#------------------------------------------------------------------------------
#$Date: 2019-11-23 09:04:18 +0200 (Sat, 23 Nov 2019) $
#$Revision: 232638 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/34/80/4348013.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4348013
loop_
_publ_author_name
'Ojeda-Amador, Ana I'
'Martínez-Martínez, Antonio J'
'Kennedy, Alan R.'
'O'Hara, Charles T'
_publ_section_title
;
 Structural Studies of Cesium, Lithium/Cesium, and Sodium/Cesium
 Bis(trimethylsilyl)amide (HMDS) Complexes.
;
_journal_issue                   11
_journal_name_full               'Inorganic chemistry'
_journal_page_first              5719
_journal_page_last               5728
_journal_paper_doi               10.1021/acs.inorgchem.6b00839
_journal_volume                  55
_journal_year                    2016
_chemical_formula_moiety         'C27.50 H70 Cs2 N6 Si4'
_chemical_formula_sum            'C27.5 H70 Cs2 N6 Si4'
_chemical_formula_weight         863.07
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2013
_cell_angle_alpha                106.321(4)
_cell_angle_beta                 98.475(4)
_cell_angle_gamma                95.449(4)
_cell_formula_units_Z            2
_cell_length_a                   11.0696(5)
_cell_length_b                   13.2566(7)
_cell_length_c                   16.0829(7)
_cell_measurement_reflns_used    33616
_cell_measurement_temperature    123(2)
_cell_measurement_theta_max      30.2233
_cell_measurement_theta_min      2.9775
_cell_volume                     2217.01(19)
_computing_cell_refinement
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.34.40 (release 27-08-2010 CrysAlis171 .NET)
(compiled Aug 27 2010,11:50:40)
;
_computing_data_collection
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.34.40 (release 27-08-2010 CrysAlis171 .NET)
(compiled Aug 27 2010,11:50:40)
;
_computing_data_reduction
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.34.40 (release 27-08-2010 CrysAlis171 .NET)
(compiled Aug 27 2010,11:50:40)
;
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_diffrn_ambient_temperature      123(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.950
_diffrn_measurement_device_type  'Xcalibur, Eos'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0336
_diffrn_reflns_av_unetI/netI     0.0216
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.950
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            90832
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.950
_diffrn_reflns_theta_full        27.000
_diffrn_reflns_theta_max         30.291
_diffrn_reflns_theta_min         2.984
_exptl_absorpt_coefficient_mu    1.775
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.73905
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.34.40 (release 27-08-2010 CrysAlis171 .NET)
(compiled Aug 27 2010,11:50:40)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.293
_exptl_crystal_description       plate
_exptl_crystal_F_000             886
_exptl_crystal_size_max          0.44
_exptl_crystal_size_mid          0.38
_exptl_crystal_size_min          0.18
_refine_diff_density_max         1.504
_refine_diff_density_min         -0.731
_refine_diff_density_rms         0.085
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.102
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     395
_refine_ls_number_reflns         12614
_refine_ls_number_restraints     60
_refine_ls_restrained_S_all      1.108
_refine_ls_R_factor_all          0.0407
_refine_ls_R_factor_gt           0.0286
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0243P)²+2.6577P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0638
_refine_ls_wR_factor_ref         0.0725
_reflns_Friedel_coverage         0.000
_reflns_number_gt                10429
_reflns_number_total             12614
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ic6b00839_si_002.cif
_cod_data_source_block           amao_TREN
_cod_original_formula_sum        'C27.50 H70 Cs2 N6 Si4'
_cod_database_code               4348013
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelxl_version_number           2013-4
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Cs1 Cs 0.30157(2) 0.28304(2) 0.26942(2) 0.03048(4) Uani 1 1 d . . . . .
Cs2 Cs 0.33098(2) 0.49757(2) 0.05405(2) 0.02790(4) Uani 1 1 d . . . . .
Si1 Si 0.04338(7) 0.38634(6) 0.14087(6) 0.03713(16) Uani 1 1 d . . . . .
N1 N 0.17752(19) 0.45357(16) 0.20010(14) 0.0304(4) Uani 1 1 d . . . . .
C1 C -0.0465(4) 0.3092(4) 0.1989(3) 0.0763(13) Uani 1 1 d . . . . .
H1A H -0.1194 0.2658 0.1577 0.114 Uiso 1 1 calc R U . . .
H1B H -0.0727 0.3585 0.2486 0.114 Uiso 1 1 calc R U . . .
H1C H 0.0056 0.2629 0.2208 0.114 Uiso 1 1 calc R U . . .
Si2 Si 0.20133(8) 0.56838(6) 0.28038(5) 0.03745(17) Uani 1 1 d . . . . .
N2 N 0.5558(2) 0.67489(16) 0.08041(13) 0.0292(4) Uani 1 1 d . . . . .
C2 C -0.0675(3) 0.4680(4) 0.0997(3) 0.0760(13) Uani 1 1 d . . . . .
H2A H -0.0243 0.5148 0.0726 0.114 Uiso 1 1 calc R U . . .
H2B H -0.1004 0.5110 0.1492 0.114 Uiso 1 1 calc R U . . .
H2C H -0.1355 0.4209 0.0560 0.114 Uiso 1 1 calc R U . . .
Si3 Si 0.51918(7) 0.76680(5) 0.03265(4) 0.02988(14) Uani 1 1 d . . . . .
N3 N 0.3749(2) 0.11106(18) 0.37454(16) 0.0409(5) Uani 1 1 d . . . . .
C3 C 0.0629(3) 0.2836(3) 0.0379(2) 0.0595(9) Uani 1 1 d . . . . .
H3A H -0.0168 0.2399 0.0091 0.089 Uiso 1 1 calc R U . . .
H3B H 0.1221 0.2383 0.0532 0.089 Uiso 1 1 calc R U . . .
H3C H 0.0936 0.3190 -0.0024 0.089 Uiso 1 1 calc R U . . .
Si4 Si 0.63801(7) 0.68969(6) 0.17965(4) 0.03021(14) Uani 1 1 d . . . . .
N4 N 0.2143(2) 0.28141(19) 0.44745(15) 0.0423(6) Uani 1 1 d . . . . .
