#------------------------------------------------------------------------------
#$Date: 2016-03-23 04:11:18 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179279 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/99/4319961.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4319961
loop_
_publ_author_name
'Wolfgang Mohr'
'Jürgen Stahl'
'Frank Hampel'
'J. A. Gladysz'
_publ_section_title
;
 Bent and Stretched but Not Yet to the Breaking Point: C8-C16 sp Carbon
 Chains That Span Two Platinum Atoms and the First Structurally
 Characterized 1,3,5,7,9,11,13,15-Octayne
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              3263
_journal_page_last               3264
_journal_paper_doi               10.1021/ic010309z
_journal_volume                  40
_journal_year                    2001
_chemical_formula_sum            'C168 H144 F10 O P4 Pt2'
_chemical_formula_weight         2882.89
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 93.1800(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   19.9891(2)
_cell_length_b                   26.3139(2)
_cell_length_c                   21.9780(2)
_cell_measurement_reflns_used    20768
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      25.03
_cell_measurement_theta_min      1.00
_cell_volume                     11542.43(18)
_computing_cell_refinement       DENZO-SMN
_computing_data_collection       Collect
_computing_data_reduction        DENZO-SMN
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_detector_area_resol_mean 9
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0394
_diffrn_reflns_av_sigmaI/netI    0.0556
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       31
_diffrn_reflns_limit_k_min       -31
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            40099
_diffrn_reflns_theta_full        25.05
_diffrn_reflns_theta_max         25.05
_diffrn_reflns_theta_min         2.30
_exptl_absorpt_coefficient_mu    2.558
_exptl_absorpt_correction_T_max  0.8828
_exptl_absorpt_correction_T_min  0.5141
_exptl_absorpt_correction_type   SCALEPACK
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.659
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             5864
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.198
_refine_diff_density_min         -0.987
_refine_diff_density_rms         0.089
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.030
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1350
_refine_ls_number_reflns         20382
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.031
_refine_ls_R_factor_all          0.0681
_refine_ls_R_factor_gt           0.0388
_refine_ls_shift/su_max          0.179
_refine_ls_shift/su_mean         0.006
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0485P)²+13.1781P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0911
_refine_ls_wR_factor_ref         0.1033
_reflns_number_gt                14829
_reflns_number_total             20382
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic010309z_3.cif
_cod_data_source_block           wm06
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 
;
_cod_database_code               4319961
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 1.056217(10) 0.264899(7) -0.011990(10) 0.03810(7) Uani 1 1 d . . .
P1 P 1.12711(7) 0.33180(5) 0.01338(6) 0.0394(3) Uani 1 1 d . . .
C1 C 0.9936(3) 0.3149(2) -0.0502(3) 0.0455(13) Uani 1 1 d . . .
Pt2 Pt 0.460705(10) 0.720330(7) 0.053888(9) 0.03584(7) Uani 1 1 d . . .
P2 P 0.97973(7) 0.20230(5) -0.04100(6) 0.0382(3) Uani 1 1 d . . .
C2 C 0.9527(3) 0.3476(2) -0.0677(3) 0.0489(14) Uani 1 1 d . . .
P3 P 0.39855(7) 0.64690(5) 0.06024(6) 0.0383(3) Uani 1 1 d . . .
C3 C 0.9061(3) 0.3845(2) -0.0799(3) 0.0460(14) Uani 1 1 d . . .
P4 P 0.52666(7) 0.79206(5) 0.04976(6) 0.0387(3) Uani 1 1 d . . .
C4 C 0.8643(3) 0.4171(2) -0.0891(3) 0.0480(14) Uani 1 1 d . . .
C5 C 0.8168(3) 0.4543(2) -0.0949(3) 0.0448(13) Uani 1 1 d . . .
C6 C 0.7751(3) 0.4879(2) -0.0956(3) 0.0424(13) Uani 1 1 d . . .
C7 C 0.7275(3) 0.5244(2) -0.0920(2) 0.0430(13) Uani 1 1 d . . .
C8 C 0.6853(3) 0.5565(2) -0.0846(2) 0.0407(12) Uani 1 1 d . . .
C9 C 0.6399(3) 0.5926(2) -0.0716(2) 0.0415(13) Uani 1 1 d . . .
C10 C 0.6000(3) 0.62306(19) -0.0540(2) 0.0404(12) Uani 1 1 d . . .
C11 C 0.5553(3) 0.65631(19) -0.0303(2) 0.0401(12) Uani 1 1 d . . .
C12 C 0.5183(3) 0.68345(19) -0.0020(2) 0.0398(12) Uani 1 1 d . . .
C21 C 1.1198(3) 0.21442(18) 0.0324(2) 0.0377(12) Uani 1 1 d . . .
F22 F 1.08621(18) 0.24092(13) 0.12947(15) 0.0618(9) Uani 1 1 d . . .
C22 C 1.1252(3) 0.2107(2) 0.0956(3) 0.0467(14) Uani 1 1 d . . .
F23 F 1.1691(2) 0.17481(17) 0.18919(17) 0.0864(13) Uani 1 1 d . . .
C23 C 1.1670(3) 0.1766(3) 0.1272(3) 0.0583(17) Uani 1 1 d . . .
F24 F 1.2472(2) 0.11139(17) 0.1260(2) 0.0952(14) Uani 1 1 d . . .
C24 C 1.2064(3) 0.1451(2) 0.0962(4) 0.0633(18) Uani 1 1 d . . .
F25 F 1.24242(19) 0.11560(13) 0.0022(2) 0.0767(11) Uani 1 1 d . . .
C25 C 1.2037(3) 0.1472(2) 0.0335(3) 0.0522(15) Uani 1 1 d . . .
F26 F 1.15988(16) 0.18112(12) -0.05786(15) 0.0548(8) Uani 1 1 d . . .
C26 C 1.1610(3) 0.1817(2) 0.0040(2) 0.0408(12) Uani 1 1 d . . .
C31 C 1.0798(3) 0.38177(19) 0.0483(2) 0.0409(12) Uani 1 1 d . . .
C32 C 1.0276(3) 0.3685(2) 0.0850(3) 0.0532(15) Uani 1 1 d . . .
H32A H 1.0206 0.3339 0.0949 0.064 Uiso 1 1 calc R . .
C33 C 0.9861(3) 0.4052(2) 0.1071(3) 0.0599(17) Uani 1 1 d . . .
H33A H 0.9515 0.3953 0.1325 0.072 Uiso 1 1 calc R . .
C34 C 0.9935(3) 0.4562(2) 0.0932(3) 0.0510(15) Uani 1 1 d . . .
C35 C 1.0460(3) 0.4690(2) 0.0582(3) 0.0507(15) Uani 1 1 d . . .
H35A H 1.0530 0.5037 0.0489 0.061 Uiso 1 1 calc R . .
C36 C 1.0891(3) 0.43309(19) 0.0361(3) 0.0456(13) Uani 1 1 d . . .
H36A H 1.1251 0.4435 0.0126 0.055 Uiso 1 1 calc R . .
C37 C 0.9441(4) 0.4957(2) 0.1141(3) 0.0683(19) Uani 1 1 d . . .
H37A H 0.9573 0.5295 0.1002 0.102 Uiso 1 1 calc R . .
H37B H 0.9442 0.4955 0.1587 0.102 Uiso 1 1 calc R . .
H37C H 0.8991 0.4877 0.0970 0.102 Uiso 1 1 calc R . .
C41 C 1.1647(3) 0.36156(19) -0.0518(2) 0.0409(13) Uani 1 1 d . . .
C42 C 1.2240(3) 0.3887(2) -0.0428(3) 0.0483(14) Uani 1 1 d . . .
H42A H 1.2455 0.3905 -0.0032 0.058 Uiso 1 1 calc R . .
C43 C 1.2521(3) 0.4134(2) -0.0912(3) 0.0559(16) Uani 1 1 d . . .
H43A H 1.2925 0.4320 -0.0844 0.067 Uiso 1 1 calc R . .
C44 C 1.2216(3) 0.4110(2) -0.1493(3) 0.0554(16) Uani 1 1 d . . .
C45 C 1.1627(3) 0.3832(2) -0.1576(3) 0.0557(16) Uani 1 1 d . . .
H45A H 1.1413 0.3809 -0.1973 0.067 Uiso 1 1 calc R . .
C46 C 1.1346(3) 0.3590(2) -0.1098(3) 0.0474(14) Uani 1 1 d . . .
H46A H 1.0942 0.3404 -0.1167 0.057 Uiso 1 1 calc R . .
C47 C 1.2529(4) 0.4367(3) -0.2028(3) 0.082(2) Uani 1 1 d . . .
H47A H 1.2939 0.4544 -0.1883 0.123 Uiso 1 1 calc R . .
H47B H 1.2212 0.4612 -0.2215 0.123 Uiso 1 1 calc R . .
H47C H 1.2639 0.4110 -0.2329 0.123 Uiso 1 1 calc R . .
