Crystallography Open Database

Information card for entry 4321932

4321931 << 4321932 >> 4321933

Preview

Coordinates	4321932.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C62 H59 Cl4 Co4 N11 O25
Calculated formula	C63.75 H48 Cl4 Co4 N10 O26.25
Title of publication	[Co4O4]4+ Cubane Core as a Brønsted Base: Preparation and Properties of [Co4O3(OH)(O2CR)2(bpy)2]3+ and [Co4O2(OH)2(O2CR)2(bpy)2]4+ Salts
Authors of publication	Katerina Dimitrou; Angelica D. Brown; Kirsten Folting; George Christou
Journal of publication	Inorganic Chemistry
Year of publication	1999
Journal volume	38
Pages of publication	1834 - 1841
a	33.838 ± 0.008 Å
b	13.826 ± 0.003 Å
c	29.944 ± 0.007 Å
α	90°
β	98.844 ± 0.012°
γ	90°
Cell volume	13843 ± 6 Å³
Number of distinct elements	6
Space group number	15
Hermann-Mauguin space group symbol	C 1 2/c 1
Hall space group symbol	-C 2yc
Residual factor for significantly intense reflections	0.0832
Weighted residual factors for all reflections included in the refinement	0.0752
Goodness-of-fit parameter for all reflections included in the refinement	0
Diffraction radiation wavelength	0.71069 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
179322 (current)	2016-03-23	cif/4/32/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/32/19.	4321932.cif
120105	2014-07-12	Adding DOIs to range 4/32 structures.	4321932.cif
34330	2012-02-24	cif/4/ Reorganising CIF range 4 into a prefix tree.	4321932.cif
19795	2011-05-25	../uploads/cif-deposit/cod/cif Adding structures of 4321932 via cif-deposit CGI script.	4321932.cif