C4 C 0.0843(4) 0.5883(3) 0.3563(3) 0.0748(13) Uani 1 1 d . . . . .
H4A H 0.0033 0.5892 0.3225 0.112 Uiso 1 1 calc R U . . .
H4B H 0.1099 0.6559 0.4031 0.112 Uiso 1 1 calc R U . . .
H4C H 0.0790 0.5300 0.3826 0.112 Uiso 1 1 calc R U . . .
N5 N 0.5844(2) 0.24927(18) 0.32037(16) 0.0399(5) Uani 1 1 d . . . . .
C5 C 0.3545(3) 0.5847(3) 0.3560(2) 0.0540(8) Uani 1 1 d . . . . .
H5A H 0.4190 0.5678 0.3207 0.081 Uiso 1 1 calc R U . . .
H5B H 0.3489 0.5366 0.3922 0.081 Uiso 1 1 calc R U . . .
H5C H 0.3749 0.6582 0.3943 0.081 Uiso 1 1 calc R U . . .
N6 N 0.1899(3) 0.03894(19) 0.19333(17) 0.0514(7) Uani 1 1 d . . . . .
C6 C 0.2056(4) 0.6892(2) 0.2401(2) 0.0544(8) Uani 1 1 d . . . . .
H6A H 0.2726 0.6905 0.2067 0.082 Uiso 1 1 calc R U . . .
H6B H 0.2195 0.7535 0.2907 0.082 Uiso 1 1 calc R U . . .
H6C H 0.1267 0.6864 0.2021 0.082 Uiso 1 1 calc R U . . .
C7 C 0.3471(3) 0.7653(3) 0.0041(2) 0.0519(8) Uani 1 1 d . . . . .
H7A H 0.3311 0.8239 -0.0201 0.078 Uiso 1 1 calc R U . . .
H7B H 0.3110 0.7737 0.0573 0.078 Uiso 1 1 calc R U . . .
H7C H 0.3099 0.6977 -0.0398 0.078 Uiso 1 1 calc R U . . .
C8 C 0.5842(4) 0.9080(2) 0.0954(2) 0.0636(10) Uani 1 1 d . . . . .
H8A H 0.6744 0.9166 0.1028 0.095 Uiso 1 1 calc R U . . .
H8B H 0.5599 0.9262 0.1534 0.095 Uiso 1 1 calc R U . . .
H8C H 0.5523 0.9551 0.0628 0.095 Uiso 1 1 calc R U . . .
C9 C 0.5684(3) 0.7451(2) -0.07757(19) 0.0415(6) Uani 1 1 d . . . . .
H9A H 0.5261 0.6767 -0.1179 0.062 Uiso 1 1 calc R U . . .
H9B H 0.6579 0.7448 -0.0702 0.062 Uiso 1 1 calc R U . . .
H9C H 0.5470 0.8024 -0.1019 0.062 Uiso 1 1 calc R U . . .
C10 C 0.6345(3) 0.5582(2) 0.20370(19) 0.0430(6) Uani 1 1 d . . . . .
H10A H 0.5517 0.5355 0.2125 0.064 Uiso 1 1 calc R U . . .
H10B H 0.6946 0.5659 0.2571 0.064 Uiso 1 1 calc R U . . .
H10C H 0.6555 0.5049 0.1540 0.064 Uiso 1 1 calc R U . . .
C11 C 0.5831(3) 0.7811(3) 0.27521(19) 0.0510(8) Uani 1 1 d . . . . .
H11A H 0.5944 0.8539 0.2717 0.076 Uiso 1 1 calc R U . . .
H11B H 0.6310 0.7785 0.3307 0.076 Uiso 1 1 calc R U . . .
H11C H 0.4955 0.7582 0.2728 0.076 Uiso 1 1 calc R U . . .
C12 C 0.8068(3) 0.7398(3) 0.1936(2) 0.0497(7) Uani 1 1 d . . . . .
H12A H 0.8432 0.6917 0.1490 0.075 Uiso 1 1 calc R U . . .
H12B H 0.8488 0.7426 0.2525 0.075 Uiso 1 1 calc R U . . .
H12C H 0.8164 0.8111 0.1867 0.075 Uiso 1 1 calc R U . . .
C13 C 0.3497(3) 0.1463(3) 0.4653(2) 0.0503(8) Uani 1 1 d . . . . .
H13A H 0.4157 0.2042 0.5016 0.060 Uiso 1 1 calc R U . . .
H13B H 0.3533 0.0863 0.4905 0.060 Uiso 1 1 calc R U . . .
C14 C 0.2283(3) 0.1844(2) 0.4718(2) 0.0485(7) Uani 1 1 d . . . . .
H00A H 0.1627 0.1274 0.4336 0.058 Uiso 1 1 calc R U . . .
H00B H 0.2150 0.1969 0.5333 0.058 Uiso 1 1 calc R U . . .
C15 C 0.2837(5) 0.3740(3) 0.5128(3) 0.0764(13) Uani 1 1 d . . . . .
H15A H 0.3720 0.3684 0.5179 0.115 Uiso 1 1 calc R U . . .
H15B H 0.2588 0.3796 0.5698 0.115 Uiso 1 1 calc R U . . .
H15C H 0.2678 0.4374 0.4955 0.115 Uiso 1 1 calc R U . . .
C16 C 0.0836(4) 0.2931(3) 0.4340(3) 0.0664(10) Uani 1 1 d . . . . .
H16A H 0.0732 0.3573 0.4164 0.100 Uiso 1 1 calc R U . . .
H16B H 0.0526 0.2991 0.4890 0.100 Uiso 1 1 calc R U . . .
H16C H 0.0372 0.2309 0.3877 0.100 Uiso 1 1 calc R U . . .
C17 C 0.5082(3) 0.1056(2) 0.3788(2) 0.0485(7) Uani 1 1 d . . . . .
H17A H 0.5207 0.0580 0.3221 0.058 Uiso 1 1 calc R U . . .
H17B H 0.5367 0.0735 0.4255 0.058 Uiso 1 1 calc R U . . .
C18 C 0.5877(3) 0.2120(3) 0.3974(2) 0.0499(7) Uani 1 1 d . . . . .
H18A H 0.5594 0.2654 0.4443 0.060 Uiso 1 1 calc R U . . .