C51 C 1.1985(3) 0.31822(18) 0.0657(2) 0.0400(12) Uani 1 1 d . . .
C52 C 1.2018(3) 0.3351(2) 0.1256(2) 0.0436(13) Uani 1 1 d . . .
H52A H 1.1670 0.3559 0.1397 0.052 Uiso 1 1 calc R . .
C53 C 1.2555(3) 0.3219(2) 0.1649(3) 0.0548(15) Uani 1 1 d . . .
H53A H 1.2574 0.3344 0.2055 0.066 Uiso 1 1 calc R . .
C54 C 1.3059(3) 0.2911(2) 0.1466(3) 0.0544(15) Uani 1 1 d . . .
C55 C 1.3018(3) 0.2736(2) 0.0872(3) 0.0501(15) Uani 1 1 d . . .
H55A H 1.3359 0.2518 0.0739 0.060 Uiso 1 1 calc R . .
C56 C 1.2497(3) 0.2868(2) 0.0469(3) 0.0463(14) Uani 1 1 d . . .
H56A H 1.2485 0.2745 0.0062 0.056 Uiso 1 1 calc R . .
C57 C 1.3638(4) 0.2765(3) 0.1901(4) 0.085(2) Uani 1 1 d . . .
H57A H 1.3582 0.2925 0.2298 0.127 Uiso 1 1 calc R . .
H57B H 1.4059 0.2880 0.1739 0.127 Uiso 1 1 calc R . .
H57C H 1.3649 0.2395 0.1950 0.127 Uiso 1 1 calc R . .
C61 C 0.9582(3) 0.20884(18) -0.1222(2) 0.0396(12) Uani 1 1 d . . .
C62 C 0.8932(3) 0.2088(2) -0.1461(3) 0.0503(14) Uani 1 1 d . . .
H62A H 0.8570 0.2052 -0.1201 0.060 Uiso 1 1 calc R . .
C63 C 0.8808(3) 0.2143(3) -0.2093(3) 0.0602(17) Uani 1 1 d . . .
H63A H 0.8358 0.2147 -0.2257 0.072 Uiso 1 1 calc R . .
C64 C 0.9326(3) 0.2190(2) -0.2484(3) 0.0510(15) Uani 1 1 d . . .
C65 C 0.9965(3) 0.2187(2) -0.2232(3) 0.0532(15) Uani 1 1 d . . .
H65A H 1.0329 0.2216 -0.2490 0.064 Uiso 1 1 calc R . .
C66 C 1.0096(3) 0.2142(2) -0.1608(3) 0.0537(15) Uani 1 1 d . . .
H66A H 1.0546 0.2149 -0.1445 0.064 Uiso 1 1 calc R . .
C67 C 0.9174(4) 0.2245(3) -0.3155(3) 0.0686(19) Uani 1 1 d . . .
H67A H 0.9594 0.2274 -0.3363 0.103 Uiso 1 1 calc R . .
H67B H 0.8903 0.2550 -0.3234 0.103 Uiso 1 1 calc R . .
H67C H 0.8926 0.1946 -0.3309 0.103 Uiso 1 1 calc R . .
C71 C 1.0083(3) 0.13690(19) -0.0315(2) 0.0397(12) Uani 1 1 d . . .
C72 C 1.0168(3) 0.1044(2) -0.0806(3) 0.0484(14) Uani 1 1 d . . .
H72A H 1.0021 0.1146 -0.1206 0.058 Uiso 1 1 calc R . .
C73 C 1.0466(3) 0.0570(2) -0.0712(3) 0.0560(16) Uani 1 1 d . . .
H73A H 1.0522 0.0355 -0.1052 0.067 Uiso 1 1 calc R . .
C74 C 1.0680(3) 0.0407(2) -0.0147(3) 0.0498(15) Uani 1 1 d . . .
C75 C 1.0558(3) 0.0715(2) 0.0356(3) 0.0513(15) Uani 1 1 d . . .
H75A H 1.0675 0.0599 0.0757 0.062 Uiso 1 1 calc R . .
C76 C 1.0262(3) 0.1191(2) 0.0263(3) 0.0479(14) Uani 1 1 d . . .
H76A H 1.0182 0.1398 0.0605 0.058 Uiso 1 1 calc R . .
C77 C 1.1038(3) -0.0094(2) -0.0050(4) 0.0676(19) Uani 1 1 d . . .
H77A H 1.1082 -0.0262 -0.0444 0.101 Uiso 1 1 calc R . .
H77B H 1.0779 -0.0312 0.0212 0.101 Uiso 1 1 calc R . .
H77C H 1.1484 -0.0034 0.0145 0.101 Uiso 1 1 calc R . .
C81 C 0.9018(3) 0.20496(19) -0.0020(2) 0.0384(12) Uani 1 1 d . . .
C82 C 0.8622(3) 0.1630(2) 0.0042(3) 0.0630(18) Uani 1 1 d . . .
H82A H 0.8762 0.1313 -0.0116 0.076 Uiso 1 1 calc R . .
C83 C 0.8021(3) 0.1656(3) 0.0330(4) 0.073(2) Uani 1 1 d . . .
H83A H 0.7756 0.1358 0.0362 0.088 Uiso 1 1 calc R . .
C84 C 0.7800(3) 0.2112(2) 0.0572(3) 0.0531(15) Uani 1 1 d . . .
C85 C 0.8192(3) 0.2531(2) 0.0484(3) 0.0568(16) Uani 1 1 d . . .
H85A H 0.8045 0.2852 0.0626 0.068 Uiso 1 1 calc R . .
C86 C 0.8783(3) 0.2507(2) 0.0203(3) 0.0550(15) Uani 1 1 d . . .
H86A H 0.9039 0.2808 0.0158 0.066 Uiso 1 1 calc R . .
C101 C 0.4030(3) 0.7555(2) 0.1162(2) 0.0411(12) Uani 1 1 d . . .
F102 F 0.45837(18) 0.71404(13) 0.20048(15) 0.0604(9) Uani 1 1 d . . .
C102 C 0.4101(3) 0.7463(2) 0.1782(3) 0.0485(14) Uani 1 1 d . . .
F103 F 0.3791(2) 0.75877(19) 0.28019(17) 0.0920(14) Uani 1 1 d . . .
C103 C 0.3704(3) 0.7691(3) 0.2197(3) 0.0622(18) Uani 1 1 d . . .
F104 F 0.2828(2) 0.8249(2) 0.2404(2) 0.1113(18) Uani 1 1 d . . .
C104 C 0.3219(3) 0.8019(3) 0.2001(3) 0.072(2) Uani 1 1 d . . .
F105 F 0.2653(2) 0.84641(18) 0.1199(2) 0.0938(15) Uani 1 1 d . . .
C105 C 0.3128(3) 0.8130(3) 0.1387(3) 0.0630(18) Uani 1 1 d . . .
F106 F 0.34176(17) 0.80071(14) 0.03926(16) 0.0625(9) Uani 1 1 d . . .
C106 C 0.3533(3) 0.7892(2) 0.0990(3) 0.0499(15) Uani 1 1 d . . .
C111 C 0.3384(3) 0.6463(2) 0.1194(2) 0.0420(13) Uani 1 1 d . . .
C112 C 0.3506(3) 0.6217(2) 0.1741(3) 0.0530(15) Uani 1 1 d . . .
H11A H 0.3901 0.6020 0.1811 0.064 Uiso 1 1 calc R . .
C113 C 0.3045(4) 0.6259(3) 0.2193(3) 0.0637(18) Uani 1 1 d . . .
H11B H 0.3134 0.6087 0.2569 0.076 Uiso 1 1 calc R . .
C114 C 0.2473(3) 0.6538(3) 0.2115(3) 0.0584(17) Uani 1 1 d . . .
C115 C 0.2348(3) 0.6778(2) 0.1564(3) 0.0590(16) Uani 1 1 d . . .
H11C H 0.1947 0.6970 0.1498 0.071 Uiso 1 1 calc R . .
C116 C 0.2792(3) 0.6747(2) 0.1105(3) 0.0489(14) Uani 1 1 d . . .
H11D H 0.2697 0.6918 0.0730 0.059 Uiso 1 1 calc R . .
C117 C 0.1981(4) 0.6582(3) 0.2613(3) 0.086(2) Uani 1 1 d . . .
H11E H 0.2149 0.6390 0.2972 0.129 Uiso 1 1 calc R . .
H11F H 0.1546 0.6444 0.2466 0.129 Uiso 1 1 calc R . .
H11G H 0.1929 0.6940 0.2723 0.129 Uiso 1 1 calc R . .
C121 C 0.3482(3) 0.63139(19) -0.0082(2) 0.0396(12) Uani 1 1 d . . .
C122 C 0.3601(3) 0.65307(19) -0.0639(2) 0.0417(13) Uani 1 1 d . . .
