Crystallography Open Database

Information card for entry 7009192

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Coordinates	7009192.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C32 H53 Ge N3 Se2 Si2
Calculated formula	C32 H53 Ge N3 Se2 Si2
SMILES	[Ge]([Se]c1ccccc1)([Se]c1ccccc1)(N(C1CCCCC1)/C(=N/C1CCCCC1)C)N([Si](C)(C)C)[Si](C)(C)C
Title of publication	Oxidative addition to M(II) (M = Ge, Sn) amidinate complexes: routes to group 14 chalcogenolates with hypervalent coordination environments
Authors of publication	Foley, Stephen R.; Yap, Glenn P. A.; Richeson, Darrin S.
Journal of publication	Journal of the Chemical Society, Dalton Transactions
Year of publication	2000
Journal issue	10
Pages of publication	1663
a	10.828 ± 0.001 Å
b	25.14 ± 0.003 Å
c	26.674 ± 0.003 Å
α	90°
β	98.304 ± 0.002°
γ	90°
Cell volume	7185 ± 1.4 Å³
Cell temperature	203 ± 2 K
Ambient diffraction temperature	203 ± 2 K
Number of distinct elements	6
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/c 1
Hall space group symbol	-P 2ybc
Residual factor for all reflections	0.0785
Residual factor for significantly intense reflections	0.0366
Weighted residual factors for significantly intense reflections	0.061
Weighted residual factors for all reflections included in the refinement	0.0641
Goodness-of-fit parameter for all reflections included in the refinement	1.006
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
179795 (current)	2016-03-25	cif/7/00/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/00/91.	7009192.cif
120443	2014-07-15	Adding 17924 DOIs guessed from source file names.	7009192.cif
35909	2012-02-26	cif/7/: reorganising range 7 into a prefix-directory tree.	7009192.cif
5312	2011-01-03	cif/ Adding files, updated with the 'cif_fix_enum' program and the cif_core.dic dictionary. The enumerator values were fixed, mostly incorrect case, but also some values that had extra underscores, dashes or spaces. Unfortunately, 22 had non-ASCII characters with the 8-th bit set, and these got incorrectly interpreted as latin1 characters and converted to their UTF8 equivalents by Perl. To fix the structures, however, they need to be redeposited from the original files with the new CIFParser/cif_filter version.	7009192.cif
3896	2010-12-08	cif/7/ Adding CIFs with data from Dalton-Trans-2004-2000/.	7009192.cif