Crystallography Open Database

Information card for entry 4325122

Preview

Coordinates	4325122.cif
Original paper (by DOI)	HTML

Structure parameters

Chemical name	Manganese (IV) tetrakis(bistert-butyl ketimide)
Formula	C36 H72 Mn N4
Calculated formula	C36 H63 Mn N4
Title of publication	Stabilizing High-Valent Metal Ions with a Ketimide Ligand Set: Synthesis of Mn(N=CtBu2)4
Authors of publication	Richard A. Lewis; Guang Wu; Trevor W. Hayton
Journal of publication	Inorganic Chemistry
Year of publication	2011
Journal volume	50
Pages of publication	4660 - 4668
a	11.356 ± 0.006 Å
b	11.738 ± 0.006 Å
c	16.586 ± 0.01 Å
α	70.2 ± 0.02°
β	89.51 ± 0.02°
γ	73.21 ± 0.019°
Cell volume	1981.7 ± 1.9 Å³
Cell temperature	150 ± 2 K
Ambient diffraction temperature	150 ± 2 K
Number of distinct elements	4
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.096
Residual factor for significantly intense reflections	0.066
Weighted residual factors for significantly intense reflections	0.1731
Weighted residual factors for all reflections included in the refinement	0.1943
Goodness-of-fit parameter for all reflections included in the refinement	1.01
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
179354 (current)	2016-03-23	cif/4/32/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/32/51.	4325122.cif
91935	2013-12-29	cod/ (saulius@koala.ibt.lt) Adding DOIs that could be assigned unambiguously to the rest of COD CIFs.	4325122.cif
43574	2012-03-15	../uploads/cif-deposit/cod/cif Adding structures of 4325122 via cif-deposit CGI script.	4325122.cif