Crystallography Open Database

Information card for entry 4349384

Preview

Coordinates	4349384.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C32 H70 Al2 Co N2 Si4
Calculated formula	C32 H70 Al2 Co N2 Si4
SMILES	C[Si](C)(C)N([Al]123([c]4([c]1(c(c(c4C)C)C)C)C)[H][Co]143([H]2)[H][Al]24([c]3([c]2(c(c(c3C)C)C)C)C)([H]1)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C
Title of publication	Diverse Reactivity of ECp* (E = Al, Ga) toward Low-Coordinate Transition Metal Amides [TM(N(SiMe<sub>3</sub>)<sub>2</sub>)<sub>2</sub>] (TM = Fe, Co, Zn): Insertion, Cp* Transfer, and Orthometalation.
Authors of publication	Weßing, Jana; Göbel, Christoph; Weber, Birgit; Gemel, Christian; Fischer, Roland A.
Journal of publication	Inorganic chemistry
Year of publication	2017
Journal volume	56
Journal issue	6
Pages of publication	3517 - 3525
a	8.6323 ± 0.0003 Å
b	9.6301 ± 0.0003 Å
c	13.9237 ± 0.0005 Å
α	94.067 ± 0.002°
β	106.104 ± 0.001°
γ	113.135 ± 0.001°
Cell volume	1001.2 ± 0.06 Å³
Cell temperature	100 K
Ambient diffraction temperature	100 K
Number of distinct elements	6
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0517
Residual factor for significantly intense reflections	0.0344
Weighted residual factors for significantly intense reflections	0.0722
Weighted residual factors for all reflections included in the refinement	0.0776
Goodness-of-fit parameter for all reflections included in the refinement	1.035
Diffraction radiation probe	x-ray
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
233911 (current)	2019-11-23	cif/ Adding structures of 4349380, 4349381, 4349382, 4349383, 4349384 via cif-deposit CGI script.	4349384.cif