H12A H 0.3962 0.6762 -0.0672 0.050 Uiso 1 1 calc R . .
C123 C 0.3193(3) 0.6410(2) -0.1148(3) 0.0519(15) Uani 1 1 d . . .
H12B H 0.3281 0.6564 -0.1527 0.062 Uiso 1 1 calc R . .
C124 C 0.2663(3) 0.6076(2) -0.1126(3) 0.0502(15) Uani 1 1 d . . .
C125 C 0.2544(3) 0.5863(2) -0.0571(3) 0.0571(16) Uani 1 1 d . . .
H12C H 0.2183 0.5631 -0.0541 0.069 Uiso 1 1 calc R . .
C126 C 0.2945(3) 0.5982(2) -0.0053(3) 0.0597(17) Uani 1 1 d . . .
H12D H 0.2850 0.5833 0.0327 0.072 Uiso 1 1 calc R . .
C127 C 0.2232(4) 0.5936(3) -0.1687(3) 0.0694(19) Uani 1 1 d . . .
H12E H 0.1884 0.5697 -0.1575 0.104 Uiso 1 1 calc R . .
H12F H 0.2511 0.5777 -0.1987 0.104 Uiso 1 1 calc R . .
H12G H 0.2022 0.6243 -0.1863 0.104 Uiso 1 1 calc R . .
C131 C 0.4530(3) 0.5933(2) 0.0784(2) 0.0407(12) Uani 1 1 d . . .
C132 C 0.5095(3) 0.6015(2) 0.1173(3) 0.0512(15) Uani 1 1 d . . .
H13A H 0.5198 0.6347 0.1320 0.061 Uiso 1 1 calc R . .
C133 C 0.5504(3) 0.5613(2) 0.1345(3) 0.0586(16) Uani 1 1 d . . .
H13B H 0.5884 0.5672 0.1615 0.070 Uiso 1 1 calc R . .
C134 C 0.5379(3) 0.5122(2) 0.1135(3) 0.0584(16) Uani 1 1 d . . .
C135 C 0.4831(4) 0.5048(2) 0.0753(3) 0.0600(17) Uani 1 1 d . . .
H13C H 0.4739 0.4717 0.0599 0.072 Uiso 1 1 calc R . .
C136 C 0.4400(3) 0.5443(2) 0.0582(3) 0.0505(15) Uani 1 1 d . . .
H13D H 0.4012 0.5377 0.0324 0.061 Uiso 1 1 calc R . .
C137 C 0.5835(4) 0.4682(3) 0.1322(4) 0.085(2) Uani 1 1 d . . .
H13E H 0.5665 0.4370 0.1125 0.128 Uiso 1 1 calc R . .
H13F H 0.5844 0.4640 0.1766 0.128 Uiso 1 1 calc R . .
H13G H 0.6289 0.4751 0.1197 0.128 Uiso 1 1 calc R . .
C141 C 0.4916(3) 0.84831(19) 0.0856(3) 0.0477(14) Uani 1 1 d . . .
C142 C 0.4943(3) 0.8529(2) 0.1489(3) 0.0500(14) Uani 1 1 d . . .
H14A H 0.5192 0.8290 0.1734 0.060 Uiso 1 1 calc R . .
C143 C 0.4609(3) 0.8921(3) 0.1759(3) 0.0653(18) Uani 1 1 d . . .
H14B H 0.4634 0.8949 0.2190 0.078 Uiso 1 1 calc R . .
C144 C 0.4240(4) 0.9271(3) 0.1417(4) 0.073(2) Uani 1 1 d . . .
C145 C 0.4219(4) 0.9228(3) 0.0794(4) 0.074(2) Uani 1 1 d . . .
H14C H 0.3972 0.9469 0.0551 0.089 Uiso 1 1 calc R . .
C146 C 0.4551(3) 0.8837(2) 0.0512(3) 0.0560(16) Uani 1 1 d . . .
H14D H 0.4527 0.8812 0.0080 0.067 Uiso 1 1 calc R . .
C147 C 0.3875(4) 0.9703(3) 0.1727(4) 0.103(3) Uani 1 1 d . . .
H14E H 0.3943 0.9670 0.2171 0.154 Uiso 1 1 calc R . .
H14F H 0.3395 0.9685 0.1612 0.154 Uiso 1 1 calc R . .
H14G H 0.4053 1.0030 0.1599 0.154 Uiso 1 1 calc R . .
C151 C 0.5389(3) 0.81351(19) -0.0277(3) 0.0433(13) Uani 1 1 d . . .
C152 C 0.4937(3) 0.7986(2) -0.0746(3) 0.0520(15) Uani 1 1 d . . .
H15A H 0.4592 0.7751 -0.0668 0.062 Uiso 1 1 calc R . .
C153 C 0.4989(4) 0.8179(2) -0.1329(3) 0.0604(17) Uani 1 1 d . . .
H15B H 0.4670 0.8081 -0.1644 0.072 Uiso 1 1 calc R . .
C154 C 0.5492(4) 0.8506(2) -0.1458(3) 0.0596(17) Uani 1 1 d . . .
C155 C 0.5945(3) 0.8649(2) -0.0993(3) 0.0648(18) Uani 1 1 d . . .
H15C H 0.6297 0.8877 -0.1078 0.078 Uiso 1 1 calc R . .
C156 C 0.5899(3) 0.8467(2) -0.0405(3) 0.0536(15) Uani 1 1 d . . .
H15D H 0.6216 0.8571 -0.0091 0.064 Uiso 1 1 calc R . .
C157 C 0.5550(5) 0.8717(3) -0.2100(3) 0.091(3) Uani 1 1 d . . .
H15E H 0.5190 0.8578 -0.2371 0.137 Uiso 1 1 calc R . .
H15F H 0.5985 0.8621 -0.2251 0.137 Uiso 1 1 calc R . .
H15G H 0.5513 0.9089 -0.2090 0.137 Uiso 1 1 calc R . .
C161 C 0.6087(3) 0.78346(19) 0.0891(2) 0.0420(13) Uani 1 1 d . . .
C162 C 0.6454(3) 0.8242(2) 0.1133(3) 0.0470(14) Uani 1 1 d . . .
H16A H 0.6282 0.8577 0.1086 0.056 Uiso 1 1 calc R . .
C163 C 0.7071(3) 0.8166(2) 0.1444(3) 0.0528(15) Uani 1 1 d . . .
H16B H 0.7313 0.8449 0.1610 0.063 Uiso 1 1 calc R . .
C164 C 0.7339(3) 0.7677(2) 0.1514(3) 0.0489(14) Uani 1 1 d . . .
C165 C 0.6965(3) 0.7278(2) 0.1269(3) 0.0499(14) Uani 1 1 d . . .
H16C H 0.7136 0.6943 0.1314 0.060 Uiso 1 1 calc R . .
C166 C 0.6350(3) 0.7349(2) 0.0961(3) 0.0469(14) Uani 1 1 d . . .
H16D H 0.6109 0.7065 0.0797 0.056 Uiso 1 1 calc R . .
C167 C 0.8007(3) 0.7600(3) 0.1862(3) 0.0627(17) Uani 1 1 d . . .
H16E H 0.8187 0.7931 0.1996 0.094 Uiso 1 1 calc R . .
H16F H 0.8320 0.7436 0.1596 0.094 Uiso 1 1 calc R . .
H16G H 0.7945 0.7385 0.2218 0.094 Uiso 1 1 calc R . .
C187 C 0.7163(3) 0.2135(3) 0.0897(3) 0.0709(19) Uani 1 1 d . . .
H18A H 0.7094 0.2482 0.1042 0.106 Uiso 1 1 calc R . .
H18B H 0.7191 0.1902 0.1244 0.106 Uiso 1 1 calc R . .
H18C H 0.6786 0.2037 0.0616 0.106 Uiso 1 1 calc R . .
C201 C 0.8602(6) 0.5973(3) -0.3113(5) 0.101(3) Uani 1 1 d . . .
H20A H 0.8821 0.6222 -0.3343 0.121 Uiso 1 1 calc R . .
C202 C 0.8798(4) 0.5902(3) -0.2510(4) 0.082(2) Uani 1 1 d . . .
H20B H 0.9146 0.6104 -0.2323 0.098 Uiso 1 1 calc R . .
C203 C 0.8484(4) 0.5535(3) -0.2177(3) 0.078(2) Uani 1 1 d . . .
H20C H 0.8621 0.5476 -0.1763 0.093 Uiso 1 1 calc R . .
C204 C 0.7972(5) 0.5257(3) -0.2455(4) 0.085(2) Uani 1 1 d . . .
H20D H 0.7749 0.5007 -0.2230 0.102 Uiso 1 1 calc R . .
C205 C 0.7784(5) 0.5339(4) -0.3054(4) 0.095(3) Uani 1 1 d . . .
H20E H 0.7426 0.5145 -0.3237 0.114 Uiso 1 1 calc R . .
