Crystallography Open Database

Information card for entry 4321427

Preview

Coordinates	4321427.cif
Original paper (by DOI)	HTML

Structure parameters

Chemical name	tetramagnesium bis[tri(tert-butylsilyl)phosphanide] bis[tri(tert-butyl)silylphosphandiide]
Formula	C36 H83 Mg2 P3 Si3
Calculated formula	C36 H83 Mg2 P3 Si3
Title of publication	Polyhedral Members of the Mg2nP2m Family Derived from Dimeric Magnesium Trialkylsilylphosphandiide
Authors of publication	Matthias Westerhausen; Mathias Krofta; Peter Mayer; Marcus Warchhold; Heinrich Nöth
Journal of publication	Inorganic Chemistry
Year of publication	2000
Journal volume	39
Pages of publication	4721 - 4724
a	13.9513 ± 0.001 Å
b	14.2692 ± 0.001 Å
c	24.2088 ± 0.0017 Å
α	90°
β	102.415 ± 0.001°
γ	90°
Cell volume	4706.6 ± 0.6 Å³
Cell temperature	183 ± 2 K
Ambient diffraction temperature	183 ± 2 K
Number of distinct elements	5
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/n 1
Hall space group symbol	-P 2yn
Residual factor for all reflections	0.077
Residual factor for significantly intense reflections	0.0611
Weighted residual factors for significantly intense reflections	0.1569
Weighted residual factors for all reflections included in the refinement	0.175
Goodness-of-fit parameter for all reflections included in the refinement	1.026
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
179317 (current)	2016-03-23	cif/4/32/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/32/14.	4321427.cif
120105	2014-07-12	Adding DOIs to range 4/32 structures.	4321427.cif
34330	2012-02-24	cif/4/ Reorganising CIF range 4 into a prefix tree.	4321427.cif
18798	2011-05-04	../uploads/cif-deposit/cod/cif Adding structures of 4321427 via cif-deposit CGI script.	4321427.cif