C88 C83 -1.2(19) . . . . ?
C83 P2 C89 C90 -104.2(11) . . . . ?
C77 P2 C89 C90 11.1(12) . . . . ?
Au2 P2 C89 C90 132.5(10) . . . . ?
C83 P2 C89 C94 79.3(11) . . . . ?
C77 P2 C89 C94 -165.4(9) . . . . ?
Au2 P2 C89 C94 -44.0(10) . . . . ?
C94 C89 C90 C91 2.7(18) . . . . ?
P2 C89 C90 C91 -173.9(9) . . . . ?
C89 C90 C91 C92 -4(2) . . . . ?
C90 C91 C92 C93 4(2) . . . . ?
C91 C92 C93 C94 -2(2) . . . . ?
C90 C89 C94 C93 -0.9(18) . . . . ?
P2 C89 C94 C93 175.9(9) . . . . ?
C92 C93 C94 C89 0(2) . . . . ?
O7B Cl2 O6A O6B -59(3) . . . . ?
O8B Cl2 O6A O6B -167(2) . . . . ?
O5 Cl2 O6A O6B 84(2) . . . . ?
O7A Cl2 O6A O6B -50(3) . . . . ?
O8A Cl2 O6A O6B -165(2) . . . . ?
O7B Cl2 O6B O6A 144(2) . . . . ?
O8B Cl2 O6B O6A 15(3) . . . . ?
O5 Cl2 O6B O6A -108(2) . . . . ?
O7A Cl2 O6B O6A 133(2) . . . . ?
O8A Cl2 O6B O6A 23(4) . . . . ?
O6A Cl2 O7A O7B -170(2) . . . . ?
O6B Cl2 O7A O7B 162(3) . . . . ?
O8B Cl2 O7A O7B -74(3) . . . . ?
O5 Cl2 O7A O7B 62(3) . . . . ?
O8A Cl2 O7A O7B -58(3) . . . . ?
O6A Cl2 O7B O7A 16(3) . . . . ?
O6B Cl2 O7B O7A -19(3) . . . . ?
O8B Cl2 O7B O7A 118(2) . . . . ?
O5 Cl2 O7B O7A -129(2) . . . . ?
O8A Cl2 O7B O7A 126(3) . . . . ?
Cl3S C1SA C1SB Cl4S 115.9(9) . . . . ?
Cl4S C1SA C1SB Cl3S -115.9(9) . . . . ?
Cl4S C1SA Cl3S C1SB 69.4(18) . . . . ?
Cl4S C1SB Cl3S C1SA -65.1(19) . . . . ?
Cl3S C1SA Cl4S C1SB -72.8(19) . . . . ?
Cl3S C1SB Cl4S C1SA 61.6(17) . . . . ?
C3S C2S Cl5S Cl7S 54(2) . . . . ?
Cl6S C2S Cl5S Cl7S -48.3(11) . . . . ?
Cl8S C2S Cl6S Cl7S -131.8(19) . . . . ?
C3S C2S Cl6S Cl7S -62.3(14) . . . . ?
Cl5S C2S Cl6S Cl7S 44.2(11) . . . . ?
Cl7S C2S Cl6S Cl8S 131.8(19) . . . . ?
C3S C2S Cl6S Cl8S 69.5(14) . . . . ?
Cl5S C2S Cl6S Cl8S 176(2) . . . . ?
Cl7S C2S C3S Cl8S -138(2) . . . . ?
Cl5S C2S C3S Cl8S 175.8(17) . . . . ?
Cl6S C2S C3S Cl8S -80.6(14) . . . . ?
Cl8S C2S C3S Cl7S 138(2) . . . . ?
Cl5S C2S C3S Cl7S -46.3(15) . . . . ?
Cl6S C2S C3S Cl7S 57.4(13) . . . . ?
Cl8S C2S Cl7S Cl5S -172(2) . . . . ?
C3S C2S Cl7S Cl5S -123(2) . . . . ?
Cl6S C2S Cl7S Cl5S 125.0(10) . . . . ?
Cl8S C2S Cl7S C3S -49(2) . . . . ?
Cl5S C2S Cl7S C3S 123(2) . . . . ?
Cl6S C2S Cl7S C3S -112(2) . . . . ?
Cl8S C2S Cl7S Cl6S 62.6(18) . . . . ?
C3S C2S Cl7S Cl6S 112(2) . . . . ?
Cl5S C2S Cl7S Cl6S -125.0(10) . . . . ?
C2S Cl5S Cl7S C3S -45.2(14) . . . . ?
C2S Cl5S Cl7S Cl6S 53.8(11) . . . . ?
Cl8S C3S Cl7S C2S 32.4(16) . . . . ?
C2S C3S Cl7S Cl5S 52.6(16) . . . . ?
Cl8S C3S Cl7S Cl5S 85(2) . . . . ?
C2S C3S Cl7S Cl6S -59.2(15) . . . . ?
Cl8S C3S Cl7S Cl6S -27(2) . . . . ?
Cl8S Cl6S Cl7S C2S -29.6(12) . . . . ?
C2S Cl6S Cl7S Cl5S -54.1(11) . . . . ?
Cl8S Cl6S Cl7S Cl5S -83.7(12) . . . . ?
C2S Cl6S Cl7S C3S 50.4(19) . . . . ?
Cl8S Cl6S Cl7S C3S 20.8(19) . . . . ?
Cl7S C2S Cl8S C3S 49(2) . . . . ?
Cl6S C2S Cl8S C3S 102(2) . . . . ?
Cl7S C2S Cl8S Cl6S -53.0(15) . . . . ?
C3S C2S Cl8S Cl6S -102(2) . . . . ?
Cl7S C3S Cl8S C2S -33.0(16) . . . . ?
C2S C3S Cl8S Cl6S 54.3(12) . . . . ?
Cl7S C3S Cl8S Cl6S 21(2) . . . . ?
Cl7S Cl6S Cl8S C2S 34.8(15) . . . . ?
Cl7S Cl6S Cl8S C3S -21(2) . . . . ?
C2S Cl6S Cl8S C3S -56(2) . . . . ?
