Crystallography Open Database

Information card for entry 4346105

Preview

Coordinates	4346105.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C22 H49 P2 Rh S3 Si
Calculated formula	C22 H49 P2 Rh S3 Si
SMILES	[Rh]12([S]=C(S1)S[Si](C)(C)C)[P](CC[P]2(C(C)(C)C)C(C)(C)C)(C(C)(C)C)C(C)(C)C
Title of publication	Chalcogen extrusion from heteroallenes and carbon monoxide by a three-coordinate rh(i) disilylamide.
Authors of publication	Whited, Matthew T.; Qiu, Lisa; Kosanovich, Alex J.; Janzen, Daron E.
Journal of publication	Inorganic chemistry
Year of publication	2015
Journal volume	54
Journal issue	7
Pages of publication	3670 - 3679
a	10.881 ± 0.002 Å
b	14.908 ± 0.003 Å
c	18.667 ± 0.004 Å
α	90°
β	100.277 ± 0.007°
γ	90°
Cell volume	2979.5 ± 1 Å³
Cell temperature	173 ± 2 K
Ambient diffraction temperature	173.15 K
Number of distinct elements	6
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/c 1
Hall space group symbol	-P 2ybc
Residual factor for all reflections	0.1085
Residual factor for significantly intense reflections	0.0621
Weighted residual factors for significantly intense reflections	0.115
Weighted residual factors for all reflections included in the refinement	0.1294
Goodness-of-fit parameter for all reflections included in the refinement	1.015
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
231619 (current)	2019-11-23	cif/ Adding structures of 4346105, 4346106, 4346107, 4346108 via cif-deposit CGI script.	4346105.cif