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Information card for entry 4341286
Preview
| Coordinates | 4341286.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C28 H35 Fe Mo2 O5 P3 |
|---|---|
| Calculated formula | C28 H35 Fe Mo2 O5 P3 |
| SMILES | [Mo]123456([P](C7CCCCC7)(C7CCCCC7)[Mo]789%10%11([P]1([Fe](P49)(C#[O])(C#[O])C#[O])C)(C#[O])[cH]1[cH]8[cH]7[cH]%11[cH]%101)(C#[O])[cH]1[cH]5[cH]6[cH]3[cH]21 |
| Title of publication | Mild P-P Bond Cleavage in the Methyldiphosphenyl Complex [Mo2Cp2(μ-PCy2)(μ-κ(2):κ(2)-P2Me)(CO)2] To Give Novel Phosphide-Bridged Trinuclear Derivatives. |
| Authors of publication | Alvarez, M. Angeles; García, M Esther; García-Vivó, Daniel; Lozano, Raquel; Ramos, Alberto; Ruiz, Miguel A. |
| Journal of publication | Inorganic chemistry |
| Year of publication | 2014 |
| Journal volume | 53 |
| Journal issue | 20 |
| Pages of publication | 11261 - 11273 |
| a | 9.9099 ± 0.0002 Å |
| b | 23.5511 ± 0.0005 Å |
| c | 15.7915 ± 0.0004 Å |
| α | 90° |
| β | 116.591 ± 0.002° |
| γ | 90° |
| Cell volume | 3295.72 ± 0.14 Å3 |
| Cell temperature | 100.2 ± 0.2 K |
| Ambient diffraction temperature | 100 ± 2 K |
| Number of distinct elements | 6 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/c 1 |
| Hall space group symbol | -P 2ybc |
| Residual factor for all reflections | 0.0345 |
| Residual factor for significantly intense reflections | 0.0303 |
| Weighted residual factors for significantly intense reflections | 0.0863 |
| Weighted residual factors for all reflections included in the refinement | 0.0888 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.074 |
| Diffraction radiation probe | x-ray |
| Diffraction radiation wavelength | 1.54184 Å |
| Diffraction radiation type | CuKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 179515 (current) | 2016-03-23 | cif/4/34/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/34/12. |
4341286.cif |
| 126926 | 2014-11-12 | cif/ Updating files of 4341286, 4341287, 4341288, 4341289 Original log message: Adding full bibliography for 4341286--4341289.cif. |
4341286.cif |
| 125293 | 2014-10-12 | cif/ Adding structures of 4341286, 4341287, 4341288, 4341289 via cif-deposit CGI script. |
4341286.cif |
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