H18B H 0.6741 0.2057 0.4196 0.060 Uiso 1 1 calc R U . . .
C19 C 0.6366(4) 0.3623(3) 0.3495(3) 0.0701(11) Uani 1 1 d . . . . .
H19A H 0.7208 0.3714 0.3824 0.105 Uiso 1 1 calc R U . . .
H19B H 0.5856 0.4031 0.3876 0.105 Uiso 1 1 calc R U . . .
H19C H 0.6383 0.3877 0.2980 0.105 Uiso 1 1 calc R U . . .
C20 C 0.6579(3) 0.1935(3) 0.2600(2) 0.0568(8) Uani 1 1 d . . . . .
H20A H 0.6227 0.1183 0.2367 0.085 Uiso 1 1 calc R U . . .
H20B H 0.7427 0.2003 0.2912 0.085 Uiso 1 1 calc R U . . .
H20C H 0.6581 0.2243 0.2113 0.085 Uiso 1 1 calc R U . . .
C21 C 0.3062(3) 0.0059(2) 0.3265(2) 0.0481(7) Uani 1 1 d . . . . .
H21A H 0.2256 0.0000 0.3458 0.058 Uiso 1 1 calc R U . . .
H21B H 0.3523 -0.0483 0.3428 0.058 Uiso 1 1 calc R U . . .
C22 C 0.2836(3) -0.0188(2) 0.2286(2) 0.0517(8) Uani 1 1 d . . . . .
H22A H 0.3624 -0.0012 0.2101 0.062 Uiso 1 1 calc R U . . .
H22B H 0.2565 -0.0961 0.2020 0.062 Uiso 1 1 calc R U . . .
C23 C 0.0686(4) 0.0054(4) 0.2045(3) 0.0850(14) Uani 1 1 d . . . . .
H23A H 0.0090 0.0396 0.1745 0.128 Uiso 1 1 calc R U . . .
H23B H 0.0648 0.0255 0.2675 0.128 Uiso 1 1 calc R U . . .
H23C H 0.0486 -0.0719 0.1794 0.128 Uiso 1 1 calc R U . . .
C24 C 0.1910(4) 0.0196(3) 0.0997(2) 0.0610(9) Uani 1 1 d . . . . .
H24A H 0.1659 -0.0563 0.0688 0.091 Uiso 1 1 calc R U . . .
H24B H 0.2744 0.0413 0.0915 0.091 Uiso 1 1 calc R U . . .
H24C H 0.1334 0.0606 0.0758 0.091 Uiso 1 1 calc R U . . .
C31 C -0.1523(9) 0.0058(9) 0.3688(6) 0.117(3) Uani 0.5 1 d D U P A -1
H31A H -0.1127 0.0484 0.3368 0.176 Uiso 0.5 1 calc R U P A -1
H31B H -0.2194 0.0405 0.3928 0.176 Uiso 0.5 1 calc R U P A -1
H31C H -0.1859 -0.0650 0.3286 0.176 Uiso 0.5 1 calc R U P A -1
C25 C -0.0620(5) -0.0037(7) 0.4405(4) 0.087(2) Uani 0.5 1 d DG U P A -1
C26 C 0.0221(6) -0.0754(6) 0.4268(4) 0.077(2) Uani 0.5 1 d DG U P A -1
H26 H 0.0186 -0.1231 0.3697 0.092 Uiso 0.5 1 calc R U P A -1
C27 C 0.1114(5) -0.0774(6) 0.4965(5) 0.084(2) Uani 0.5 1 d G U P A -1
H27 H 0.1689 -0.1265 0.4872 0.100 Uiso 0.5 1 calc R U P A -1
C28 C 0.1166(6) -0.0076(7) 0.5801(4) 0.091(2) Uani 0.5 1 d G U P A -1
H28 H 0.1777 -0.0090 0.6277 0.109 Uiso 0.5 1 calc R U P A -1
C29 C 0.0325(7) 0.0641(7) 0.5938(4) 0.093(2) Uani 0.5 1 d G U P A -1
H29 H 0.0360 0.1119 0.6509 0.112 Uiso 0.5 1 calc R U P A -1
C30 C -0.0568(6) 0.0661(6) 0.5240(5) 0.095(2) Uani 0.5 1 d DG U P A -1
H30 H -0.1143 0.1152 0.5334 0.114 Uiso 0.5 1 calc R U P A -1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cs Cs -0.3680 2.1192 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Cs1 N4 108.36(6) . .
N1 Cs1 N6 120.89(7) . .
N4 Cs1 N6 87.69(7) . .
N1 Cs1 N5 133.44(6) . .
N4 Cs1 N5 98.72(7) . .
N6 Cs1 N5 96.80(7) . .
N1 Cs1 N3 164.80(6) . .
N4 Cs1 N3 57.13(6) . .
N6 Cs1 N3 58.25(7) . .
N5 Cs1 N3 58.64(6) . .
N1 Cs1 C9 81.06(6) . 2_665
N4 Cs1 C9 170.53(7) . 2_665
N6 Cs1 C9 88.14(7) . 2_665
N5 Cs1 C9 73.36(7) . 2_665
N3 Cs1 C9 113.55(6) . 2_665
N1 Cs1 C24 107.29(7) . .
N4 Cs1 C24 109.57(7) . .
N6 Cs1 C24 22.45(7) . .
N5 Cs1 C24 97.87(8) . .
N3 Cs1 C24 76.36(7) . .
C9 Cs1 C24 67.30(8) 2_665 .
N1 Cs1 C15 102.21(8) . .
N4 Cs1 C15 21.37(7) . .
N6 Cs1 C15 107.96(8) . .
N5 Cs1 C15 89.46(9) . .
N3 Cs1 C15 65.99(8) . .
C9 Cs1 C15 157.95(9) 2_665 .
C24 Cs1 C15 130.27(8) . .
N1 Cs1 C5 48.88(6) . .
N4 Cs1 C5 87.88(7) . .
N6 Cs1 C5 166.25(8) . .
N5 Cs1 C5 96.74(7) . .
N3 Cs1 C5 128.50(6) . .
C9 Cs1 C5 98.06(7) 2_665 .
C24 Cs1 C5 155.13(7) . .
