Crystallography Open Database

Information card for entry 7013884

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Structure parameters

Formula	C25 H52 O P3 Rh
Calculated formula	C25 H52 O P3 Rh
SMILES	[Rh]([P](CC)(CC)CC)([P](CC)(CC)CC)([P](CC)(CC)CC)Oc1ccc(cc1)C
Title of publication	Cationic Rh complexes with novel spiro tetraarylpentaborate anions prepared from arylboronic acids and aryloxorhodium complexes.
Authors of publication	Nishihara, Yasushi; Nara, Kyoko; Nishide, Yasuhiro; Osakada, Kohtaro
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2004
Journal issue	9
Pages of publication	1366 - 1375
a	18.949 ± 0.006 Å
b	18.153 ± 0.004 Å
c	17.641 ± 0.003 Å
α	90°
β	90°
γ	90°
Cell volume	6068 ± 3 Å³
Cell temperature	23 K
Number of distinct elements	5
Space group number	61
Hermann-Mauguin space group symbol	P b c a
Hall space group symbol	-P 2ac 2ab
Residual factor for significantly intense reflections	0.038
Weighted residual factors for all reflections included in the refinement	0.051
Goodness-of-fit parameter for all reflections included in the refinement	1.001
Diffraction radiation wavelength	0.7107 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
301847 (current)	2025-08-21	Add cross-references to PubChem compounds in COD range 7/01/ Each referenced PubChem compound corresponds to the full crystal structure.	7013884.cif
176453	2016-02-16	cif/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in range 7.	7013884.cif
120443	2014-07-15	Adding 17924 DOIs guessed from source file names.	7013884.cif
35909	2012-02-26	cif/7/: reorganising range 7 into a prefix-directory tree.	7013884.cif
3896	2010-12-08	cif/7/ Adding CIFs with data from Dalton-Trans-2004-2000/.	7013884.cif