#------------------------------------------------------------------------------
#$Date: 2016-03-23 22:59:06 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179498 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/95/4339527.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4339527
loop_
_publ_author_name
'Tobash, Paul H.'
'DiFilippo, Gary'
'Bobev, Svilen'
'Hur, Namjung'
'Thompson, Joe D.'
'Sarrao, John L.'
_publ_section_title
;
 Structure and properties of Gd3Ge4: the orthorhombic RE3Ge4 structures
 revisited (RE = Y, Tb-Tm).
;
_journal_issue                   21
_journal_name_full               'Inorganic chemistry'
_journal_page_first              8690
_journal_page_last               8697
_journal_paper_doi               10.1021/ic7009034
_journal_volume                  46
_journal_year                    2007
_chemical_formula_moiety         4(Ge),3(Tb)
_chemical_formula_sum            'Ge4 Tb3'
_chemical_formula_weight         767.12
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           63
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-C 2c 2'
_symmetry_space_group_name_H-M   'C m c m'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2007-04-11 # Formatted by publCIF
;
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   4.0629(7)
_cell_length_b                   10.6647(19)
_cell_length_c                   14.245(3)
_cell_measurement_reflns_used    372
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      26.28
_cell_measurement_theta_min      2.86
_cell_volume                     617.2(2)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      120(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0322
_diffrn_reflns_av_sigmaI/netI    0.0248
_diffrn_reflns_limit_h_max       5
_diffrn_reflns_limit_h_min       -5
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            1984
_diffrn_reflns_theta_full        26.28
_diffrn_reflns_theta_max         26.28
_diffrn_reflns_theta_min         2.86
_exptl_absorpt_coefficient_mu    52.959
_exptl_absorpt_correction_T_max  0.2054
_exptl_absorpt_correction_T_min  0.0900
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
; 
SADABS (Sheldrick, 2003)
;
_exptl_crystal_colour            silver
_exptl_crystal_density_diffrn    8.255
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             1292
_exptl_crystal_size_max          0.05
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.03
_refine_diff_density_max         1.452
_refine_diff_density_min         -1.496
_refine_diff_density_rms         0.296
_refine_ls_extinction_coef       0.00382(16)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.205
_refine_ls_matrix_type           full
_refine_ls_number_parameters     28
_refine_ls_number_reflns         372
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.205
_refine_ls_R_factor_all          0.0226
_refine_ls_R_factor_gt           0.0214
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0041P)²+19.5760P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0434
_refine_ls_wR_factor_ref         0.0440
_reflns_number_gt                363
_reflns_number_total             372
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic7009034-file003.cif
_cod_data_source_block           Tb3Ge4
_cod_original_cell_volume        617.23(19)
_cod_database_code               4339527
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z+1/2'
'-x, y, -z+1/2'
'x, -y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x, y, -z-1/2'
'x, -y, z-1/2'
'-x, y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, y+1/2, -z-1/2'
'x+1/2, -y+1/2, z-1/2'
'-x+1/2, y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Tb2 Tb 0.0000 0.04502(6) 0.2500 0.0081(2) Uani 1 4 d S
Tb1 Tb 0.0000 0.33137(4) 0.09691(4) 0.0084(2) Uani 1 2 d S
Ge1 Ge 0.0000 0.0204(2) 0.0164(2) 0.0082(7) Uani 0.50 2 d SP
Ge3 Ge 0.0000 0.77248(13) 0.2500 0.0094(3) Uani 1 4 d S
Ge2 Ge 0.0000 0.62070(10) 0.10911(8) 0.0105(3) Uani 1 2 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Tb Tb -0.1723 4.1537 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge3 Tb2 Ge2 105.78(2) 1_545 5_445
Ge3 Tb2 Ge2 105.78(2) 1_545 5_545
Ge2 Tb2 Ge2 86.40(3) 5_445 5_545
Ge3 Tb2 Ge2 105.78(2) 1_545 14_546
Ge2 Tb2 Ge2 148.43(5) 5_445 14_546
Ge2 Tb2 Ge2 85.11(4) 5_545 14_546
Ge3 Tb2 Ge2 105.78(2) 1_545 14_446
Ge2 Tb2 Ge2 85.11(4) 5_445 14_446
Ge2 Tb2 Ge2 148.43(5) 5_545 14_446
Ge2 Tb2 Ge2 86.40(3) 14_546 14_446
Ge3 Tb2 Ge3 140.056(19) 1_545 5_545
Ge2 Tb2 Ge3 103.36(3) 5_445 5_545
Ge2 Tb2 Ge3 49.61(2) 5_545 5_545
Ge2 Tb2 Ge3 49.61(2) 14_546 5_545
Ge2 Tb2 Ge3 103.35(3) 14_446 5_545
Ge3 Tb2 Ge3 140.056(19) 1_545 5_445
Ge2 Tb2 Ge3 49.61(2) 5_445 5_445
Ge2 Tb2 Ge3 103.36(3) 5_545 5_445
Ge2 Tb2 Ge3 103.35(3) 14_546 5_445
Ge2 Tb2 Ge3 49.61(2) 14_446 5_445
Ge3 Tb2 Ge3 79.89(4) 5_545 5_445
Ge3 Tb2 Ge1 85.49(5) 1_545 .
