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Information card for entry 7004857
Preview
| Coordinates | 7004857.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Common name | Bis(N,N-dimethyldithiocarbamato)((3- aminopropyl)dimethylphosphine)cobalt(iii) Hexafluorophosphate |
|---|---|
| Chemical name | Bis(N,N-dimethyldithiocarbamato)((3-aminopropyl)dimethylphosphine)cobalt(III) Hexafluorophosphate |
| Formula | C11 H26 Co F6 N3 P2 S4 |
| Calculated formula | C11 H26 Co F6 N3 P2 S4 |
| SMILES | [Co]123([S]=C(S1)N(C)C)(SC(=[S]2)N(C)C)[P](C)(C)CCC[NH2]3.[P](F)(F)(F)(F)(F)[F-] |
| Title of publication | Preparation and characterization of mixed-ligand cobalt(III) complexes containing (3-aminopropyl)dimethylphosphine (pdmp). Conformation of the six-membered pdmp chelate ring. |
| Authors of publication | Suzuki, Takayoshi; Fujiiwara, Katsuhiro; Takagi, Hideo D.; Kashiwabara, Kazuo |
| Journal of publication | Dalton transactions (Cambridge, England : 2003) |
| Year of publication | 2007 |
| Journal issue | 3 |
| Pages of publication | 308 - 319 |
| a | 10.924 ± 0.005 Å |
| b | 15.016 ± 0.005 Å |
| c | 13.904 ± 0.005 Å |
| α | 90° |
| β | 90.129 ± 0.017° |
| γ | 90° |
| Cell volume | 2280.7 ± 1.5 Å3 |
| Cell temperature | 296 ± 2 K |
| Ambient diffraction temperature | 296 ± 2 K |
| Number of distinct elements | 7 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/a 1 |
| Hall space group symbol | -P 2yab |
| Residual factor for all reflections | 0.0397 |
| Residual factor for significantly intense reflections | 0.0361 |
| Weighted residual factors for significantly intense reflections | 0.1116 |
| Weighted residual factors for all reflections included in the refinement | 0.1148 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.091 |
| Diffraction radiation wavelength | 0.71075 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 179752 (current) | 2016-03-25 | cif/7/00/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/00/48. |
7004857.cif |
| 120443 | 2014-07-15 | Adding 17924 DOIs guessed from source file names. | 7004857.cif |
| 35909 | 2012-02-26 | cif/7/: reorganising range 7 into a prefix-directory tree. | 7004857.cif |
| 1186 | 2010-06-03 | Adding CIFs from Chem-Comm-2010_20-22/ and Dalton-Trans-2007/ processing. | 7004857.cif |
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