C15 Cs1 C5 69.76(8) . .
N1 Cs1 C16 91.44(7) . .
N4 Cs1 C16 21.61(8) . .
N6 Cs1 C16 84.87(8) . .
N5 Cs1 C16 120.32(8) . .
N3 Cs1 C16 73.38(8) . .
C9 Cs1 C16 165.27(8) 2_665 .
C24 Cs1 C16 103.42(9) . .
C15 Cs1 C16 36.26(10) . .
C5 Cs1 C16 86.22(8) . .
N1 Cs1 C22 142.23(7) . .
N4 Cs1 C22 84.16(7) . .
N6 Cs1 C22 21.81(8) . .
N5 Cs1 C22 76.11(7) . .
N3 Cs1 C22 39.84(7) . .
C9 Cs1 C22 88.82(7) 2_665 .
C24 Cs1 C22 36.54(8) . .
C15 Cs1 C22 100.60(8) . .
C5 Cs1 C22 168.32(7) . .
C16 Cs1 C22 89.46(8) . .
N1 Cs1 C18 148.00(6) . .
N4 Cs1 C18 78.18(7) . .
N6 Cs1 C18 90.14(8) . .
N5 Cs1 C18 21.36(6) . .
N3 Cs1 C18 40.29(7) . .
C9 Cs1 C18 93.35(7) 2_665 .
C24 Cs1 C18 99.25(8) . .
C15 Cs1 C18 72.19(9) . .
C5 Cs1 C18 101.67(7) . .
C16 Cs1 C18 99.61(8) . .
C22 Cs1 C18 68.35(8) . .
N2 Cs2 N2 92.85(5) . 2_665
N2 Cs2 N1 128.29(5) . .
N2 Cs2 N1 125.72(5) 2_665 .
N2 Cs2 C9 111.70(6) . 2_665
N2 Cs2 C9 51.33(6) 2_665 2_665
N1 Cs2 C9 78.58(6) . 2_665
N2 Cs2 C2 110.28(8) . 2_565
N2 Cs2 C2 98.97(9) 2_665 2_565
N1 Cs2 C2 97.33(8) . 2_565
C9 Cs2 C2 128.72(9) 2_665 2_565
N2 Cs2 C3 176.30(7) . .
N2 Cs2 C3 88.90(7) 2_665 .
N1 Cs2 C3 48.33(7) . .
C9 Cs2 C3 67.01(8) 2_665 .
C2 Cs2 C3 72.62(9) 2_565 .
N2 Cs2 C7 48.93(6) . .
N2 Cs2 C7 112.64(6) 2_665 .
N1 Cs2 C7 120.97(6) . .
C9 Cs2 C7 157.77(7) 2_665 .
C2 Cs2 C7 63.41(8) 2_565 .
C3 Cs2 C7 133.07(8) . .
N2 Cs2 C6 89.04(6) . .
N2 Cs2 C6 172.60(6) 2_665 .
N1 Cs2 C6 48.64(6) . .
C9 Cs2 C6 121.39(7) 2_665 .
C2 Cs2 C6 87.05(10) 2_565 .
C3 Cs2 C6 88.82(8) . .
C7 Cs2 C6 73.87(7) . .
N2 Cs2 Si4 23.97(4) . .
N2 Cs2 Si4 98.94(4) 2_665 .
N1 Cs2 Si4 107.93(4) . .
C9 Cs2 Si4 97.45(5) 2_665 .
C2 Cs2 Si4 131.16(7) 2_565 .
C3 Cs2 Si4 152.40(6) . .
C7 Cs2 Si4 67.76(5) . .
C6 Cs2 Si4 80.02(6) . .
N2 Cs2 Si4 98.89(4) . 2_665
N2 Cs2 Si4 23.85(4) 2_665 2_665
N1 Cs2 Si4 130.75(4) . 2_665
C9 Cs2 Si4 70.45(5) 2_665 2_665
C2 Cs2 Si4 75.23(8) 2_565 2_665
C3 Cs2 Si4 84.00(6) . 2_665
C7 Cs2 Si4 99.35(6) . 2_665
C6 Cs2 Si4 162.16(6) . 2_665
Si4 Cs2 Si4 113.170(12) . 2_665
N2 Cs2 Si1 149.50(4) . .
N2 Cs2 Si1 115.49(4) 2_665 .
N1 Cs2 Si1 23.92(4) . .
C9 Cs2 Si1 80.86(5) 2_665 .
C2 Cs2 Si1 77.69(7) 2_565 .
C3 Cs2 Si1 27.79(6) . .
C7 Cs2 Si1 121.35(5) . .
C6 Cs2 Si1 61.43(5) . .
Si4 Cs2 Si1 131.607(16) . .
Si4 Cs2 Si1 111.580(17) 2_665 .
N2 Cs2 Si3 101.43(4) . 2_665
N2 Cs2 Si3 23.32(4) 2_665 2_665
N1 Cs2 Si3 105.02(4) . 2_665
C9 Cs2 Si3 28.07(4) 2_665 2_665
C2 Cs2 Si3 115.20(8) 2_565 2_665
C3 Cs2 Si3 78.99(6) . 2_665
C7 Cs2 Si3 133.98(5) . 2_665
C6 Cs2 Si3 149.34(5) . 2_665
Si4 Cs2 Si3 97.951(16) . 2_665
Si4 Cs2 Si3 44.407(15) 2_665 2_665
Si1 Cs2 Si3 101.169(16) . 2_665
N1 Si1 C1 114.54(15) . .
N1 Si1 C2 115.47(16) . .
C1 Si1 C2 105.2(2) . .
N1 Si1 C3 112.29(13) . .
C1 Si1 C3 104.2(2) . .
C2 Si1 C3 104.0(2) . .
N1 Si1 Cs1 52.13(7) . .
C1 Si1 Cs1 78.07(13) . .
C2 Si1 Cs1 166.03(15) . .
C3 Si1 Cs1 88.10(12) . .
N1 Si1 Cs2 52.26(7) . .
C1 Si1 Cs2 158.73(14) . .
C2 Si1 Cs2 96.02(14) . .
C3 Si1 Cs2 71.72(11) . .
Cs1 Si1 Cs2 80.899(14) . .
Si1 N1 Si2 127.66(13) . .
