Crystallography Open Database

Information card for entry 4346107

Preview

Coordinates	4346107.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C26 H58 N O2 P2 Rh S2 Si2
Calculated formula	C26 H58 N O2 P2 Rh S2 Si2
SMILES	[Rh]12(SC(=NC(=[S]2)O[Si](C)(C)C)O[Si](C)(C)C)[P](C(C)(C)C)(C(C)(C)C)CC[P]1(C(C)(C)C)C(C)(C)C
Title of publication	Chalcogen extrusion from heteroallenes and carbon monoxide by a three-coordinate rh(i) disilylamide.
Authors of publication	Whited, Matthew T.; Qiu, Lisa; Kosanovich, Alex J.; Janzen, Daron E.
Journal of publication	Inorganic chemistry
Year of publication	2015
Journal volume	54
Journal issue	7
Pages of publication	3670 - 3679
a	12.893 ± 0.003 Å
b	21.409 ± 0.005 Å
c	27.026 ± 0.006 Å
α	90°
β	90°
γ	90°
Cell volume	7460 ± 3 Å³
Cell temperature	173 K
Ambient diffraction temperature	173.15 K
Number of distinct elements	8
Space group number	61
Hermann-Mauguin space group symbol	P b c a
Hall space group symbol	-P 2ac 2ab
Residual factor for all reflections	0.1568
Residual factor for significantly intense reflections	0.1042
Weighted residual factors for significantly intense reflections	0.222
Weighted residual factors for all reflections included in the refinement	0.242
Goodness-of-fit parameter for all reflections included in the refinement	1.133
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
231619 (current)	2019-11-23	cif/ Adding structures of 4346105, 4346106, 4346107, 4346108 via cif-deposit CGI script.	4346107.cif