Ge2 Tb2 Ge1 49.25(3) 5_445 .
Ge2 Tb2 Ge1 49.25(3) 5_545 .
Ge2 Tb2 Ge1 134.08(2) 14_546 .
Ge2 Tb2 Ge1 134.08(2) 14_446 .
Ge3 Tb2 Ge1 93.46(4) 5_545 .
Ge3 Tb2 Ge1 93.46(4) 5_445 .
Ge3 Tb2 Ge1 85.49(5) 1_545 10_556
Ge2 Tb2 Ge1 134.07(2) 5_445 10_556
Ge2 Tb2 Ge1 134.07(2) 5_545 10_556
Ge2 Tb2 Ge1 49.25(3) 14_546 10_556
Ge2 Tb2 Ge1 49.25(3) 14_446 10_556
Ge3 Tb2 Ge1 93.46(4) 5_545 10_556
Ge3 Tb2 Ge1 93.46(4) 5_445 10_556
Ge1 Tb2 Ge1 170.98(9) . 10_556
Ge3 Tb2 Tb1 52.602(12) 1_545 5_445
Ge2 Tb2 Tb1 53.23(2) 5_445 5_445
Ge2 Tb2 Tb1 98.21(2) 5_545 5_445
Ge2 Tb2 Tb1 158.28(3) 14_546 5_445
Ge2 Tb2 Tb1 100.82(2) 14_446 5_445
Ge3 Tb2 Tb1 144.420(11) 5_545 5_445
Ge3 Tb2 Tb1 96.776(18) 5_445 5_445
Ge1 Tb2 Tb1 51.15(3) . 5_445
Ge1 Tb2 Tb1 122.12(4) 10_556 5_445
Ge3 Tb2 Tb1 52.602(12) 1_545 5_545
Ge2 Tb2 Tb1 98.21(2) 5_445 5_545
Ge2 Tb2 Tb1 53.23(2) 5_545 5_545
Ge2 Tb2 Tb1 100.82(2) 14_546 5_545
Ge2 Tb2 Tb1 158.28(3) 14_446 5_545
Ge3 Tb2 Tb1 96.776(18) 5_545 5_545
Ge3 Tb2 Tb1 144.420(11) 5_445 5_545
Ge1 Tb2 Tb1 51.15(3) . 5_545
Ge1 Tb2 Tb1 122.12(4) 10_556 5_545
Tb1 Tb2 Tb1 65.571(16) 5_445 5_545
Ge3 Tb2 Tb1 52.602(12) 1_545 14_446
Ge2 Tb2 Tb1 100.82(2) 5_445 14_446
Ge2 Tb2 Tb1 158.28(3) 5_545 14_446
Ge2 Tb2 Tb1 98.21(2) 14_546 14_446
Ge2 Tb2 Tb1 53.23(2) 14_446 14_446
Ge3 Tb2 Tb1 144.419(11) 5_545 14_446
Ge3 Tb2 Tb1 96.776(18) 5_445 14_446
Ge1 Tb2 Tb1 122.12(4) . 14_446
Ge1 Tb2 Tb1 51.15(3) 10_556 14_446
Tb1 Tb2 Tb1 71.08(2) 5_445 14_446
Tb1 Tb2 Tb1 105.20(2) 5_545 14_446
Ge2 Tb1 Ge2 100.58(3) 9_565 5_445
Ge2 Tb1 Ge2 100.58(3) 9_565 5_545
Ge2 Tb1 Ge2 84.07(3) 5_445 5_545
Ge2 Tb1 Ge1 52.21(5) 9_565 13_455
Ge2 Tb1 Ge1 88.17(4) 5_445 13_455
Ge2 Tb1 Ge1 149.70(5) 5_545 13_455
Ge2 Tb1 Ge1 52.21(4) 9_565 13
Ge2 Tb1 Ge1 149.70(5) 5_445 13
Ge2 Tb1 Ge1 88.17(4) 5_545 13
Ge1 Tb1 Ge1 83.91(9) 13_455 13
Ge2 Tb1 Ge3 137.797(10) 9_565 5_545
Ge2 Tb1 Ge3 104.65(3) 5_445 5_545
Ge2 Tb1 Ge3 50.19(3) 5_545 5_545
Ge1 Tb1 Ge3 159.01(4) 13_455 5_545
Ge1 Tb1 Ge3 92.40(5) 13 5_545
Ge2 Tb1 Ge3 137.797(10) 9_565 5_445
Ge2 Tb1 Ge3 50.19(3) 5_445 5_445
Ge2 Tb1 Ge3 104.65(3) 5_545 5_445
Ge1 Tb1 Ge3 92.40(5) 13_455 5_445
