Crystallography Open Database

Information card for entry 4342610

Preview

Coordinates	4342610.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C26 H70 F6 N4 O6 S2 Si8 U2
Calculated formula	C26 H70 F6 N4 O6 S2 Si8 U2
SMILES	C[Si](C)(C)N1[U]23(N([Si](C)(C)C)[Si](C)(C)C)[O]=S(O[U](C[Si]1(C)C)(N([Si](C2)(C)C)[Si](C)(C)C)(N([Si](C)(C)C)[Si](C)(C)C)[O]=S(O3)(=O)C(F)(F)F)(=O)C(F)(F)F
Title of publication	U(III)-CN versus U(IV)-NC Coordination in Tris(silylamide) Complexes.
Authors of publication	Hervé, Alexandre; Bouzidi, Yamina; Berthet, Jean-Claude; Belkhiri, Lotfi; Thuéry, Pierre; Boucekkine, Abdou; Ephritikhine, Michel
Journal of publication	Inorganic chemistry
Year of publication	2015
Journal volume	54
Journal issue	5
Pages of publication	2474
a	11.2771 ± 0.0006 Å
b	11.4316 ± 0.0005 Å
c	11.6871 ± 0.0007 Å
α	80.495 ± 0.003°
β	88.841 ± 0.002°
γ	62.631 ± 0.003°
Cell volume	1316.96 ± 0.13 Å³
Cell temperature	150 ± 2 K
Ambient diffraction temperature	150 ± 2 K
Number of distinct elements	8
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0418
Residual factor for significantly intense reflections	0.0311
Weighted residual factors for significantly intense reflections	0.0642
Weighted residual factors for all reflections included in the refinement	0.0666
Goodness-of-fit parameter for all reflections included in the refinement	0.984
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
179529 (current)	2016-03-24	cif/4/34/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/34/26.	4342610.cif
132694	2015-03-04	cif/ Adding structures of 4342606, 4342607, 4342608, 4342609, 4342610, 4342611, 4342612, 4342613, 4342614 via cif-deposit CGI script.	4342610.cif