Crystallography Open Database

Information card for entry 4330567

Preview

Coordinates	4330567.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C32 H48 Cl13 N5 P2 Rh Sb2
Calculated formula	C32 H48 Cl13 N5 P2 Rh Sb2
SMILES	[Sb](Cl)(Cl)(Cl)(Cl)(Cl)[Cl-].[Sb](Cl)(Cl)(Cl)(Cl)(Cl)[Cl-].[Rh]12(Cl)([P](CC)(CC)CC)([P](CC)(CC)CC)N(c3c(n4[n]1ccc4)cc(cc3)C)c1c(n3[n]2ccc3)cc(cc1)C
Title of publication	Syntheses and Electronic Properties of Rhodium(III) Complexes Bearing a Redox-Active Ligand
Authors of publication	Sarath Wanniarachchi; Brendan J. Liddle; Brandon Kizer; Jeewantha S. Hewage; Sergey V. Lindeman; James R. Gardinier
Journal of publication	Inorganic Chemistry
Year of publication	2012
Journal volume	51
Pages of publication	10572 - 10580
a	13.2609 ± 0.0003 Å
b	20.1369 ± 0.0004 Å
c	20.3237 ± 0.0004 Å
α	90°
β	107.415 ± 0.001°
γ	90°
Cell volume	5178.34 ± 0.19 Å³
Cell temperature	100 ± 2 K
Ambient diffraction temperature	100 ± 2 K
Number of distinct elements	7
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/n 1
Hall space group symbol	-P 2yn
Residual factor for all reflections	0.058
Residual factor for significantly intense reflections	0.0397
Weighted residual factors for significantly intense reflections	0.0903
Weighted residual factors for all reflections included in the refinement	0.0967
Goodness-of-fit parameter for all reflections included in the refinement	1.02
Diffraction radiation wavelength	1.54178 Å
Diffraction radiation type	CuKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
179408 (current)	2016-03-23	cif/4/33/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/33/05.	4330567.cif
80020	2013-04-06	cif/ Adding structures of 4330567 via cif-deposit CGI script.	4330567.cif