Crystallography Open Database

Information card for entry 4346553

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Coordinates	4346553.cif
Original paper (by DOI)	HTML

Structure parameters

Common name	[NMe4][TMS-S], 6
Chemical name	Tetramethylammonium-trimethylsilylthiolate aceonitrile solvate
Formula	C9 H24 N2 S Si
Calculated formula	C9 H24 N2 S Si
Title of publication	Synthesis of organic (trimethylsilyl)chalcogenolate salts Cat[TMS-E] (E = S, Se, Te): the methylcarbonate anion as a desilylating agent.
Authors of publication	Finger, Lars H.; Scheibe, Benjamin; Sundermeyer, Jörg
Journal of publication	Inorganic chemistry
Year of publication	2015
Journal volume	54
Journal issue	19
Pages of publication	9568 - 9575
a	7.6236 ± 0.0011 Å
b	7.6281 ± 0.0011 Å
c	13.2227 ± 0.0018 Å
α	90°
β	104.094 ± 0.004°
γ	90°
Cell volume	745.8 ± 0.18 Å³
Cell temperature	110 ± 2 K
Ambient diffraction temperature	110 ± 2 K
Number of distinct elements	5
Space group number	11
Hermann-Mauguin space group symbol	P 1 21/m 1
Hall space group symbol	-P 2yb
Residual factor for all reflections	0.1308
Residual factor for significantly intense reflections	0.0784
Weighted residual factors for significantly intense reflections	0.1331
Weighted residual factors for all reflections included in the refinement	0.1505
Goodness-of-fit parameter for all reflections included in the refinement	1.1
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
231834 (current)	2019-11-23	cif/ Adding structures of 4346552, 4346553, 4346554, 4346555, 4346556 via cif-deposit CGI script.	4346553.cif