Si1 N1 Cs1 103.09(9) . .
Si2 N1 Cs1 109.54(10) . .
Si1 N1 Cs2 103.82(9) . .
Si2 N1 Cs2 105.00(9) . .
Cs1 N1 Cs2 106.00(6) . .
Si1 C1 H1A 109.5 . .
Si1 C1 H1B 109.5 . .
H1A C1 H1B 109.5 . .
Si1 C1 H1C 109.5 . .
H1A C1 H1C 109.5 . .
H1B C1 H1C 109.5 . .
N1 Si2 C6 114.03(14) . .
N1 Si2 C5 110.98(13) . .
C6 Si2 C5 105.84(16) . .
N1 Si2 C4 116.31(15) . .
C6 Si2 C4 104.00(17) . .
C5 Si2 C4 104.69(19) . .
N1 Si2 Cs1 47.40(8) . .
C6 Si2 Cs1 149.95(11) . .
C5 Si2 Cs1 70.06(10) . .
C4 Si2 Cs1 105.80(12) . .
N1 Si2 Cs2 51.35(7) . .
C6 Si2 Cs2 72.03(10) . .
C5 Si2 Cs2 96.68(11) . .
C4 Si2 Cs2 158.47(17) . .
Cs1 Si2 Cs2 78.811(14) . .
Si3 N2 Si4 129.40(13) . .
Si3 N2 Cs2 112.46(10) . .
Si4 N2 Cs2 105.86(9) . .
Si3 N2 Cs2 107.74(9) . 2_665
Si4 N2 Cs2 105.89(9) . 2_665
Cs2 N2 Cs2 87.15(5) . 2_665
Si1 C2 Cs2 152.9(2) . 2_565
Si1 C2 H2A 109.5 . .
Cs2 C2 H2A 80.5 2_565 .
Si1 C2 H2B 109.5 . .
Cs2 C2 H2B 89.5 2_565 .
H2A C2 H2B 109.5 . .
Si1 C2 H2C 109.5 . .
Cs2 C2 H2C 44.2 2_565 .
H2A C2 H2C 109.5 . .
H2B C2 H2C 109.5 . .
N2 Si3 C8 116.77(14) . .
N2 Si3 C9 112.83(12) . .
C8 Si3 C9 104.62(16) . .
N2 Si3 C7 113.06(13) . .
C8 Si3 C7 105.60(18) . .
C9 Si3 C7 102.61(15) . .
N2 Si3 Cs2 48.94(7) . 2_665
C8 Si3 Cs2 133.92(14) . 2_665
C9 Si3 Cs2 64.05(9) . 2_665
C7 Si3 Cs2 120.35(11) . 2_665
N2 Si3 Cs2 45.43(8) . .
C8 Si3 Cs2 143.06(13) . .
C9 Si3 Cs2 112.23(10) . .
C7 Si3 Cs2 69.31(11) . .
Cs2 Si3 Cs2 65.150(11) 2_665 .
C21 N3 C17 108.9(2) . .
C21 N3 C13 110.7(2) . .
C17 N3 C13 108.9(3) . .
C21 N3 Cs1 110.03(18) . .
C17 N3 Cs1 108.06(15) . .
C13 N3 Cs1 110.31(17) . .
Si1 C3 Cs2 80.49(10) . .
Si1 C3 H3A 109.5 . .
Cs2 C3 H3A 152.6 . .
Si1 C3 H3B 109.5 . .
Cs2 C3 H3B 89.8 . .
H3A C3 H3B 109.5 . .
Si1 C3 H3C 109.5 . .
Cs2 C3 H3C 44.0 . .
H3A C3 H3C 109.5 . .
H3B C3 H3C 109.5 . .
N2 Si4 C12 114.86(13) . .
N2 Si4 C10 110.66(12) . .
C12 Si4 C10 104.66(15) . .
N2 Si4 C11 115.47(13) . .
C12 Si4 C11 105.14(16) . .
C10 Si4 C11 105.05(15) . .
N2 Si4 Cs2 50.17(7) . .
C12 Si4 Cs2 153.19(11) . .
C10 Si4 Cs2 68.83(9) . .
C11 Si4 Cs2 101.65(11) . .
N2 Si4 Cs2 50.26(7) . 2_665
C12 Si4 Cs2 86.56(11) . 2_665
C10 Si4 Cs2 80.02(9) . 2_665
C11 Si4 Cs2 165.23(11) . 2_665
Cs2 Si4 Cs2 66.829(12) . 2_665
C15 N4 C16 109.9(3) . .
C15 N4 C14 112.3(3) . .
C16 N4 C14 109.0(3) . .
C15 N4 Cs1 105.3(2) . .
C16 N4 Cs1 105.61(19) . .
C14 N4 Cs1 114.45(16) . .
Si2 C4 H4A 109.5 . .
Si2 C4 H4B 109.5 . .
H4A C4 H4B 109.5 . .
Si2 C4 H4C 109.5 . .
H4A C4 H4C 109.5 . .
H4B C4 H4C 109.5 . .
C20 N5 C18 112.0(3) . .
C20 N5 C19 107.4(3) . .
C18 N5 C19 108.6(3) . .
C20 N5 Cs1 125.9(2) . .
C18 N5 Cs1 104.76(18) . .
C19 N5 Cs1 96.4(2) . .
Si2 C5 Cs1 82.07(10) . .
Si2 C5 H5A 109.5 . .
Cs1 C5 H5A 76.0 . .
Si2 C5 H5B 109.5 . .
Cs1 C5 H5B 54.6 . .
H5A C5 H5B 109.5 . .
Si2 C5 H5C 109.5 . .
Cs1 C5 H5C 163.6 . .
H5A C5 H5C 109.5 . .
H5B C5 H5C 109.5 . .
C23 N6 C24 109.1(3) . .
C23 N6 C22 112.5(3) . .
C24 N6 C22 108.1(3) . .
C23 N6 Cs1 119.3(2) . .
C24 N6 Cs1 101.27(18) . .
C22 N6 Cs1 105.66(18) . .
Si2 C6 Cs2 80.31(10) . .
Si2 C6 H6A 109.5 . .
Cs2 C6 H6A 41.5 . .
Si2 C6 H6B 109.5 . .
