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Information card for entry 7008798
Preview
| Coordinates | 7008798.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C24 H60 Cl2 Li2 O8 Si4 Zn2 |
|---|---|
| Calculated formula | C24 H60 Cl2 Li2 O8 Si4 Zn2 |
| SMILES | C[O]12[Zn]([C@H]([Si](C)(C)C)[Si](C)(OC)[O](C)[Li]23[O]2CCCC2)([Cl]2)[O](C)([Zn]1([C@@H]([Si](C)(C)C)[Si](C)(OC)[O]1C)[Cl]3)[Li]21[O]1CCCC1 |
| Title of publication | The coordination chemistry of the C1-symmetric bis(silyl)methyl ligand [CH(SiMe3){SiMe(OMe)2}]- revisited: Li/M- (M = Zn, Tl, Ce), Li4- or Ce2-methoxy-bridged alkyls. |
| Authors of publication | Hitchcock, Peter B.; Huang, Qigu; Lappert, Michael F.; Zhou, Meisu |
| Journal of publication | Dalton transactions (Cambridge, England : 2003) |
| Year of publication | 2005 |
| Journal issue | 18 |
| Pages of publication | 2988 - 2993 |
| a | 9.6026 ± 0.0003 Å |
| b | 15.4505 ± 0.0003 Å |
| c | 13.7502 ± 0.0004 Å |
| α | 90° |
| β | 94.667 ± 0.001° |
| γ | 90° |
| Cell volume | 2033.28 ± 0.1 Å3 |
| Cell temperature | 173 ± 2 K |
| Ambient diffraction temperature | 173 ± 2 K |
| Number of distinct elements | 7 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/n 1 |
| Hall space group symbol | -P 2yn |
| Residual factor for all reflections | 0.0366 |
| Residual factor for significantly intense reflections | 0.0305 |
| Weighted residual factors for significantly intense reflections | 0.0749 |
| Weighted residual factors for all reflections included in the refinement | 0.0781 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.026 |
| Diffraction radiation probe | x-ray |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 179791 (current) | 2016-03-25 | cif/7/00/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/00/87. |
7008798.cif |
| 120443 | 2014-07-15 | Adding 17924 DOIs guessed from source file names. | 7008798.cif |
| 35909 | 2012-02-26 | cif/7/: reorganising range 7 into a prefix-directory tree. | 7008798.cif |
| 1504 | 2010-09-08 | cif/7/ Adding data extracted from RSC 2005 and 2006 year publications. |
7008798.cif |
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Users of the data should acknowledge the original authors of the
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