Crystallography Open Database

Information card for entry 4514024

Preview

Coordinates	4514024.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C94 H118 Ge2 N2 O Si2
Calculated formula	C94 H118 Ge2 N2 O Si2
Title of publication	Efficient Reduction of Carbon Dioxide to Methanol Equivalents Catalyzed by Two-Coordinate Amido‒Germanium(II) and −Tin(II) Hydride Complexes
Authors of publication	Hadlington, Terrance J.; Kefalidis, Christos E.; Maron, Laurent; Jones, Cameron
Journal of publication	ACS Catalysis
Year of publication	2017
Journal volume	7
Journal issue	3
Pages of publication	1853
a	24.283 ± 0.005 Å
b	21.152 ± 0.004 Å
c	17.759 ± 0.004 Å
α	90°
β	114.38 ± 0.03°
γ	90°
Cell volume	8308 ± 4 Å³
Cell temperature	100 ± 2 K
Ambient diffraction temperature	100 ± 2 K
Number of distinct elements	6
Space group number	15
Hermann-Mauguin space group symbol	C 1 2/c 1
Hall space group symbol	-C 2yc
Residual factor for all reflections	0.086
Residual factor for significantly intense reflections	0.0695
Weighted residual factors for significantly intense reflections	0.196
Weighted residual factors for all reflections included in the refinement	0.2107
Goodness-of-fit parameter for all reflections included in the refinement	1.054
Diffraction radiation wavelength	0.7108 Å
Diffraction radiation type	Synchrotron
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
193399 (current)	2017-03-04	cif/ Updating files of 4514024, 4514025, 4514026 Original log message: Adding full bibliography for 4514024--4514026.cif.	4514024.cif
191946	2017-02-10	cif/ Adding structures of 4514024 via cif-deposit CGI script.	4514024.cif