Crystallography Open Database

Information card for entry 4318231

Preview

Coordinates	4318231.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C41 H45 Cl N2 O2.5 P Rh
Calculated formula	C35 H33 Cl N2 O P Rh
Title of publication	Synthesis, Coordination to Rh(I), and Hydroformylation Catalysis of New β-Aminophosphines Bearing a Dangling Nitrogen Group: An Unusual Inversion of a Rh-Coordinated P Center
Authors of publication	Jacques Andrieu; Philippe Richard; Jean-Michel Camus; Rinaldo Poli
Journal of publication	Inorganic Chemistry
Year of publication	2002
Journal volume	41
Pages of publication	3876 - 3885
a	11.8621 ± 0.0004 Å
b	12.7054 ± 0.0004 Å
c	12.9551 ± 0.0005 Å
α	75.371 ± 0.001°
β	82.537 ± 0.001°
γ	78.473 ± 0.001°
Cell volume	1844.59 ± 0.11 Å³
Cell temperature	110 ± 2 K
Ambient diffraction temperature	110 ± 2 K
Number of distinct elements	7
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0582
Residual factor for significantly intense reflections	0.0448
Weighted residual factors for significantly intense reflections	0.1188
Weighted residual factors for all reflections included in the refinement	0.1248
Goodness-of-fit parameter for all reflections included in the refinement	1.087
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
176467 (current)	2016-02-16	cif/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in range 4.	4318231.cif
120093	2014-07-12	Adding DOIs to range 4/31 structures.	4318231.cif
34330	2012-02-24	cif/4/ Reorganising CIF range 4 into a prefix tree.	4318231.cif
14595	2011-03-11	../uploads/cif-deposit/cod/cif Adding structures of 4318231 via cif-deposit CGI script.	4318231.cif