Cs2 C6 H6B 149.3 . .
H6A C6 H6B 109.5 . .
Si2 C6 H6C 109.5 . .
Cs2 C6 H6C 93.3 . .
H6A C6 H6C 109.5 . .
H6B C6 H6C 109.5 . .
Si3 C7 Cs2 83.33(11) . .
Si3 C7 H7A 109.5 . .
Cs2 C7 H7A 164.6 . .
Si3 C7 H7B 109.5 . .
Cs2 C7 H7B 72.5 . .
H7A C7 H7B 109.5 . .
Si3 C7 H7C 109.5 . .
Cs2 C7 H7C 56.8 . .
H7A C7 H7C 109.5 . .
H7B C7 H7C 109.5 . .
Si3 C8 H8A 109.5 . .
Si3 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
Si3 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
Si3 C9 Cs1 172.87(15) . 2_665
Si3 C9 Cs2 87.88(9) . 2_665
Cs1 C9 Cs2 90.95(7) 2_665 2_665
Si3 C9 H9A 109.5 . .
Cs1 C9 H9A 75.9 2_665 .
Cs2 C9 H9A 60.4 2_665 .
Si3 C9 H9B 109.5 . .
Cs1 C9 H9B 63.8 2_665 .
Cs2 C9 H9B 65.0 2_665 .
H9A C9 H9B 109.5 . .
Si3 C9 H9C 109.5 . .
Cs1 C9 H9C 72.1 2_665 .
Cs2 C9 H9C 162.5 2_665 .
H9A C9 H9C 109.5 . .
H9B C9 H9C 109.5 . .
Si4 C10 H10A 109.5 . .
Si4 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
Si4 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
Si4 C11 H11A 109.5 . .
Si4 C11 H11B 109.5 . .
H11A C11 H11B 109.5 . .
Si4 C11 H11C 109.5 . .
H11A C11 H11C 109.5 . .
H11B C11 H11C 109.5 . .
Si4 C12 H12A 109.5 . .
Si4 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
Si4 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
N3 C13 C14 114.4(3) . .
N3 C13 H13A 108.7 . .
C14 C13 H13A 108.7 . .
N3 C13 H13B 108.7 . .
C14 C13 H13B 108.7 . .
H13A C13 H13B 107.6 . .
N4 C14 C13 115.4(3) . .
N4 C14 H00A 108.4 . .
C13 C14 H00A 108.4 . .
N4 C14 H00B 108.4 . .
C13 C14 H00B 108.4 . .
H00A C14 H00B 107.5 . .
N4 C15 Cs1 53.30(17) . .
N4 C15 H15A 109.5 . .
Cs1 C15 H15A 81.0 . .
N4 C15 H15B 109.5 . .
Cs1 C15 H15B 162.7 . .
H15A C15 H15B 109.5 . .
N4 C15 H15C 109.5 . .
Cs1 C15 H15C 78.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
N4 C16 Cs1 52.78(15) . .
N4 C16 H16A 109.5 . .
Cs1 C16 H16A 77.0 . .
N4 C16 H16B 109.5 . .
Cs1 C16 H16B 161.8 . .
H16A C16 H16B 109.5 . .
N4 C16 H16C 109.5 . .
Cs1 C16 H16C 83.1 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
N3 C17 C18 114.6(3) . .
N3 C17 H17A 108.6 . .
C18 C17 H17A 108.6 . .
N3 C17 H17B 108.6 . .
C18 C17 H17B 108.6 . .
H17A C17 H17B 107.6 . .
N5 C18 C17 113.2(3) . .
N5 C18 Cs1 53.88(15) . .
C17 C18 Cs1 84.25(18) . .
N5 C18 H18A 108.9 . .
C17 C18 H18A 108.9 . .
Cs1 C18 H18A 77.7 . .
N5 C18 H18B 108.9 . .
C17 C18 H18B 108.9 . .
Cs1 C18 H18B 162.3 . .
H18A C18 H18B 107.7 . .
N5 C19 H19A 109.5 . .
N5 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
N5 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
N5 C20 H20A 109.5 . .
N5 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
N5 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
N3 C21 C22 114.7(2) . .
N3 C21 H21A 108.6 . .
C22 C21 H21A 108.6 . .
N3 C21 H21B 108.6 . .
C22 C21 H21B 108.6 . .
H21A C21 H21B 107.6 . .
N6 C22 C21 114.3(3) . .
N6 C22 Cs1 52.53(14) . .
C21 C22 Cs1 86.12(16) . .
N6 C22 H22A 108.7 . .
C21 C22 H22A 108.7 . .
Cs1 C22 H22A 78.1 . .
N6 C22 H22B 108.7 . .
C21 C22 H22B 108.7 . .
Cs1 C22 H22B 160.6 . .
H22A C22 H22B 107.6 . .
N6 C23 H23A 109.5 . .
N6 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
N6 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
N6 C24 Cs1 56.28(15) . .
N6 C24 H24A 109.5 . .
Cs1 C24 H24A 164.9 . .
N6 C24 H24B 109.5 . .
Cs1 C24 H24B 74.2 . .
H24A C24 H24B 109.5 . .
N6 C24 H24C 109.5 . .
Cs1 C24 H24C 82.1 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
C25 C31 H31A 109.5 . .
C25 C31 H31B 109.5 . .
H31A C31 H31B 109.5 . .
C25 C31 H31C 109.5 . .
H31A C31 H31C 109.5 . .
H31B C31 H31C 109.5 . .
C26 C25 C30 120.0 . .
C26 C25 C31 122.1(5) . .
C30 C25 C31 117.8(5) . .
C27 C26 C25 120.0 . .
C27 C26 H26 120.0 . .
C25 C26 H26 120.0 . .
C28 C27 C26 120.0 . .
C28 C27 H27 120.0 . .
C26 C27 H27 120.0 . .
C29 C28 C27 120.0 . .
C29 C28 H28 120.0 . .
C27 C28 H28 120.0 . .
C28 C29 C30 120.0 . .
C28 C29 H29 120.0 . .
C30 C29 H29 120.0 . .
C29 C30 C25 120.0 . .
C29 C30 H30 120.0 . .
C25 C30 H30 120.0 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Cs1 N1 3.129(2) .
