Crystallography Open Database

Information card for entry 4349383

Preview

Coordinates	4349383.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C32 H66 Al2 N2 Si4 Zn
Calculated formula	C32 H66 Al2 N2 Si4 Zn
SMILES	c1(c([c]2([Al]([Zn][Al]3([c]4(c(c(c([c]34C)C)C)C)C)N([Si](C)(C)C)[Si](C)(C)C)(N([Si](C)(C)C)[Si](C)(C)C)[c]2(c1C)C)C)C)C
Title of publication	Diverse Reactivity of ECp* (E = Al, Ga) toward Low-Coordinate Transition Metal Amides [TM(N(SiMe<sub>3</sub>)<sub>2</sub>)<sub>2</sub>] (TM = Fe, Co, Zn): Insertion, Cp* Transfer, and Orthometalation.
Authors of publication	Weßing, Jana; Göbel, Christoph; Weber, Birgit; Gemel, Christian; Fischer, Roland A.
Journal of publication	Inorganic chemistry
Year of publication	2017
Journal volume	56
Journal issue	6
Pages of publication	3517 - 3525
a	8.5944 ± 0.0005 Å
b	9.6962 ± 0.0005 Å
c	14.0679 ± 0.0009 Å
α	93.962 ± 0.005°
β	106.393 ± 0.005°
γ	112.654 ± 0.005°
Cell volume	1016.75 ± 0.12 Å³
Cell temperature	113 K
Ambient diffraction temperature	113 K
Number of distinct elements	6
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0457
Residual factor for significantly intense reflections	0.0354
Weighted residual factors for significantly intense reflections	0.0898
Weighted residual factors for all reflections included in the refinement	0.097
Goodness-of-fit parameter for all reflections included in the refinement	1.044
Diffraction radiation probe	x-ray
Diffraction radiation wavelength	1.54184 Å
Diffraction radiation type	CuKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
233911 (current)	2019-11-23	cif/ Adding structures of 4349380, 4349381, 4349382, 4349383, 4349384 via cif-deposit CGI script.	4349383.cif