Crystallography Open Database

Information card for entry 4316485

Preview

Coordinates	4316485.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C144 H124 Au8 O44 P8 Si W12
Calculated formula	C144 H120 Au8 O44 P8 Si W12
Title of publication	Intercluster Compound between a Tetrakis{triphenylphosphinegold(I)}oxonium Cation and a Keggin Polyoxometalate (POM): Formation during the Course of Carboxylate Elimination of a Monomeric Triphenylphosphinegold(I) Carboxylate in the Presence of POMs
Authors of publication	Kenji Nomiya; Takuya Yoshida; Yoshitaka Sakai; Arisa Nanba; Shinichiro Tsuruta
Journal of publication	Inorganic Chemistry
Year of publication	2010
Journal volume	49
Pages of publication	8247 - 8254
a	28.606 ± 0.0016 Å
b	19.0414 ± 0.0016 Å
c	32.434 ± 0.002 Å
α	90°
β	107.659 ± 0.002°
γ	90°
Cell volume	16834 ± 2 Å³
Cell temperature	90 K
Ambient diffraction temperature	90 K
Number of distinct elements	7
Space group number	15
Hermann-Mauguin space group symbol	C 1 2/c 1
Hall space group symbol	-C 2yc
Residual factor for all reflections	0.0671
Residual factor for significantly intense reflections	0.0549
Weighted residual factors for significantly intense reflections	0.1386
Weighted residual factors for all reflections included in the refinement	0.1476
Goodness-of-fit parameter for all reflections included in the refinement	1.159
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
179244 (current)	2016-03-23	cif/4/31/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/31/64.	4316485.cif
91935	2013-12-29	cod/ (saulius@koala.ibt.lt) Adding DOIs that could be assigned unambiguously to the rest of COD CIFs.	4316485.cif
34330	2012-02-24	cif/4/ Reorganising CIF range 4 into a prefix tree.	4316485.cif
17004	2011-03-31	cif/ Commiting CIFs, that were updated with the 'cif_fix_values' script, using options '--fix-misspelled replacement_values.lst', '--fix-temperature' and '--fix-enums' with built-in table of enum values. The following cmd was used: > (set -x; find ? -name \*.cif \| sort \| xargs -i sh -c 'if !( > cif_fix_values --fix-misspelled ~/../inputs/replacament_values.lst {} \| > cif_filter --add-cif-header {} \| > sponge {} ) 2>&1 \| grep NOTE; then svn revert {}; > fi' ) &	4316485.cif
9688	2011-02-10	../uploads/cif-deposit/cod/cif Adding structures of 4316485 via cif-deposit CGI script.	4316485.cif