C206 C 0.8089(5) 0.5685(4) -0.3392(4) 0.097(3) Uani 1 1 d . . .
H20F H 0.7958 0.5733 -0.3810 0.116 Uiso 1 1 calc R . .
C211 C 0.9377(4) 0.3990(3) -0.3377(3) 0.083(2) Uani 1 1 d . . .
H21A H 0.9207 0.3998 -0.3789 0.100 Uiso 1 1 calc R . .
C212 C 0.9782(4) 0.3586(3) -0.3170(4) 0.081(2) Uani 1 1 d . . .
H21B H 0.9910 0.3329 -0.3443 0.097 Uiso 1 1 calc R . .
C213 C 0.9989(4) 0.3566(3) -0.2573(4) 0.078(2) Uani 1 1 d . . .
H21C H 1.0259 0.3291 -0.2425 0.093 Uiso 1 1 calc R . .
C214 C 0.9812(4) 0.3944(3) -0.2180(4) 0.077(2) Uani 1 1 d . . .
H21D H 0.9959 0.3929 -0.1762 0.092 Uiso 1 1 calc R . .
C215 C 0.9422(4) 0.4343(3) -0.2392(4) 0.075(2) Uani 1 1 d . . .
H21E H 0.9292 0.4598 -0.2117 0.090 Uiso 1 1 calc R . .
C216 C 0.9223(4) 0.4377(3) -0.2984(4) 0.081(2) Uani 1 1 d . . .
H21F H 0.8977 0.4665 -0.3132 0.097 Uiso 1 1 calc R . .
O221 O 0.5432(11) 1.0133(9) 0.2537(10) 0.216(11) Uiso 0.488(14) 1 d PD . .
H22F H 0.5505 1.0444 0.2596 0.324 Uiso 0.488(14) 1 calc PR . .
C222 C 0.6019(6) 0.9865(5) 0.2639(5) 0.137(4) Uiso 1 1 d D . .
H22A H 0.6193 0.9964 0.3053 0.164 Uiso 1 1 calc R . .
H22B H 0.6335 1.0010 0.2354 0.164 Uiso 1 1 calc R . .
C223 C 0.6106(6) 0.9318(4) 0.2607(5) 0.132(4) Uiso 1 1 d D . .
H22C H 0.6563 0.9233 0.2774 0.158 Uiso 1 1 calc R . .
H22E H 0.6076 0.9215 0.2173 0.158 Uiso 1 1 calc R . .
O224 O 0.5621(7) 0.9018(5) 0.2933(6) 0.124(6) Uiso 0.512(14) 1 d PD . .
H22D H 0.5697 0.8707 0.2884 0.186 Uiso 0.512(14) 1 calc PR . .
C231 C 0.3045(6) 0.9775(8) -0.0568(7) 0.151(5) Uani 1 1 d . . .
H23A H 0.2591 0.9761 -0.0462 0.181 Uiso 1 1 calc R . .
C232 C 0.3435(9) 1.0190(5) -0.0412(6) 0.129(5) Uani 1 1 d . . .
H23B H 0.3271 1.0465 -0.0184 0.155 Uiso 1 1 calc R . .
C233 C 0.4039(9) 1.0183(5) -0.0593(8) 0.158(6) Uani 1 1 d . . .
H23C H 0.4311 1.0473 -0.0508 0.189 Uiso 1 1 calc R . .
C234 C 0.4305(7) 0.9806(8) -0.0888(7) 0.167(6) Uani 1 1 d . . .
H23D H 0.4759 0.9818 -0.0993 0.200 Uiso 1 1 calc R . .
C235 C 0.3933(9) 0.9418(5) -0.1029(5) 0.118(4) Uani 1 1 d . . .
H23E H 0.4119 0.9147 -0.1251 0.142 Uiso 1 1 calc R . .
C236 C 0.3320(9) 0.9383(5) -0.0881(6) 0.142(5) Uani 1 1 d . . .
H23F H 0.3061 0.9090 -0.0987 0.170 Uiso 1 1 calc R . .
C241 C 0.8490(6) -0.0120(4) -0.1692(5) 0.116(4) Uani 1 1 d . . .
H24A H 0.8295 -0.0427 -0.1559 0.139 Uiso 1 1 calc R . .
C242 C 0.8174(5) 0.0386(4) -0.1593(4) 0.099(3) Uani 1 1 d . . .
H24B H 0.7768 0.0420 -0.1391 0.119 Uiso 1 1 calc R . .
C243 C 0.8495(5) 0.0786(4) -0.1803(4) 0.087(2) Uani 1 1 d . . .
H24C H 0.8311 0.1114 -0.1746 0.105 Uiso 1 1 calc R . .
C244 C 0.9074(5) 0.0749(4) -0.2097(4) 0.091(3) Uani 1 1 d . . .
H24D H 0.9271 0.1049 -0.2249 0.109 Uiso 1 1 calc R . .
C245 C 0.9371(5) 0.0307(3) -0.2177(4) 0.098(3) Uani 1 1 d . . .
H24E H 0.9787 0.0289 -0.2366 0.117 Uiso 1 1 calc R . .
C246 C 0.9072(5) -0.0115(3) -0.1985(4) 0.088(2) Uani 1 1 d . . .
H24F H 0.9280 -0.0432 -0.2058 0.106 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Pt1 C21 176.8(2) . . ?
C1 Pt1 P1 87.71(15) . . ?
C21 Pt1 P1 91.33(14) . . ?
C1 Pt1 P2 87.95(15) . . ?
C21 Pt1 P2 93.02(14) . . ?
P1 Pt1 P2 175.66(5) . . ?
C31 P1 C51 106.6(2) . . ?
C31 P1 C41 105.5(2) . . ?
C51 P1 C41 103.7(2) . . ?
C31 P1 Pt1 109.10(18) . . ?
C51 P1 Pt1 116.91(17) . . ?
C41 P1 Pt1 114.23(17) . . ?
C2 C1 Pt1 172.9(5) . . ?
C12 Pt2 C101 176.3(2) . . ?
C12 Pt2 P3 87.74(15) . . ?
C101 Pt2 P3 90.70(15) . . ?
C12 Pt2 P4 91.35(15) . . ?
C101 Pt2 P4 90.08(15) . . ?
P3 Pt2 P4 177.55(5) . . ?
C81 P2 C71 104.7(2) . . ?
C81 P2 C61 107.2(2) . . ?
C71 P2 C61 104.9(2) . . ?
C81 P2 Pt1 114.37(17) . . ?
C71 P2 Pt1 116.27(17) . . ?
C61 P2 Pt1 108.62(17) . . ?
C1 C2 C3 173.2(7) . . ?
C121 P3 C131 107.9(2) . . ?
C121 P3 C111 103.5(2) . . ?
C131 P3 C111 104.4(2) . . ?
C121 P3 Pt2 114.53(17) . . ?
C131 P3 Pt2 110.26(18) . . ?
C111 P3 Pt2 115.49(17) . . ?
C4 C3 C2 178.3(7) . . ?
C151 P4 C161 108.5(3) . . ?
C151 P4 C141 103.0(3) . . ?
C161 P4 C141 104.5(2) . . ?
C151 P4 Pt2 113.38(18) . . ?
C161 P4 Pt2 112.34(18) . . ?
C141 P4 Pt2 114.24(18) . . ?
C3 C4 C5 175.6(7) . . ?
C6 C5 C4 175.3(6) . . ?
C5 C6 C7 175.7(6) . . ?
C8 C7 C6 175.7(6) . . ?
C7 C8 C9 175.3(6) . . ?
C10 C9 C8 173.4(6) . . ?
C9 C10 C11 176.2(6) . . ?
C12 C11 C10 171.8(6) . . ?
C11 C12 Pt2 171.6(5) . . ?
C26 C21 C22 113.4(5) . . ?
C26 C21 Pt1 124.3(4) . . ?
C22 C21 Pt1 122.3(4) . . ?
F22 C22 C23 116.8(5) . . ?
F22 C22 C21 119.3(5) . . ?
C23 C22 C21 123.9(6) . . ?
C24 C23 F23 119.7(6) . . ?
C24 C23 C22 119.7(6) . . ?
F23 C23 C22 120.6(6) . . ?
F24 C24 C23 120.7(7) . . ?
F24 C24 C25 120.1(7) . . ?
C23 C24 C25 119.2(6) . . ?
F25 C25 C26 121.4(6) . . ?
F25 C25 C24 119.6(6) . . ?
C26 C25 C24 119.1(6) . . ?
F26 C26 C21 119.2(5) . . ?
F26 C26 C25 116.0(5) . . ?
C21 C26 C25 124.7(5) . . ?
C36 C31 C32 117.6(5) . . ?
C36 C31 P1 123.0(4) . . ?
C32 C31 P1 119.1(4) . . ?
C33 C32 C31 120.8(5) . . ?
C32 C33 C34 121.8(6) . . ?
