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Information card for entry 7000590
Preview
| Coordinates | 7000590.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C45 H45 P2 Rh |
|---|---|
| Calculated formula | C45 H45 P2 Rh |
| SMILES | [Rh]1234([P](c5ccccc5)(c5ccccc5)C#CC(C)(C)C)([P](c5ccccc5)(c5ccccc5)C#CC(C)(C)C)[cH]5[cH]1[cH]2[c]13[c]45cccc1 |
| Title of publication | Synthesis and structure of indenyl rhodium(I) complexes containing unsaturated phosphines: catalyst precursors for alkene hydroboration |
| Authors of publication | Garon, Christian N.; McIsaac, Daniel I.; Vogels, Christopher M.; Decken, Andreas; Williams, Ian D.; Kleeberg, Christian; Marder, Todd B.; Westcott, Stephen A. |
| Journal of publication | Dalton Transactions |
| Year of publication | 2009 |
| Journal issue | 9 |
| Pages of publication | 1624 - 1631 |
| a | 11.06 ± 0.0006 Å |
| b | 11.8418 ± 0.0007 Å |
| c | 17.1608 ± 0.001 Å |
| α | 108.854 ± 0.001° |
| β | 92.464 ± 0.001° |
| γ | 112.489 ± 0.001° |
| Cell volume | 1929.21 ± 0.19 Å3 |
| Cell temperature | 198 ± 1 K |
| Ambient diffraction temperature | 198 ± 1 K |
| Number of distinct elements | 4 |
| Space group number | 2 |
| Hermann-Mauguin space group symbol | P -1 |
| Hall space group symbol | -P 1 |
| Residual factor for all reflections | 0.0402 |
| Residual factor for significantly intense reflections | 0.0332 |
| Weighted residual factors for significantly intense reflections | 0.0877 |
| Weighted residual factors for all reflections included in the refinement | 0.0922 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.091 |
| Diffraction radiation probe | x-ray |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 176432 (current) | 2016-02-14 | cif/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries. |
7000590.cif |
| 120443 | 2014-07-15 | Adding 17924 DOIs guessed from source file names. | 7000590.cif |
| 35909 | 2012-02-26 | cif/7/: reorganising range 7 into a prefix-directory tree. | 7000590.cif |
| 1143 | 2010-05-03 | cif/7/ Adding CIFs from Dalton-Trans-2009/ deposition. |
7000590.cif |
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