Ge1 Tb1 Ge3 159.01(4) 13 5_445
Ge3 Tb1 Ge3 83.66(2) 5_545 5_445
Ge2 Tb1 Ge1 61.41(5) 9_565 5
Ge2 Tb1 Ge1 161.22(5) 5_445 5
Ge2 Tb1 Ge1 93.69(4) 5_545 5
Ge1 Tb1 Ge1 84.419(19) 13_455 5
Ge1 Tb1 Ge1 11.96(7) 13 5
Ge3 Tb1 Ge1 87.80(5) 5_545 5
Ge3 Tb1 Ge1 147.19(5) 5_445 5
Ge2 Tb1 Ge1 61.41(5) 9_565 5_455
Ge2 Tb1 Ge1 93.69(4) 5_445 5_455
Ge2 Tb1 Ge1 161.22(5) 5_545 5_455
Ge1 Tb1 Ge1 11.96(7) 13_455 5_455
Ge1 Tb1 Ge1 84.419(19) 13 5_455
Ge3 Tb1 Ge1 147.19(5) 5_545 5_455
Ge3 Tb1 Ge1 87.80(5) 5_445 5_455
Ge1 Tb1 Ge1 82.43(8) 5 5_455
Ge2 Tb1 Ge2 83.34(3) 9_565 .
Ge2 Tb1 Ge2 137.402(17) 5_445 .
Ge2 Tb1 Ge2 137.402(17) 5_545 .
Ge1 Tb1 Ge2 60.69(4) 13_455 .
Ge1 Tb1 Ge2 60.69(4) 13 .
Ge3 Tb1 Ge2 99.53(3) 5_545 .
Ge3 Tb1 Ge2 99.53(3) 5_445 .
Ge1 Tb1 Ge2 50.81(3) 5 .
Ge1 Tb1 Ge2 50.81(3) 5_455 .
Ge2 Tb1 Tb2 117.93(2) 9_565 5
Ge2 Tb1 Tb2 141.17(3) 5_445 5
Ge2 Tb1 Tb2 93.09(2) 5_545 5
Ge1 Tb1 Tb2 110.79(4) 13_455 5
Ge1 Tb1 Tb2 68.34(4) 13 5
Ge3 Tb1 Tb2 49.30(3) 5_545 5
Ge3 Tb1 Tb2 94.02(2) 5_445 5
Ge1 Tb1 Tb2 57.47(5) 5 5
Ge1 Tb1 Tb2 100.12(4) 5_455 5
Ge2 Tb1 Tb2 50.276(19) . 5
Ge2 Tb1 Tb2 117.93(2) 9_565 5_455
Ge2 Tb1 Tb2 93.09(2) 5_445 5_455
Ge2 Tb1 Tb2 141.17(3) 5_545 5_455
Ge1 Tb1 Tb2 68.34(4) 13_455 5_455
Ge1 Tb1 Tb2 110.79(4) 13 5_455
Ge3 Tb1 Tb2 94.02(2) 5_545 5_455
Ge3 Tb1 Tb2 49.30(3) 5_445 5_455
Ge1 Tb1 Tb2 100.12(4) 5 5_455
Ge1 Tb1 Tb2 57.47(5) 5_455 5_455
Ge2 Tb1 Tb2 50.276(19) . 5_455
Tb2 Tb1 Tb2 65.570(16) 5 5_455
Ge1 Ge1 Ge2 129.80(5) 9 5_545
Ge1 Ge1 Ge2 129.80(5) 9 5_445
Ge2 Ge1 Ge2 100.18(7) 5_545 5_445
Ge1 Ge1 Tb1 88.0(5) 9 13
Ge2 Ge1 Tb1 62.74(4) 5_545 13
Ge2 Ge1 Tb1 124.58(10) 5_445 13
Ge1 Ge1 Tb1 88.0(5) 9 13_455
Ge2 Ge1 Tb1 124.58(10) 5_545 13_455
Ge2 Ge1 Tb1 62.74(4) 5_445 13_455
Tb1 Ge1 Tb1 83.91(9) 13 13_455
Ge1 Ge1 Tb1 80.1(4) 9 5_445
Ge2 Ge1 Tb1 125.74(12) 5_545 5_445
Ge2 Ge1 Tb1 64.74(5) 5_445 5_445
Tb1 Ge1 Tb1 168.04(7) 13 5_445
Tb1 Ge1 Tb1 95.582(19) 13_455 5_445
Ge1 Ge1 Tb1 80.1(4) 9 5_545
Ge2 Ge1 Tb1 64.74(5) 5_545 5_545
Ge2 Ge1 Tb1 125.74(12) 5_445 5_545
Tb1 Ge1 Tb1 95.582(19) 13 5_545
Tb1 Ge1 Tb1 168.04(7) 13_455 5_545
Tb1 Ge1 Tb1 82.43(8) 5_445 5_545
Ge1 Ge1 Tb2 141.6(7) 9 .
