Crystallography Open Database

Information card for entry 4349381

Preview

Coordinates	4349381.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C22 H51 Co Ga N2 Si4
Calculated formula	C22 H51 Co Ga N2 Si4
SMILES	[Co](N([Si](C)(C)C)[Si](C)(C)C)(N([Si](C)(C)C)[Si](C)(C)C)[Ga]1234[c]5([c]1([c]2([c]3([c]45C)C)C)C)C
Title of publication	Diverse Reactivity of ECp* (E = Al, Ga) toward Low-Coordinate Transition Metal Amides [TM(N(SiMe<sub>3</sub>)<sub>2</sub>)<sub>2</sub>] (TM = Fe, Co, Zn): Insertion, Cp* Transfer, and Orthometalation.
Authors of publication	Weßing, Jana; Göbel, Christoph; Weber, Birgit; Gemel, Christian; Fischer, Roland A.
Journal of publication	Inorganic chemistry
Year of publication	2017
Journal volume	56
Journal issue	6
Pages of publication	3517 - 3525
a	16.8275 ± 0.0002 Å
b	21.4098 ± 0.0002 Å
c	18.8062 ± 0.0002 Å
α	90°
β	106.876 ± 0.001°
γ	90°
Cell volume	6483.59 ± 0.12 Å³
Cell temperature	108 K
Ambient diffraction temperature	108 K
Number of distinct elements	6
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/c 1
Hall space group symbol	-P 2ybc
Residual factor for all reflections	0.044
Residual factor for significantly intense reflections	0.0338
Weighted residual factors for significantly intense reflections	0.0828
Weighted residual factors for all reflections included in the refinement	0.088
Goodness-of-fit parameter for all reflections included in the refinement	1.023
Diffraction radiation probe	x-ray
Diffraction radiation wavelength	1.54178 Å
Diffraction radiation type	CuKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
233911 (current)	2019-11-23	cif/ Adding structures of 4349380, 4349381, 4349382, 4349383, 4349384 via cif-deposit CGI script.	4349381.cif