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Information card for entry 7010491
Preview
| Coordinates | 7010491.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Common name | nov1699 |
|---|---|
| Formula | C24 H44 Li2 N4 Si2 |
| Calculated formula | C24 H44 Li2 N4 Si2 |
| SMILES | [Li]1[N]([Si](C)(C)C)(c2ccccc2)[Li]([N]1([Si](C)(C)C)c1ccccc1)[N](C)(C)CC[N](C)(C)[Li]1[N]([Si](C)(C)C)(c2ccccc2)[Li]([N]1([Si](C)(C)C)c1ccccc1)[N](C)(C)CCN(C)(C) |
| Title of publication | Synthesis and structures of lithium N-trimethylsilyl- and -neopentyl-anilides and their Et2O and tmen adducts; crystal structures of [(Li{μ-N(Ph)R}-trans)2(μ-tmen)]\ιnfty (R = SiMe3 1 or CH2But 2) and [Li{μ-N(Ph)CH2But}(OEt2)]2 † |
| Authors of publication | Bezombes, Jean Philippe; Hitchcock, Peter B.; Lappert, Michael F.; Merle, Philippe G. |
| Journal of publication | Journal of the Chemical Society, Dalton Transactions |
| Year of publication | 2001 |
| Journal issue | 6 |
| Pages of publication | 816 |
| a | 9.259 ± 0.001 Å |
| b | 18.225 ± 0.002 Å |
| c | 9.3338 ± 0.0007 Å |
| α | 90° |
| β | 118.617 ± 0.006° |
| γ | 90° |
| Cell volume | 1382.6 ± 0.2 Å3 |
| Cell temperature | 173 ± 2 K |
| Ambient diffraction temperature | 173 ± 2 K |
| Number of distinct elements | 5 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/c 1 |
| Hall space group symbol | -P 2ybc |
| Residual factor for all reflections | 0.1079 |
| Residual factor for significantly intense reflections | 0.0815 |
| Weighted residual factors for significantly intense reflections | 0.189 |
| Weighted residual factors for all reflections included in the refinement | 0.2 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.186 |
| Diffraction radiation probe | x-ray |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 213973 (current) | 2019-03-05 | cod/ Removed potentially copyrighted or irrelevant data items from 1289 entries. |
7010491.cif |
| 211196 | 2018-09-27 | cod/ Removing the _chemical_name_common and _chemical_name_systematic data items that contained the summary chemical formula instead of the chemical name from 6249 entries. |
7010491.cif |
| 179808 | 2016-03-25 | cif/7/01/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/01/04. |
7010491.cif |
| 120443 | 2014-07-15 | Adding 17924 DOIs guessed from source file names. | 7010491.cif |
| 35909 | 2012-02-26 | cif/7/: reorganising range 7 into a prefix-directory tree. | 7010491.cif |
| 3896 | 2010-12-08 | cif/7/ Adding CIFs with data from Dalton-Trans-2004-2000/. |
7010491.cif |
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