Ge2 Ge1 Tb2 58.08(5) 5_545 .
Ge2 Ge1 Tb2 58.08(5) 5_445 .
Tb1 Ge1 Tb2 119.26(4) 13 .
Tb1 Ge1 Tb2 119.26(4) 13_455 .
Tb1 Ge1 Tb2 71.38(7) 5_445 .
Tb1 Ge1 Tb2 71.38(7) 5_545 .
Ge2 Ge3 Ge2 102.22(7) 10_556 .
Ge2 Ge3 Tb2 128.89(4) 10_556 1_565
Ge2 Ge3 Tb2 128.89(4) . 1_565
Ge2 Ge3 Tb1 133.37(3) 10_556 5_455
Ge2 Ge3 Tb1 64.67(2) . 5_455
Tb2 Ge3 Tb1 78.10(3) 1_565 5_455
Ge2 Ge3 Tb1 133.37(3) 10_556 5
Ge2 Ge3 Tb1 64.67(2) . 5
Tb2 Ge3 Tb1 78.10(3) 1_565 5
Tb1 Ge3 Tb1 83.67(2) 5_455 5
Ge2 Ge3 Tb1 64.67(2) 10_556 14_556
Ge2 Ge3 Tb1 133.37(3) . 14_556
Tb2 Ge3 Tb1 78.10(3) 1_565 14_556
Tb1 Ge3 Tb1 156.20(5) 5_455 14_556
Tb1 Ge3 Tb1 91.45(2) 5 14_556
Ge2 Ge3 Tb1 64.67(2) 10_556 14_456
Ge2 Ge3 Tb1 133.37(3) . 14_456
Tb2 Ge3 Tb1 78.10(3) 1_565 14_456
Tb1 Ge3 Tb1 91.45(2) 5_455 14_456
Tb1 Ge3 Tb1 156.20(5) 5 14_456
Tb1 Ge3 Tb1 83.67(2) 14_556 14_456
Ge2 Ge3 Tb2 61.23(3) 10_556 5_455
Ge2 Ge3 Tb2 61.23(3) . 5_455
Tb2 Ge3 Tb2 140.056(19) 1_565 5_455
Tb1 Ge3 Tb2 74.327(17) 5_455 5_455
Tb1 Ge3 Tb2 125.89(3) 5 5_455
Tb1 Ge3 Tb2 125.89(3) 14_556 5_455
Tb1 Ge3 Tb2 74.327(17) 14_456 5_455
Ge2 Ge3 Tb2 61.23(3) 10_556 5
Ge2 Ge3 Tb2 61.23(3) . 5
Tb2 Ge3 Tb2 140.056(19) 1_565 5
Tb1 Ge3 Tb2 125.89(3) 5_455 5
Tb1 Ge3 Tb2 74.327(17) 5 5
Tb1 Ge3 Tb2 74.327(17) 14_556 5
Tb1 Ge3 Tb2 125.89(3) 14_456 5
Tb2 Ge3 Tb2 79.89(4) 5_455 5
Ge3 Ge2 Ge1 129.91(4) . 5_455
Ge3 Ge2 Ge1 129.91(4) . 5
Ge1 Ge2 Ge1 100.18(7) 5_455 5
Ge3 Ge2 Tb2 69.17(3) . 5
Ge1 Ge2 Tb2 138.80(8) 5_455 5
Ge1 Ge2 Tb2 72.67(6) 5 5
Ge3 Ge2 Tb2 69.17(3) . 5_455
Ge1 Ge2 Tb2 72.67(6) 5_455 5_455
Ge1 Ge2 Tb2 138.80(8) 5 5_455
Tb2 Ge2 Tb2 86.40(3) 5 5_455
Ge3 Ge2 Tb1 131.23(5) . 9_565
Ge1 Ge2 Tb1 65.05(7) 5_455 9_565
Ge1 Ge2 Tb1 65.05(7) 5 9_565
Tb2 Ge2 Tb1 135.476(19) 5 9_565
Tb2 Ge2 Tb1 135.476(19) 5_455 9_565
