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Information card for entry 7004854
Preview
| Coordinates | 7004854.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Common name | trans(Cl,Cl)cis(P,P)-dichlorobis((3- aminopropyl)dimethylphosphine)cobalt(iii) hexafluorophosphate |
|---|---|
| Chemical name | trans(Cl,Cl)cis(P,P)-dichlorobis((3-aminopropyl)dimethylphosphine)cobalt(III) hexafluorophosphate |
| Formula | C10 H28 Cl2 Co F6 N2 P3 |
| Calculated formula | C10 H28 Cl2 Co F6 N2 P3 |
| SMILES | [Co]12(Cl)(Cl)([P](C)(C)CCC[NH2]1)[P](C)(C)CCC[NH2]2.[P](F)(F)(F)(F)(F)[F-] |
| Title of publication | Preparation and characterization of mixed-ligand cobalt(III) complexes containing (3-aminopropyl)dimethylphosphine (pdmp). Conformation of the six-membered pdmp chelate ring. |
| Authors of publication | Suzuki, Takayoshi; Fujiiwara, Katsuhiro; Takagi, Hideo D.; Kashiwabara, Kazuo |
| Journal of publication | Dalton transactions (Cambridge, England : 2003) |
| Year of publication | 2007 |
| Journal issue | 3 |
| Pages of publication | 308 - 319 |
| a | 8.178 ± 0.011 Å |
| b | 10.073 ± 0.013 Å |
| c | 12.811 ± 0.016 Å |
| α | 105.659 ± 0.012° |
| β | 94.09 ± 0.02° |
| γ | 98.15 ± 0.02° |
| Cell volume | 999 ± 2 Å3 |
| Cell temperature | 193 ± 2 K |
| Ambient diffraction temperature | 193 ± 2 K |
| Number of distinct elements | 7 |
| Space group number | 2 |
| Hermann-Mauguin space group symbol | P -1 |
| Hall space group symbol | -P 1 |
| Residual factor for all reflections | 0.059 |
| Residual factor for significantly intense reflections | 0.0421 |
| Weighted residual factors for significantly intense reflections | 0.0908 |
| Weighted residual factors for all reflections included in the refinement | 0.0985 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.078 |
| Diffraction radiation wavelength | 0.7107 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 179752 (current) | 2016-03-25 | cif/7/00/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/00/48. |
7004854.cif |
| 120443 | 2014-07-15 | Adding 17924 DOIs guessed from source file names. | 7004854.cif |
| 35909 | 2012-02-26 | cif/7/: reorganising range 7 into a prefix-directory tree. | 7004854.cif |
| 1186 | 2010-06-03 | Adding CIFs from Chem-Comm-2010_20-22/ and Dalton-Trans-2007/ processing. | 7004854.cif |
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