C35 C34 C33 116.9(5) . . ?
C35 C34 C37 122.1(6) . . ?
C33 C34 C37 121.0(6) . . ?
C34 C35 C36 122.6(5) . . ?
C35 C36 C31 120.2(5) . . ?
C46 C41 C42 118.7(5) . . ?
C46 C41 P1 121.7(4) . . ?
C42 C41 P1 119.6(4) . . ?
C43 C42 C41 120.6(5) . . ?
C42 C43 C44 120.5(6) . . ?
C45 C44 C43 118.2(6) . . ?
C45 C44 C47 121.0(6) . . ?
C43 C44 C47 120.8(6) . . ?
C46 C45 C44 121.4(6) . . ?
C45 C46 C41 120.5(5) . . ?
C52 C51 C56 118.2(5) . . ?
C52 C51 P1 122.1(4) . . ?
C56 C51 P1 119.5(4) . . ?
C51 C52 C53 120.4(5) . . ?
C54 C53 C52 121.5(6) . . ?
C53 C54 C55 117.9(6) . . ?
C53 C54 C57 121.0(6) . . ?
C55 C54 C57 121.2(6) . . ?
C56 C55 C54 121.9(5) . . ?
C55 C56 C51 120.1(5) . . ?
C66 C61 C62 119.2(5) . . ?
C66 C61 P2 118.1(4) . . ?
C62 C61 P2 122.7(4) . . ?
C61 C62 C63 119.2(6) . . ?
C64 C63 C62 121.7(6) . . ?
C65 C64 C63 117.5(6) . . ?
C65 C64 C67 122.5(6) . . ?
C63 C64 C67 120.1(6) . . ?
C64 C65 C66 121.6(6) . . ?
C61 C66 C65 120.8(6) . . ?
C76 C71 C72 117.9(5) . . ?
C76 C71 P2 119.3(4) . . ?
C72 C71 P2 122.7(4) . . ?
C73 C72 C71 120.2(5) . . ?
C74 C73 C72 121.9(6) . . ?
C73 C74 C75 118.6(5) . . ?
C73 C74 C77 121.8(6) . . ?
C75 C74 C77 119.6(6) . . ?
C76 C75 C74 119.6(6) . . ?
C71 C76 C75 121.7(5) . . ?
C82 C81 C86 117.1(5) . . ?
C82 C81 P2 122.0(4) . . ?
C86 C81 P2 120.9(4) . . ?
C81 C82 C83 121.6(6) . . ?
C82 C83 C84 121.0(6) . . ?
C85 C84 C83 116.3(6) . . ?
C85 C84 C187 122.7(6) . . ?
C83 C84 C187 121.0(6) . . ?
C86 C85 C84 122.7(6) . . ?
C85 C86 C81 121.1(6) . . ?
C106 C101 C102 114.8(5) . . ?
C106 C101 Pt2 122.1(4) . . ?
C102 C101 Pt2 123.1(4) . . ?
F102 C102 C101 119.9(5) . . ?
F102 C102 C103 117.2(5) . . ?
C101 C102 C103 122.9(6) . . ?
C104 C103 F103 119.4(6) . . ?
C104 C103 C102 119.7(6) . . ?
F103 C103 C102 120.8(6) . . ?
C103 C104 F104 120.4(7) . . ?
C103 C104 C105 120.0(5) . . ?
F104 C104 C105 119.7(6) . . ?
F105 C105 C106 122.2(6) . . ?
F105 C105 C104 119.5(6) . . ?
C106 C105 C104 118.3(6) . . ?
F106 C106 C105 116.0(5) . . ?
F106 C106 C101 119.7(5) . . ?
C105 C106 C101 124.2(6) . . ?
C112 C111 C116 118.7(5) . . ?
C112 C111 P3 122.5(4) . . ?
C116 C111 P3 118.8(4) . . ?
C111 C112 C113 119.5(6) . . ?
C114 C113 C112 122.4(6) . . ?
C113 C114 C115 118.0(6) . . ?
C113 C114 C117 121.6(7) . . ?
C115 C114 C117 120.4(7) . . ?
C116 C115 C114 121.5(6) . . ?
C115 C116 C111 120.0(6) . . ?
C122 C121 C126 118.2(5) . . ?
C122 C121 P3 121.9(4) . . ?
C126 C121 P3 119.9(4) . . ?
C121 C122 C123 119.9(5) . . ?
C124 C123 C122 122.5(5) . . ?
C125 C124 C123 117.5(5) . . ?
C125 C124 C127 120.3(6) . . ?
C123 C124 C127 122.2(6) . . ?
C124 C125 C126 120.9(6) . . ?
C121 C126 C125 121.0(6) . . ?
C136 C131 C132 118.1(5) . . ?
C136 C131 P3 123.7(4) . . ?
C132 C131 P3 118.1(4) . . ?
C133 C132 C131 119.9(5) . . ?
C132 C133 C134 121.9(6) . . ?
C135 C134 C133 117.7(6) . . ?
C135 C134 C137 120.7(6) . . ?
C133 C134 C137 121.7(6) . . ?
C134 C135 C136 121.8(6) . . ?
C131 C136 C135 120.5(6) . . ?
C146 C141 C142 118.6(5) . . ?
C146 C141 P4 120.7(5) . . ?
C142 C141 P4 120.2(4) . . ?
C143 C142 C141 120.1(6) . . ?
C144 C143 C142 121.5(7) . . ?
C143 C144 C145 118.4(6) . . ?
C143 C144 C147 120.5(7) . . ?
C145 C144 C147 121.1(7) . . ?
C144 C145 C146 121.2(7) . . ?
C141 C146 C145 120.4(6) . . ?
C156 C151 C152 118.9(5) . . ?
C156 C151 P4 121.6(4) . . ?
C152 C151 P4 119.4(4) . . ?
C151 C152 C153 120.3(6) . . ?
C154 C153 C152 121.0(6) . . ?
C153 C154 C155 118.7(6) . . ?
C153 C154 C157 121.1(7) . . ?
C155 C154 C157 120.2(6) . . ?
C154 C155 C156 121.4(6) . . ?
C151 C156 C155 119.7(6) . . ?
C162 C161 C166 118.7(5) . . ?
C162 C161 P4 121.9(4) . . ?
C166 C161 P4 119.5(4) . . ?
C161 C162 C163 120.8(5) . . ?
C162 C163 C164 120.7(5) . . ?
C165 C164 C163 117.3(5) . . ?
C165 C164 C167 122.7(5) . . ?
C163 C164 C167 119.9(5) . . ?
C166 C165 C164 122.5(5) . . ?
C165 C166 C161 119.9(5) . . ?
C202 C201 C206 121.0(9) . . ?
C201 C202 C203 119.4(9) . . ?
C204 C203 C202 119.1(7) . . ?
C205 C204 C203 120.2(8) . . ?
C206 C205 C204 122.0(10) . . ?
C205 C206 C201 118.2(9) . . ?
C216 C211 C212 120.1(7) . . ?
C213 C212 C211 119.1(7) . . ?
C212 C213 C214 120.3(7) . . ?
C215 C214 C213 120.0(8) . . ?
C216 C215 C214 120.8(7) . . ?
C215 C216 C211 119.5(7) . . ?
O221 C222 C223 127.1(15) . . ?
C222 C223 O224 115.1(11) . . ?
C236 C231 C232 119.0(12) . . ?
C233 C232 C231 116.1(12) . . ?
C232 C233 C234 124.9(14) . . ?
C233 C234 C235 118.3(14) . . ?
C236 C235 C234 122.5(13) . . ?
C235 C236 C231 119.2(12) . . ?
C246 C241 C242 116.1(9) . . ?
C243 C242 C241 116.0(10) . . ?
C242 C243 C244 123.3(9) . . ?
C245 C244 C243 121.7(10) . . ?
C244 C245 C246 118.4(10) . . ?
C245 C246 C241 124.4(9) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C1 1.972(6) . ?
Pt1 C21 2.048(5) . ?
Pt1 P1 2.3088(13) . ?
Pt1 P2 2.3129(13) . ?
P1 C31 1.814(5) . ?
P1 C51 1.817(6) . ?
P1 C41 1.830(6) . ?
C1 C2 1.234(8) . ?
Pt2 C12 1.983(5) . ?
Pt2 C101 2.058(5) . ?
Pt2 P3 2.3057(13) . ?
Pt2 P4 2.3071(14) . ?
P2 C81 1.821(5) . ?
P2 C71 1.822(5) . ?
P2 C61 1.820(6) . ?
C2 C3 1.361(8) . ?
P3 C121 1.810(5) . ?
P3 C131 1.811(5) . ?
P3 C111 1.820(5) . ?
C3 C4 1.209(8) . ?
P4 C151 1.823(6) . ?
P4 C161 1.825(6) . ?
P4 C141 1.834(5) . ?
C4 C5 1.363(8) . ?