Ge3 Ge2 Tb1 65.15(3) . 5
Ge1 Ge2 Tb1 141.64(9) 5_455 5
Ge1 Ge2 Tb1 75.93(5) 5 5
Tb2 Ge2 Tb1 77.40(2) 5 5
Tb2 Ge2 Tb1 134.31(4) 5_455 5
Tb1 Ge2 Tb1 79.42(3) 9_565 5
Ge3 Ge2 Tb1 65.15(3) . 5_455
Ge1 Ge2 Tb1 75.93(5) 5_455 5_455
Ge1 Ge2 Tb1 141.64(9) 5 5_455
Tb2 Ge2 Tb1 134.31(4) 5 5_455
Tb2 Ge2 Tb1 77.40(2) 5_455 5_455
Tb1 Ge2 Tb1 79.42(3) 9_565 5_455
Tb1 Ge2 Tb1 84.07(3) 5 5_455
Ge3 Ge2 Tb1 132.11(5) . .
Ge1 Ge2 Tb1 64.45(6) 5_455 .
Ge1 Ge2 Tb1 64.45(6) 5 .
Tb2 Ge2 Tb1 76.50(3) 5 .
Tb2 Ge2 Tb1 76.50(3) 5_455 .
Tb1 Ge2 Tb1 96.66(3) 9_565 .
Tb1 Ge2 Tb1 137.403(17) 5 .
Tb1 Ge2 Tb1 137.402(17) 5_455 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Tb2 Ge3 2.9065(16) 1_545
Tb2 Ge2 2.9675(9) 5_445
Tb2 Ge2 2.9675(9) 5_545
Tb2 Ge2 2.9675(9) 14_546
Tb2 Ge2 2.9675(9) 14_446
Tb2 Ge3 3.1641(13) 5_545
Tb2 Ge3 3.1641(13) 5_445
Tb2 Ge1 3.338(3) .
Tb2 Ge1 3.338(3) 10_556
Tb2 Tb1 3.7516(7) 5_445
Tb2 Tb1 3.7516(7) 5_545
Tb2 Tb1 3.7516(7) 14_446
Tb1 Ge2 2.9790(14) 9_565
Tb1 Ge2 3.0339(9) 5_445
Tb1 Ge2 3.0339(9) 5_545
Tb1 Ge1 3.039(3) 13_455
Tb1 Ge1 3.039(3) 13
Tb1 Ge3 3.0459(6) 5_545
Tb1 Ge3 3.0459(6) 5_445
Tb1 Ge1 3.083(2) 5
Tb1 Ge1 3.083(2) 5_455
Tb1 Ge2 3.0906(13) .
Tb1 Tb2 3.7516(7) 5
Tb1 Tb2 3.7516(7) 5_455
Ge1 Ge1 0.639(4) 9
Ge1 Ge2 2.6484(15) 5_545
Ge1 Ge2 2.6484(15) 5_445
Ge1 Tb1 3.039(3) 13
Ge1 Tb1 3.039(3) 13_455
Ge1 Tb1 3.083(2) 5_445
Ge1 Tb1 3.083(2) 5_545
Ge3 Ge2 2.5784(15) 10_556
Ge3 Ge2 2.5784(15) .
Ge3 Tb2 2.9065(16) 1_565
Ge3 Tb1 3.0458(6) 5_455
Ge3 Tb1 3.0458(6) 5
Ge3 Tb1 3.0458(6) 14_556
Ge3 Tb1 3.0458(6) 14_456
Ge3 Tb2 3.1641(13) 5_455
Ge3 Tb2 3.1641(13) 5
Ge2 Ge1 2.6484(15) 5_455
Ge2 Ge1 2.6484(15) 5
Ge2 Tb2 2.9675(9) 5
Ge2 Tb2 2.9675(9) 5_455
Ge2 Tb1 2.9790(14) 9_565
Ge2 Tb1 3.0339(9) 5
Ge2 Tb1 3.0339(9) 5_455
