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Information card for entry 7003010
Preview
| Coordinates | 7003010.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C50 H70 N2 O2 P2 Ru2 |
|---|---|
| Calculated formula | C50 H70 N2 O2 P2 Ru2 |
| SMILES | [Ru]12345([N]#[N][Ru]6789%10([P](C%11=C(O6)Cc6c%11cccc6)(C(C)C)C(C)C)[c]6([c]%10([c]9([c]8([c]76C)C)C)C)C)([P](C6=C(O1)Cc1c6cccc1)(C(C)C)C(C)C)[c]1([c]5([c]4([c]3([c]21C)C)C)C)C |
| Title of publication | Exploring the reactivity of a coordinatively unsaturated Cp*Ru(kappa(2)-P,O) complex with small molecule substrates: application in E-H bond activation (E = H, B, and Si). |
| Authors of publication | Rankin, Matthew A; Hesp, Kevin D; Schatte, Gabriele; McDonald, Robert; Stradiotto, Mark |
| Journal of publication | Dalton transactions (Cambridge, England : 2003) |
| Year of publication | 2009 |
| Journal issue | 24 |
| Pages of publication | 4756 - 4765 |
| a | 17.4049 ± 0.0011 Å |
| b | 13.5276 ± 0.0008 Å |
| c | 23.149 ± 0.0019 Å |
| α | 90° |
| β | 118.873 ± 0.003° |
| γ | 90° |
| Cell volume | 4772.8 ± 0.6 Å3 |
| Cell temperature | 173 ± 2 K |
| Ambient diffraction temperature | 173 ± 2 K |
| Number of distinct elements | 6 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/c 1 |
| Hall space group symbol | -P 2ybc |
| Residual factor for all reflections | 0.1098 |
| Residual factor for significantly intense reflections | 0.0557 |
| Weighted residual factors for significantly intense reflections | 0.0936 |
| Weighted residual factors for all reflections included in the refinement | 0.1136 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.023 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 179734 (current) | 2016-03-25 | cif/7/00/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/00/30. |
7003010.cif |
| 120677 | 2014-07-23 | cod/ (saulius@koala.ibt.lt) Adding 4906 DOIs identified by CodBot. |
7003010.cif |
| 35909 | 2012-02-26 | cif/7/: reorganising range 7 into a prefix-directory tree. | 7003010.cif |
| 1167 | 2010-05-13 | cif/ Adding data from the rest of 2009 RSC journals, Inorg-Chem-2008 and Chem-Comm-2010_18-19. |
7003010.cif |
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