C5 C6 1.216(7) . ?
C6 C7 1.358(8) . ?
C7 C8 1.210(7) . ?
C8 C9 1.356(7) . ?
C9 C10 1.208(7) . ?
C10 C11 1.374(7) . ?
C11 C12 1.223(7) . ?
C21 C26 1.367(7) . ?
C21 C22 1.389(8) . ?
F22 C22 1.364(6) . ?
C22 C23 1.386(8) . ?
F23 C23 1.362(7) . ?
C23 C24 1.353(9) . ?
F24 C24 1.350(7) . ?
C24 C25 1.376(9) . ?
F25 C25 1.352(7) . ?
C25 C26 1.382(8) . ?
F26 C26 1.358(6) . ?
C31 C36 1.391(7) . ?
C31 C32 1.399(8) . ?
C32 C33 1.378(8) . ?
C33 C34 1.387(8) . ?
C34 C35 1.376(8) . ?
C34 C37 1.522(8) . ?
C35 C36 1.383(8) . ?
C41 C46 1.381(7) . ?
C41 C42 1.389(7) . ?
C42 C43 1.391(8) . ?
C43 C44 1.384(8) . ?
C44 C45 1.390(8) . ?
C44 C47 1.520(9) . ?
C45 C46 1.376(8) . ?
C51 C52 1.388(7) . ?
C51 C56 1.395(7) . ?
C52 C53 1.384(8) . ?
C53 C54 1.371(8) . ?
C54 C55 1.383(8) . ?
C54 C57 1.509(9) . ?
C55 C56 1.375(8) . ?
C61 C66 1.375(8) . ?
C61 C62 1.376(8) . ?
C62 C63 1.405(8) . ?
C63 C64 1.389(9) . ?
C64 C65 1.363(9) . ?
C64 C67 1.495(9) . ?
C65 C66 1.388(8) . ?
C71 C76 1.381(8) . ?
C71 C72 1.395(7) . ?
C72 C73 1.393(8) . ?
C73 C74 1.359(8) . ?
C74 C75 1.402(8) . ?
C74 C77 1.510(8) . ?
C75 C76 1.396(8) . ?
C81 C82 1.369(8) . ?
C81 C86 1.391(8) . ?
C82 C83 1.391(9) . ?
C83 C84 1.394(9) . ?
C84 C85 1.374(9) . ?
C84 C187 1.495(8) . ?
C85 C86 1.367(8) . ?
C101 C106 1.370(8) . ?
C101 C102 1.383(8) . ?
F102 C102 1.355(7) . ?
C102 C103 1.381(8) . ?
F103 C103 1.358(7) . ?
C103 C104 1.351(10) . ?
F104 C104 1.357(7) . ?
C104 C105 1.382(10) . ?
F105 C105 1.343(7) . ?
C105 C106 1.375(8) . ?
F106 C106 1.354(7) . ?
C111 C112 1.375(8) . ?
C111 C116 1.405(8) . ?
C112 C113 1.397(8) . ?
C113 C114 1.363(9) . ?
C114 C115 1.376(9) . ?
C114 C117 1.516(9) . ?
C115 C116 1.382(8) . ?
C121 C122 1.382(7) . ?
C121 C126 1.388(8) . ?
C122 C123 1.385(8) . ?
C123 C124 1.378(8) . ?
C124 C125 1.377(8) . ?
C124 C127 1.510(8) . ?
C125 C126 1.392(8) . ?
C131 C136 1.383(7) . ?
C131 C132 1.397(8) . ?
C132 C133 1.377(8) . ?
C133 C134 1.388(8) . ?
C134 C135 1.357(9) . ?
C134 C137 1.517(9) . ?
C135 C136 1.389(8) . ?
C141 C146 1.381(8) . ?
C141 C142 1.393(8) . ?
C142 C143 1.381(8) . ?
C143 C144 1.377(10) . ?
C144 C145 1.371(10) . ?
C144 C147 1.532(9) . ?
C145 C146 1.390(9) . ?
C151 C156 1.383(8) . ?
C151 C152 1.390(8) . ?
C152 C153 1.387(8) . ?
C153 C154 1.365(9) . ?
C154 C155 1.380(9) . ?
C154 C157 1.528(9) . ?
C155 C156 1.386(8) . ?
C161 C162 1.389(7) . ?
C161 C166 1.388(7) . ?
C162 C163 1.391(8) . ?
C163 C164 1.400(8) . ?
C164 C165 1.380(8) . ?
C164 C167 1.513(8) . ?
C165 C166 1.381(8) . ?
C201 C202 1.373(12) . ?
C201 C206 1.389(13) . ?
C202 C203 1.384(10) . ?
C203 C204 1.372(11) . ?
C204 C205 1.366(11) . ?
C205 C206 1.344(12) . ?
C211 C216 1.381(10) . ?
C211 C212 1.397(11) . ?
C212 C213 1.354(11) . ?
C213 C214 1.377(10) . ?
C214 C215 1.373(10) . ?
C215 C216 1.343(10) . ?
O221 C222 1.377(17) . ?
C222 C223 1.453(14) . ?
C223 O224 1.467(14) . ?
C231 C236 1.371(18) . ?
C231 C232 1.374(17) . ?
C232 C233 1.292(17) . ?
C233 C234 1.314(18) . ?
C234 C235 1.291(17) . ?
C235 C236 1.290(16) . ?
C241 C246 1.361(13) . ?
C241 C242 1.495(14) . ?
C242 C243 1.329(12) . ?
C243 C244 1.360(11) . ?
C244 C245 1.322(11) . ?
C245 C246 1.342(12) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 Pt1 P1 C31 48.6(3) . . . . ?
C21 Pt1 P1 C31 -128.3(2) . . . . ?
P2 Pt1 P1 C31 50.2(7) . . . . ?
C1 Pt1 P1 C51 169.5(3) . . . . ?
C21 Pt1 P1 C51 -7.4(2) . . . . ?
P2 Pt1 P1 C51 171.1(7) . . . . ?
C1 Pt1 P1 C41 -69.1(3) . . . . ?
C21 Pt1 P1 C41 114.0(2) . . . . ?
P2 Pt1 P1 C41 -67.6(7) . . . . ?
C21 Pt1 C1 C2 -4(7) . . . . ?
P1 Pt1 C1 C2 -77(4) . . . . ?
P2 Pt1 C1 C2 103(4) . . . . ?
C1 Pt1 P2 C81 -67.4(3) . . . . ?
C21 Pt1 P2 C81 109.5(2) . . . . ?
P1 Pt1 P2 C81 -69.0(7) . . . . ?
C1 Pt1 P2 C71 170.3(3) . . . . ?
C21 Pt1 P2 C71 -12.8(3) . . . . ?
P1 Pt1 P2 C71 168.7(7) . . . . ?
C1 Pt1 P2 C61 52.3(2) . . . . ?
C21 Pt1 P2 C61 -130.8(2) . . . . ?
P1 Pt1 P2 C61 50.7(7) . . . . ?
Pt1 C1 C2 C3 0(8) . . . . ?
C12 Pt2 P3 C121 -71.1(2) . . . . ?
C101 Pt2 P3 C121 112.2(2) . . . . ?
P4 Pt2 P3 C121 -139.4(12) . . . . ?
C12 Pt2 P3 C131 50.7(2) . . . . ?
C101 Pt2 P3 C131 -126.0(2) . . . . ?
P4 Pt2 P3 C131 -17.5(12) . . . . ?
C12 Pt2 P3 C111 168.8(3) . . . . ?
C101 Pt2 P3 C111 -7.9(3) . . . . ?
P4 Pt2 P3 C111 100.5(12) . . . . ?
C1 C2 C3 C4 -18(24) . . . . ?
C12 Pt2 P4 C151 53.2(2) . . . . ?
C101 Pt2 P4 C151 -130.1(2) . . . . ?
P3 Pt2 P4 C151 121.4(12) . . . . ?
C12 Pt2 P4 C161 -70.2(2) . . . . ?
C101 Pt2 P4 C161 106.4(2) . . . . ?
P3 Pt2 P4 C161 -2.1(12) . . . . ?
C12 Pt2 P4 C141 170.9(3) . . . . ?
C101 Pt2 P4 C141 -12.4(3) . . . . ?
P3 Pt2 P4 C141 -120.9(12) . . . . ?
C2 C3 C4 C5 21(27) . . . . ?
C3 C4 C5 C6 8(13) . . . . ?
C4 C5 C6 C7 -29(14) . . . . ?
C5 C6 C7 C8 16(14) . . . . ?
C6 C7 C8 C9 20(14) . . . . ?
C7 C8 C9 C10 -27(11) . . . . ?
C8 C9 C10 C11 1(13) . . . . ?
C9 C10 C11 C12 7(12) . . . . ?
C10 C11 C12 Pt2 -17(7) . . . . ?
C101 Pt2 C12 C11 6(6) . . . . ?
