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Information card for entry 4323388
Preview
| Coordinates | 4323388.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C9 H15 Cl F12 N P2 Rh |
|---|---|
| Calculated formula | C18 H30 Cl F12 N2 P2 Rh |
| SMILES | [Rh]12345678([cH]9[c]4([cH]3[cH]2[cH]19)CC[NH+](C)C)[c]1([cH]5[cH]6[cH]7[cH]81)CC[NH+](C)C.[P](F)(F)(F)(F)(F)[F-].[P](F)(F)(F)(F)(F)[F-].[Cl-] |
| Title of publication | Transition-Metal Derivatives of a Functionalized Cyclopentadienyl Ligand. 15.Synthesis and Structures of Amino Cyclopentadienyl Derivatives of Rhodium(I) and Rhodium(III) Including Water-Soluble Compounds |
| Authors of publication | Athanassios I. Philippopoulos; Nick Hadjiliadis; Claire E. Hart; Bruno Donnadieu; Patrick C. Mc Gowan; René Poilblanc |
| Journal of publication | Inorganic Chemistry |
| Year of publication | 1997 |
| Journal volume | 36 |
| Pages of publication | 1842 - 1849 |
| a | 6.617 ± 0.002 Å |
| b | 7.436 ± 0.002 Å |
| c | 13.965 ± 0.003 Å |
| α | 76.39 ± 0.02° |
| β | 82.31 ± 0.02° |
| γ | 87.26 ± 0.02° |
| Cell volume | 661.7 ± 0.3 Å3 |
| Cell temperature | 293 K |
| Ambient diffraction temperature | 293 K |
| Number of distinct elements | 7 |
| Space group number | 1 |
| Hermann-Mauguin space group symbol | P 1 |
| Hall space group symbol | P 1 |
| Residual factor for significantly intense reflections | 0.044 |
| Weighted residual factors for significantly intense reflections | 0.0484 |
| Goodness-of-fit parameter for significantly intense reflections | 3.6013 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 209078 (current) | 2018-07-17 | cif/4/32/33/ Removing the _exptl_crystal_density_diffrn data item in entry 4323388 since it clearly contains an incorrect value ("0.0"). |
4323388.cif |
| 176467 | 2016-02-16 | cif/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in range 4. |
4323388.cif |
| 120105 | 2014-07-12 | Adding DOIs to range 4/32 structures. | 4323388.cif |
| 34330 | 2012-02-24 | cif/4/ Reorganising CIF range 4 into a prefix tree. |
4323388.cif |
| 23418 | 2011-08-08 | ../uploads/cif-deposit/cod/cif Adding structures of 4323388 via cif-deposit CGI script. |
4323388.cif |
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