Crystallography Open Database

Information card for entry 4325120

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Structure parameters

Chemical name	Lithium Manganese(III) tetrakis(bistert-butyl ketimide)
Formula	C36 H72 Li Mn N4
Calculated formula	C36 H72 Li Mn N4
Title of publication	Stabilizing High-Valent Metal Ions with a Ketimide Ligand Set: Synthesis of Mn(N=CtBu2)4
Authors of publication	Richard A. Lewis; Guang Wu; Trevor W. Hayton
Journal of publication	Inorganic Chemistry
Year of publication	2011
Journal volume	50
Pages of publication	4660 - 4668
a	16.7762 ± 0.0012 Å
b	15.2054 ± 0.001 Å
c	15.8446 ± 0.0011 Å
α	90°
β	90°
γ	90°
Cell volume	4041.8 ± 0.5 Å³
Cell temperature	150 ± 2 K
Ambient diffraction temperature	150 ± 2 K
Number of distinct elements	5
Space group number	52
Hermann-Mauguin space group symbol	P n n a
Hall space group symbol	-P 2a 2bc
Residual factor for all reflections	0.1033
Residual factor for significantly intense reflections	0.0641
Weighted residual factors for significantly intense reflections	0.1655
Weighted residual factors for all reflections included in the refinement	0.1999
Goodness-of-fit parameter for all reflections included in the refinement	1.028
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
301838 (current)	2025-08-21	Add cross-references to PubChem compounds in COD range 4/32/ Each referenced PubChem compound corresponds to the full crystal structure.	4325120.cif
179354	2016-03-23	cif/4/32/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/32/51.	4325120.cif
91935	2013-12-29	cod/ (saulius@koala.ibt.lt) Adding DOIs that could be assigned unambiguously to the rest of COD CIFs.	4325120.cif
43572	2012-03-15	../uploads/cif-deposit/cod/cif Adding structures of 4325120 via cif-deposit CGI script.	4325120.cif