P3 Pt2 C12 C11 -59(3) . . . . ?
P4 Pt2 C12 C11 119(3) . . . . ?
C1 Pt1 C21 C26 -177(19) . . . . ?
P1 Pt1 C21 C26 -104.0(4) . . . . ?
P2 Pt1 C21 C26 76.1(4) . . . . ?
C1 Pt1 C21 C22 3(4) . . . . ?
P1 Pt1 C21 C22 75.5(4) . . . . ?
P2 Pt1 C21 C22 -104.4(4) . . . . ?
C26 C21 C22 F22 -179.4(5) . . . . ?
Pt1 C21 C22 F22 1.1(7) . . . . ?
C26 C21 C22 C23 -1.3(8) . . . . ?
Pt1 C21 C22 C23 179.2(4) . . . . ?
F22 C22 C23 C24 179.3(5) . . . . ?
C21 C22 C23 C24 1.2(9) . . . . ?
F22 C22 C23 F23 -1.2(8) . . . . ?
C21 C22 C23 F23 -179.4(5) . . . . ?
F23 C23 C24 F24 1.0(9) . . . . ?
C22 C23 C24 F24 -179.5(5) . . . . ?
F23 C23 C24 C25 179.9(5) . . . . ?
C22 C23 C24 C25 -0.7(9) . . . . ?
F24 C24 C25 F25 -0.5(9) . . . . ?
C23 C24 C25 F25 -179.4(5) . . . . ?
F24 C24 C25 C26 179.3(5) . . . . ?
C23 C24 C25 C26 0.4(9) . . . . ?
C22 C21 C26 F26 179.1(4) . . . . ?
Pt1 C21 C26 F26 -1.4(7) . . . . ?
C22 C21 C26 C25 1.0(8) . . . . ?
Pt1 C21 C26 C25 -179.5(4) . . . . ?
F25 C25 C26 F26 1.0(8) . . . . ?
C24 C25 C26 F26 -178.8(5) . . . . ?
F25 C25 C26 C21 179.1(5) . . . . ?
C24 C25 C26 C21 -0.6(9) . . . . ?
C51 P1 C31 C36 93.5(5) . . . . ?
C41 P1 C31 C36 -16.3(5) . . . . ?
Pt1 P1 C31 C36 -139.5(4) . . . . ?
C51 P1 C31 C32 -92.2(5) . . . . ?
C41 P1 C31 C32 158.0(5) . . . . ?
Pt1 P1 C31 C32 34.9(5) . . . . ?
C36 C31 C32 C33 1.5(9) . . . . ?
P1 C31 C32 C33 -173.2(5) . . . . ?
C31 C32 C33 C34 1.1(10) . . . . ?
C32 C33 C34 C35 -2.6(10) . . . . ?
C32 C33 C34 C37 175.5(6) . . . . ?
C33 C34 C35 C36 1.7(9) . . . . ?
C37 C34 C35 C36 -176.4(6) . . . . ?
C34 C35 C36 C31 0.8(9) . . . . ?
C32 C31 C36 C35 -2.4(8) . . . . ?
P1 C31 C36 C35 172.1(4) . . . . ?
C31 P1 C41 C46 -95.2(5) . . . . ?
C51 P1 C41 C46 153.0(4) . . . . ?
Pt1 P1 C41 C46 24.6(5) . . . . ?
C31 P1 C41 C42 82.9(5) . . . . ?
C51 P1 C41 C42 -29.0(5) . . . . ?
Pt1 P1 C41 C42 -157.3(4) . . . . ?
C46 C41 C42 C43 0.7(8) . . . . ?
P1 C41 C42 C43 -177.4(5) . . . . ?
C41 C42 C43 C44 -0.4(9) . . . . ?
C42 C43 C44 C45 -0.2(9) . . . . ?
C42 C43 C44 C47 -178.5(6) . . . . ?
C43 C44 C45 C46 0.6(10) . . . . ?
C47 C44 C45 C46 178.8(6) . . . . ?
C44 C45 C46 C41 -0.3(9) . . . . ?
C42 C41 C46 C45 -0.4(8) . . . . ?
P1 C41 C46 C45 177.7(5) . . . . ?
C31 P1 C51 C52 14.6(5) . . . . ?
C41 P1 C51 C52 125.6(4) . . . . ?
Pt1 P1 C51 C52 -107.7(4) . . . . ?
C31 P1 C51 C56 -170.1(4) . . . . ?
C41 P1 C51 C56 -59.1(5) . . . . ?
Pt1 P1 C51 C56 67.6(5) . . . . ?
C56 C51 C52 C53 1.4(8) . . . . ?
P1 C51 C52 C53 176.8(4) . . . . ?
C51 C52 C53 C54 -1.4(9) . . . . ?
C52 C53 C54 C55 0.1(9) . . . . ?
C52 C53 C54 C57 -179.3(6) . . . . ?
C53 C54 C55 C56 1.0(9) . . . . ?
C57 C54 C55 C56 -179.5(6) . . . . ?
C54 C55 C56 C51 -0.9(9) . . . . ?
C52 C51 C56 C55 -0.3(8) . . . . ?
P1 C51 C56 C55 -175.8(4) . . . . ?
C81 P2 C61 C66 172.2(4) . . . . ?
C71 P2 C61 C66 -76.9(5) . . . . ?
Pt1 P2 C61 C66 48.1(4) . . . . ?
C81 P2 C61 C62 -7.5(5) . . . . ?
C71 P2 C61 C62 103.4(5) . . . . ?
Pt1 P2 C61 C62 -131.6(4) . . . . ?
C66 C61 C62 C63 0.1(8) . . . . ?
P2 C61 C62 C63 179.7(4) . . . . ?
C61 C62 C63 C64 0.9(9) . . . . ?
C62 C63 C64 C65 -0.7(9) . . . . ?
C62 C63 C64 C67 179.7(6) . . . . ?
C63 C64 C65 C66 -0.4(9) . . . . ?
C67 C64 C65 C66 179.2(6) . . . . ?
C62 C61 C66 C65 -1.1(8) . . . . ?
P2 C61 C66 C65 179.2(4) . . . . ?
C64 C65 C66 C61 1.4(9) . . . . ?
C81 P2 C71 C76 -64.8(5) . . . . ?
C61 P2 C71 C76 -177.6(4) . . . . ?
Pt1 P2 C71 C76 62.4(5) . . . . ?
C81 P2 C71 C72 119.0(5) . . . . ?
C61 P2 C71 C72 6.2(5) . . . . ?
Pt1 P2 C71 C72 -113.8(4) . . . . ?
C76 C71 C72 C73 -4.3(8) . . . . ?
P2 C71 C72 C73 171.9(5) . . . . ?
C71 C72 C73 C74 0.4(9) . . . . ?
C72 C73 C74 C75 4.0(9) . . . . ?
C72 C73 C74 C77 -176.6(6) . . . . ?
C73 C74 C75 C76 -4.3(8) . . . . ?
C77 C74 C75 C76 176.3(5) . . . . ?
C72 C71 C76 C75 4.0(8) . . . . ?
P2 C71 C76 C75 -172.4(4) . . . . ?
C74 C75 C76 C71 0.3(9) . . . . ?
C71 P2 C81 C82 -27.5(6) . . . . ?
C61 P2 C81 C82 83.6(5) . . . . ?
Pt1 P2 C81 C82 -155.9(5) . . . . ?
C71 P2 C81 C86 155.7(5) . . . . ?
C61 P2 C81 C86 -93.2(5) . . . . ?
Pt1 P2 C81 C86 27.4(5) . . . . ?
C86 C81 C82 C83 -1.8(10) . . . . ?
P2 C81 C82 C83 -178.7(5) . . . . ?
C81 C82 C83 C84 -0.5(11) . . . . ?
C82 C83 C84 C85 2.9(10) . . . . ?
C82 C83 C84 C187 -178.2(6) . . . . ?
C83 C84 C85 C86 -3.0(10) . . . . ?
C187 C84 C85 C86 178.1(6) . . . . ?
C84 C85 C86 C81 0.8(10) . . . . ?
C82 C81 C86 C85 1.7(9) . . . . ?
P2 C81 C86 C85 178.6(5) . . . . ?
C12 Pt2 C101 C106 -166(3) . . . . ?
P3 Pt2 C101 C106 -101.4(5) . . . . ?
P4 Pt2 C101 C106 80.9(5) . . . . ?
C12 Pt2 C101 C102 13(4) . . . . ?
P3 Pt2 C101 C102 77.1(5) . . . . ?
P4 Pt2 C101 C102 -100.5(5) . . . . ?
C106 C101 C102 F102 -179.1(5) . . . . ?
Pt2 C101 C102 F102 2.2(8) . . . . ?
C106 C101 C102 C103 0.1(9) . . . . ?
Pt2 C101 C102 C103 -178.6(5) . . . . ?
F102 C102 C103 C104 179.4(6) . . . . ?