Cs1 N4 3.159(2) .
Cs1 N6 3.173(2) .
Cs1 N5 3.223(3) .
Cs1 N3 3.291(2) .
Cs1 C9 3.535(3) 2_665
Cs1 C24 3.741(3) .
Cs1 C15 3.800(4) .
Cs1 C5 3.803(3) .
Cs1 C16 3.821(4) .
Cs1 C22 3.849(3) .
Cs1 C18 3.859(3) .
Cs2 N2 3.149(2) .
Cs2 N2 3.168(2) 2_665
Cs2 N1 3.241(2) .
Cs2 C9 3.601(3) 2_665
Cs2 C2 3.687(4) 2_565
Cs2 C3 3.831(3) .
Cs2 C7 3.847(3) .
Cs2 C6 3.868(3) .
Cs2 Si4 3.9445(8) .
Cs2 Si4 3.9629(7) 2_665
Cs2 Si1 3.9794(8) .
Cs2 Si3 4.0022(7) 2_665
Si1 N1 1.662(2) .
Si1 C1 1.878(3) .
Si1 C2 1.879(4) .
Si1 C3 1.881(4) .
N1 Si2 1.665(2) .
C1 H1A 0.9800 .
C1 H1B 0.9800 .
C1 H1C 0.9800 .
Si2 C6 1.888(3) .
Si2 C5 1.891(4) .
Si2 C4 1.895(3) .
N2 Si3 1.663(2) .
N2 Si4 1.666(2) .
N2 Cs2 3.168(2) 2_665
C2 Cs2 3.687(4) 2_565
C2 H2A 0.9800 .
C2 H2B 0.9800 .
C2 H2C 0.9800 .
Si3 C8 1.873(3) .
Si3 C9 1.884(3) .
Si3 C7 1.890(3) .
Si3 Cs2 4.0021(7) 2_665
N3 C21 1.462(4) .
N3 C17 1.476(4) .
N3 C13 1.479(4) .
C3 H3A 0.9800 .
C3 H3B 0.9800 .
C3 H3C 0.9800 .
Si4 C12 1.881(3) .
Si4 C10 1.887(3) .
Si4 C11 1.889(3) .
Si4 Cs2 3.9629(7) 2_665
N4 C15 1.436(4) .
N4 C16 1.461(5) .
N4 C14 1.461(4) .
C4 H4A 0.9800 .
C4 H4B 0.9800 .
C4 H4C 0.9800 .
N5 C20 1.448(4) .
N5 C18 1.454(4) .
N5 C19 1.469(4) .
C5 H5A 0.9800 .
C5 H5B 0.9800 .
C5 H5C 0.9800 .
N6 C23 1.427(5) .
N6 C24 1.457(4) .
N6 C22 1.485(5) .
C6 H6A 0.9800 .
C6 H6B 0.9800 .
C6 H6C 0.9800 .
C7 H7A 0.9800 .
C7 H7B 0.9800 .
C7 H7C 0.9800 .
C8 H8A 0.9800 .
C8 H8B 0.9800 .
C8 H8C 0.9800 .
C9 Cs1 3.535(3) 2_665
C9 Cs2 3.601(3) 2_665
C9 H9A 0.9800 .
C9 H9B 0.9800 .
C9 H9C 0.9800 .
C10 H10A 0.9800 .
C10 H10B 0.9800 .
C10 H10C 0.9800 .
C11 H11A 0.9800 .
C11 H11B 0.9800 .
C11 H11C 0.9800 .
C12 H12A 0.9800 .
C12 H12B 0.9800 .
C12 H12C 0.9800 .
C13 C14 1.488(5) .
C13 H13A 0.9900 .
C13 H13B 0.9900 .
C14 H00A 0.9900 .
C14 H00B 0.9900 .
C15 H15A 0.9800 .
C15 H15B 0.9800 .
C15 H15C 0.9800 .
C16 H16A 0.9800 .
C16 H16B 0.9800 .
C16 H16C 0.9800 .
C17 C18 1.518(4) .
C17 H17A 0.9900 .
C17 H17B 0.9900 .
C18 H18A 0.9900 .
C18 H18B 0.9900 .
C19 H19A 0.9800 .
C19 H19B 0.9800 .
C19 H19C 0.9800 .
C20 H20A 0.9800 .
C20 H20B 0.9800 .
C20 H20C 0.9800 .
C21 C22 1.493(5) .
C21 H21A 0.9900 .
C21 H21B 0.9900 .
C22 H22A 0.9900 .
C22 H22B 0.9900 .
C23 H23A 0.9800 .
C23 H23B 0.9800 .
C23 H23C 0.9800 .
C24 H24A 0.9800 .
C24 H24B 0.9800 .
C24 H24C 0.9800 .
C31 C25 1.453(6) .
C31 H31A 0.9800 .
C31 H31B 0.9800 .
C31 H31C 0.9800 .
C25 C26 1.3900 .
C25 C30 1.3900 .
C26 C27 1.3900 .
C26 H26 0.9500 .
C27 C28 1.3900 .
C27 H27 0.9500 .
C28 C29 1.3900 .
C28 H28 0.9500 .
C29 C30 1.3900 .
C29 H29 0.9500 .
C30 H30 0.9500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C1 Si1 N1 Si2 -77.8(2) . .
C2 Si1 N1 Si2 44.6(3) . .
C3 Si1 N1 Si2 163.53(18) . .
Cs1 Si1 N1 Si2 -127.83(19) . .
Cs2 Si1 N1 Si2 121.77(18) . .
C1 Si1 N1 Cs1 50.0(2) . .
C2 Si1 N1 Cs1 172.42(18) . .
C3 Si1 N1 Cs1 -68.64(15) . .
Cs2 Si1 N1 Cs1 -110.40(9) . .
C1 Si1 N1 Cs2 160.39(19) . .
C2 Si1 N1 Cs2 -77.18(19) . .
C3 Si1 N1 Cs2 41.76(16) . .
Cs1 Si1 N1 Cs2 110.40(9) . .
Si1 N1 Si2 C6 -83.4(2) . .
Cs1 N1 Si2 C6 151.34(14) . .
Cs2 N1 Si2 C6 37.89(16) . .
