Crystallography Open Database

Information card for entry 4310957

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Coordinates	4310957.cif
Original paper (by DOI)	HTML

Structure parameters

Chemical name	Catena[tetrakis(mu2-trifluoroacetato-O,O')-di-rhodium(II)- (mu2-O-acetone)-tetrakis(mu2-trifluoroacetato-O,O')-tetra-copper(I)]
Formula	C19 H6 Cu4 F24 O17 Rh2
Calculated formula	C19 H6 Cu4 F24 O17 Rh2
Title of publication	On the Road to a Termolecular Complex with Acetone: A Heterometallic Supramolecular Network {[Rh2(O2CCF3)4].μ2-OCMe2.[Cu4(O2CCF3)4]}
Authors of publication	Evgeny V. Dikarev; Kristian W. Andreini; Marina A. Petrukhina
Journal of publication	Inorganic Chemistry
Year of publication	2004
Journal volume	43
Pages of publication	3219 - 3224
a	8.5009 ± 0.0005 Å
b	11.1068 ± 0.0006 Å
c	20.8409 ± 0.0012 Å
α	92.395 ± 0.001°
β	94.699 ± 0.001°
γ	107.529 ± 0.001°
Cell volume	1865.49 ± 0.18 Å³
Cell temperature	173 ± 2 K
Ambient diffraction temperature	173 ± 2 K
Number of distinct elements	6
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0264
Residual factor for significantly intense reflections	0.0246
Weighted residual factors for significantly intense reflections	0.0634
Weighted residual factors for all reflections included in the refinement	0.0645
Goodness-of-fit parameter for all reflections included in the refinement	1.032
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
179148 (current)	2016-03-23	cif/4/31/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/31/09.	4310957.cif
129439	2015-01-07	cod/ (robertas@burundukas) Correcting values of _exptl_crystal_density_meas and _exptl_crystal_density_method data items: codsql "select codid from validation where message like '%\\'_exptl_crystal_density_meas\\' value \"not measured\" is %'" -NB \ \| codid2file \ \| xargs perl -i -pe "s/_exptl_crystal_density_meas\\s+'not +measured'/_exptl_crystal_density_meas ?/i; \ s/_exptl_crystal_density_method\\s+('not +measured'\|\\?\|none)/_exptl_crystal_density_method ./i"	4310957.cif
120093	2014-07-12	Adding DOIs to range 4/31 structures.	4310957.cif
34330	2012-02-24	cif/4/ Reorganising CIF range 4 into a prefix tree.	4310957.cif
11788	2011-02-22	cif/4/ Redepositing CIFs that were formally processed with an old version of cif_fix_values script.	4310957.cif
2449	2010-11-10	../uploads/cif-deposit/cod/cif Adding structures of 4310957 via cif-deposit CGI script.	4310957.cif