C101 C102 C103 C104 0.2(10) . . . . ?
F102 C102 C103 F103 -1.0(9) . . . . ?
C101 C102 C103 F103 179.8(6) . . . . ?
F103 C103 C104 F104 0.8(11) . . . . ?
C102 C103 C104 F104 -179.6(6) . . . . ?
F103 C103 C104 C105 179.7(6) . . . . ?
C102 C103 C104 C105 -0.7(11) . . . . ?
C103 C104 C105 F105 -178.7(6) . . . . ?
F104 C104 C105 F105 0.1(10) . . . . ?
C103 C104 C105 C106 1.0(11) . . . . ?
F104 C104 C105 C106 179.9(6) . . . . ?
F105 C105 C106 F106 -1.1(9) . . . . ?
C104 C105 C106 F106 179.1(6) . . . . ?
F105 C105 C106 C101 178.9(6) . . . . ?
C104 C105 C106 C101 -0.8(10) . . . . ?
C102 C101 C106 F106 -179.7(5) . . . . ?
Pt2 C101 C106 F106 -1.0(7) . . . . ?
C102 C101 C106 C105 0.3(9) . . . . ?
Pt2 C101 C106 C105 179.0(5) . . . . ?
C121 P3 C111 C112 133.0(5) . . . . ?
C131 P3 C111 C112 20.2(5) . . . . ?
Pt2 P3 C111 C112 -101.1(5) . . . . ?
C121 P3 C111 C116 -51.3(5) . . . . ?
C131 P3 C111 C116 -164.1(4) . . . . ?
Pt2 P3 C111 C116 74.7(4) . . . . ?
C116 C111 C112 C113 -0.5(8) . . . . ?
P3 C111 C112 C113 175.2(5) . . . . ?
C111 C112 C113 C114 -0.2(10) . . . . ?
C112 C113 C114 C115 1.0(10) . . . . ?
C112 C113 C114 C117 -179.6(6) . . . . ?
C113 C114 C115 C116 -1.2(9) . . . . ?
C117 C114 C115 C116 179.5(6) . . . . ?
C114 C115 C116 C111 0.5(9) . . . . ?
C112 C111 C116 C115 0.4(8) . . . . ?
P3 C111 C116 C115 -175.5(4) . . . . ?
C131 P3 C121 C122 -106.0(5) . . . . ?
C111 P3 C121 C122 143.7(4) . . . . ?
Pt2 P3 C121 C122 17.1(5) . . . . ?
C131 P3 C121 C126 76.2(5) . . . . ?
C111 P3 C121 C126 -34.1(5) . . . . ?
Pt2 P3 C121 C126 -160.6(4) . . . . ?
C126 C121 C122 C123 -0.6(8) . . . . ?
P3 C121 C122 C123 -178.4(4) . . . . ?
C121 C122 C123 C124 -0.2(9) . . . . ?
C122 C123 C124 C125 0.5(9) . . . . ?
C122 C123 C124 C127 -178.3(6) . . . . ?
C123 C124 C125 C126 0.0(10) . . . . ?
C127 C124 C125 C126 178.8(6) . . . . ?
C122 C121 C126 C125 1.1(9) . . . . ?
P3 C121 C126 C125 178.9(5) . . . . ?
C124 C125 C126 C121 -0.8(10) . . . . ?
C121 P3 C131 C136 -22.3(5) . . . . ?
C111 P3 C131 C136 87.4(5) . . . . ?
Pt2 P3 C131 C136 -148.0(4) . . . . ?
C121 P3 C131 C132 161.0(4) . . . . ?
C111 P3 C131 C132 -89.3(5) . . . . ?
Pt2 P3 C131 C132 35.3(5) . . . . ?
C136 C131 C132 C133 0.1(9) . . . . ?
P3 C131 C132 C133 177.0(5) . . . . ?
C131 C132 C133 C134 0.9(10) . . . . ?
C132 C133 C134 C135 -0.5(10) . . . . ?
C132 C133 C134 C137 179.6(6) . . . . ?
C133 C134 C135 C136 -0.9(10) . . . . ?
C137 C134 C135 C136 179.0(6) . . . . ?
C132 C131 C136 C135 -1.5(9) . . . . ?
P3 C131 C136 C135 -178.2(5) . . . . ?
C134 C135 C136 C131 1.9(10) . . . . ?
C151 P4 C141 C146 27.8(5) . . . . ?
C161 P4 C141 C146 141.1(5) . . . . ?
Pt2 P4 C141 C146 -95.7(5) . . . . ?
C151 P4 C141 C142 -160.1(5) . . . . ?
C161 P4 C141 C142 -46.8(5) . . . . ?
Pt2 P4 C141 C142 76.4(5) . . . . ?
C146 C141 C142 C143 0.1(9) . . . . ?
P4 C141 C142 C143 -172.2(5) . . . . ?
C141 C142 C143 C144 0.4(10) . . . . ?
C142 C143 C144 C145 -1.0(11) . . . . ?
C142 C143 C144 C147 -179.9(7) . . . . ?
C143 C144 C145 C146 0.9(11) . . . . ?
C147 C144 C145 C146 179.9(7) . . . . ?
C142 C141 C146 C145 -0.1(9) . . . . ?
P4 C141 C146 C145 172.1(5) . . . . ?
C144 C145 C146 C141 -0.4(11) . . . . ?
C161 P4 C151 C156 -37.1(5) . . . . ?
C141 P4 C151 C156 73.3(5) . . . . ?
Pt2 P4 C151 C156 -162.6(4) . . . . ?
C161 P4 C151 C152 146.7(4) . . . . ?
C141 P4 C151 C152 -102.8(5) . . . . ?
Pt2 P4 C151 C152 21.2(5) . . . . ?
C156 C151 C152 C153 -1.7(9) . . . . ?
P4 C151 C152 C153 174.6(5) . . . . ?
C151 C152 C153 C154 1.8(10) . . . . ?
C152 C153 C154 C155 -0.9(10) . . . . ?
C152 C153 C154 C157 179.8(6) . . . . ?
C153 C154 C155 C156 0.0(10) . . . . ?
C157 C154 C155 C156 179.2(6) . . . . ?
C152 C151 C156 C155 0.8(9) . . . . ?
P4 C151 C156 C155 -175.4(5) . . . . ?
C154 C155 C156 C151 0.1(10) . . . . ?
C151 P4 C161 C162 79.6(5) . . . . ?
C141 P4 C161 C162 -29.8(5) . . . . ?
Pt2 P4 C161 C162 -154.2(4) . . . . ?
C151 P4 C161 C166 -101.3(5) . . . . ?
C141 P4 C161 C166 149.3(5) . . . . ?
Pt2 P4 C161 C166 24.8(5) . . . . ?
C166 C161 C162 C163 -0.6(9) . . . . ?
P4 C161 C162 C163 178.5(4) . . . . ?
C161 C162 C163 C164 0.7(9) . . . . ?
C162 C163 C164 C165 -0.6(9) . . . . ?
C162 C163 C164 C167 -179.1(6) . . . . ?
C163 C164 C165 C166 0.4(9) . . . . ?
C167 C164 C165 C166 178.9(6) . . . . ?
C164 C165 C166 C161 -0.3(9) . . . . ?
C162 C161 C166 C165 0.4(9) . . . . ?
P4 C161 C166 C165 -178.7(4) . . . . ?
C206 C201 C202 C203 0.8(13) . . . . ?
C201 C202 C203 C204 -1.5(12) . . . . ?
C202 C203 C204 C205 0.9(12) . . . . ?
C203 C204 C205 C206 0.6(13) . . . . ?
C204 C205 C206 C201 -1.3(14) . . . . ?
C202 C201 C206 C205 0.6(13) . . . . ?
C216 C211 C212 C213 3.5(12) . . . . ?
C211 C212 C213 C214 -1.1(12) . . . . ?
C212 C213 C214 C215 0.1(12) . . . . ?
C213 C214 C215 C216 -1.6(12) . . . . ?
C214 C215 C216 C211 4.0(12) . . . . ?
C212 C211 C216 C215 -5.0(12) . . . . ?
O221 C222 C223 O224 -48(2) . . . . ?
C236 C231 C232 C233 2(2) . . . . ?
C231 C232 C233 C234 -3(2) . . . . ?
C232 C233 C234 C235 3(3) . . . . ?
C233 C234 C235 C236 -2(2) . . . . ?
C234 C235 C236 C231 1(2) . . . . ?
C232 C231 C236 C235 -1(2) . . . . ?
C246 C241 C242 C243 0.3(12) . . . . ?
C241 C242 C243 C244 0.5(13) . . . . ?
C242 C243 C244 C245 -2.2(14) . . . . ?
C243 C244 C245 C246 3.0(13) . . . . ?
C244 C245 C246 C241 -2.3(14) . . . . ?
C242 C241 C246 C245 0.7(14) . . . . ?