Si1 N1 Si2 C5 157.20(17) . .
Cs1 N1 Si2 C5 31.92(15) . .
Cs2 N1 Si2 C5 -81.53(13) . .
Si1 N1 Si2 C4 37.7(3) . .
Cs1 N1 Si2 C4 -87.59(19) . .
Cs2 N1 Si2 C4 158.96(18) . .
Si1 N1 Si2 Cs1 125.28(19) . .
Cs2 N1 Si2 Cs1 -113.44(10) . .
Si1 N1 Si2 Cs2 -121.27(19) . .
Cs1 N1 Si2 Cs2 113.44(10) . .
N1 Si1 C2 Cs2 156.2(4) . 2_565
C1 Si1 C2 Cs2 -76.5(5) . 2_565
C3 Si1 C2 Cs2 32.7(5) . 2_565
Cs1 Si1 C2 Cs2 -178.27(17) . 2_565
Cs2 Si1 C2 Cs2 105.3(4) . 2_565
Si4 N2 Si3 C8 3.2(3) . .
Cs2 N2 Si3 C8 139.43(17) . .
Cs2 N2 Si3 C8 -126.22(17) 2_665 .
Si4 N2 Si3 C9 124.46(18) . .
Cs2 N2 Si3 C9 -99.30(13) . .
Cs2 N2 Si3 C9 -4.95(15) 2_665 .
Si4 N2 Si3 C7 -119.64(19) . .
Cs2 N2 Si3 C7 16.60(16) . .
Cs2 N2 Si3 C7 110.95(14) 2_665 .
Si4 N2 Si3 Cs2 129.4(2) . 2_665
Cs2 N2 Si3 Cs2 -94.35(9) . 2_665
Si4 N2 Si3 Cs2 -136.2(2) . .
Cs2 N2 Si3 Cs2 94.35(9) 2_665 .
N1 Si1 C3 Cs2 -33.69(12) . .
C1 Si1 C3 Cs2 -158.23(14) . .
C2 Si1 C3 Cs2 91.81(14) . .
Cs1 Si1 C3 Cs2 -81.04(4) . .
Si3 N2 Si4 C12 -68.2(2) . .
Cs2 N2 Si4 C12 153.43(13) . .
Cs2 N2 Si4 C12 61.88(15) 2_665 .
Si3 N2 Si4 C10 173.58(17) . .
Cs2 N2 Si4 C10 35.22(14) . .
Cs2 N2 Si4 C10 -56.34(14) 2_665 .
Si3 N2 Si4 C11 54.4(2) . .
Cs2 N2 Si4 C11 -83.91(14) . .
Cs2 N2 Si4 C11 -175.47(13) 2_665 .
Si3 N2 Si4 Cs2 138.4(2) . .
Cs2 N2 Si4 Cs2 -91.56(8) 2_665 .
Si3 N2 Si4 Cs2 -130.1(2) . 2_665
Cs2 N2 Si4 Cs2 91.56(8) . 2_665
N1 Si2 C5 Cs1 -24.46(11) . .
C6 Si2 C5 Cs1 -148.67(11) . .
C4 Si2 C5 Cs1 101.80(13) . .
Cs2 Si2 C5 Cs1 -75.51(4) . .
N1 Si2 C6 Cs2 -30.28(12) . .
C5 Si2 C6 Cs2 92.00(12) . .
C4 Si2 C6 Cs2 -157.97(16) . .
Cs1 Si2 C6 Cs2 14.6(3) . .
N2 Si3 C7 Cs2 -12.57(12) . .
C8 Si3 C7 Cs2 -141.40(13) . .
C9 Si3 C7 Cs2 109.26(11) . .
Cs2 Si3 C7 Cs2 42.12(10) 2_665 .
N2 Si3 C9 Cs2 4.15(12) . 2_665
C8 Si3 C9 Cs2 132.09(14) . 2_665
C7 Si3 C9 Cs2 -117.84(12) . 2_665
Cs2 Si3 C9 Cs2 -45.27(8) . 2_665
C21 N3 C13 C14 -76.9(3) . .
C17 N3 C13 C14 163.5(2) . .
Cs1 N3 C13 C14 45.1(3) . .
C15 N4 C14 C13 -73.1(4) . .
C16 N4 C14 C13 164.9(3) . .
Cs1 N4 C14 C13 46.9(3) . .
N3 C13 C14 N4 -65.7(4) . .
C16 N4 C15 Cs1 -113.3(3) . .
C14 N4 C15 Cs1 125.2(3) . .
C15 N4 C16 Cs1 113.1(3) . .
C14 N4 C16 Cs1 -123.4(2) . .
C21 N3 C17 C18 159.8(3) . .
C13 N3 C17 C18 -79.5(3) . .
Cs1 N3 C17 C18 40.3(3) . .
C20 N5 C18 C17 -76.1(3) . .
C19 N5 C18 C17 165.5(3) . .
Cs1 N5 C18 C17 63.4(3) . .
C20 N5 C18 Cs1 -139.5(3) . .
C19 N5 C18 Cs1 102.2(3) . .
N3 C17 C18 N5 -78.3(4) . .
N3 C17 C18 Cs1 -31.8(2) . .
C17 N3 C21 C22 -83.7(3) . .
C13 N3 C21 C22 156.7(3) . .
Cs1 N3 C21 C22 34.5(3) . .
C23 N6 C22 C21 -67.9(4) . .
C24 N6 C22 C21 171.6(3) . .
Cs1 N6 C22 C21 63.9(3) . .
C23 N6 C22 Cs1 -131.7(3) . .
C24 N6 C22 Cs1 107.8(3) . .
N3 C21 C22 N6 -72.7(4) . .
N3 C21 C22 Cs1 -27.1(3) . .
C23 N6 C24 Cs1 126.6(3) . .
C22 N6 C24 Cs1 -110.8(2) . .
C30 C25 C26 C27 0.0 . .
C31 C25 C26 C27 176.3(8) . .
C25 C26 C27 C28 0.0 . .
C26 C27 C28 C29 0.0 . .
C27 C28 C29 C30 0.0 . .
C28 C29 C30 C25 0.0 . .
C26 C25 C30 C29 0.0 . .
C31 C25 C30 C29 -176.4(7) . .
