Crystallography Open Database

Information card for entry 4325238

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Coordinates	4325238.cif
Original paper (by DOI)	HTML

Structure parameters

Chemical name	Triphenylmonoiodophosphonium Uranium(V) tetraiodo-bistrimethylsilyloxide
Formula	C24 H33 I5 O2 P Si2 U
Calculated formula	C24 H33 I5 O2 P Si2 U
Title of publication	Facile Reduction of a Uranyl(VI) β-Ketoiminate Complex to U(IV) Upon Oxo Silylation
Authors of publication	Jessie L. Brown; Charles C. Mokhtarzadeh; Jeremie M. Lever; Guang Wu; Trevor W. Hayton
Journal of publication	Inorganic Chemistry
Year of publication	2011
Journal volume	50
Pages of publication	5105 - 5112
a	9.452 ± 0.007 Å
b	9.961 ± 0.008 Å
c	20.94 ± 0.016 Å
α	103.327 ± 0.012°
β	90.511 ± 0.013°
γ	101.222 ± 0.012°
Cell volume	1879 ± 3 Å³
Cell temperature	150 ± 2 K
Ambient diffraction temperature	150 ± 2 K
Number of distinct elements	7
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0654
Residual factor for significantly intense reflections	0.0494
Weighted residual factors for significantly intense reflections	0.1216
Weighted residual factors for all reflections included in the refinement	0.1346
Goodness-of-fit parameter for all reflections included in the refinement	1.004
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
179355 (current)	2016-03-23	cif/4/32/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/32/52.	4325238.cif
91935	2013-12-29	cod/ (saulius@koala.ibt.lt) Adding DOIs that could be assigned unambiguously to the rest of COD CIFs.	4325238.cif
43691	2012-03-15	../uploads/cif-deposit/cod/cif Adding structures of 4325238 via cif-deposit CGI script.	4325238.cif