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Information card for entry 7021700
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| Coordinates | 7021700.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Chemical name | Osmium(0)(eta4-1,5-cyclooctadiene)(eta6-1,3,5,7-cyclooctatetraene) |
|---|---|
| Formula | C16 H20 Os |
| Calculated formula | C16 H20 Os |
| SMILES | [Os]12345678([CH]9=[CH]1CC[CH]2=[CH]3CC9)[CH]1C=C[CH]8=[CH]7[CH]6=[CH]5[CH]4=1 |
| Title of publication | Narrowly dispersed silica supported osmium nanoparticles prepared by an organometallic approach: H2 and CO adsorption stoichiometry and hydrogenolysis catalytic activity. |
| Authors of publication | Low, Jia En; Foelske-Schmitz, Annette; Krumeich, Frank; Wörle, Michael; Baudouin, David; Rascón, Fernando; Copéret, Christophe |
| Journal of publication | Dalton transactions (Cambridge, England : 2003) |
| Year of publication | 2013 |
| Journal volume | 42 |
| Journal issue | 35 |
| Pages of publication | 12620 - 12625 |
| a | 12.293 ± 0.002 Å |
| b | 8.9556 ± 0.0016 Å |
| c | 13.02 ± 0.002 Å |
| α | 90° |
| β | 115.75 ± 0.004° |
| γ | 90° |
| Cell volume | 1291 ± 0.4 Å3 |
| Cell temperature | 233 ± 2 K |
| Ambient diffraction temperature | 233.15 K |
| Number of distinct elements | 3 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/c 1 |
| Hall space group symbol | -P 2ybc |
| Residual factor for all reflections | 0.0354 |
| Residual factor for significantly intense reflections | 0.0195 |
| Weighted residual factors for significantly intense reflections | 0.0385 |
| Weighted residual factors for all reflections included in the refinement | 0.0424 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.031 |
| Diffraction radiation probe | x-ray |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Diffraction radiation X-ray symbol | K-L~3~ |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 179922 (current) | 2016-03-25 | cif/7/02/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/02/17. |
7021700.cif |
| 87660 | 2013-08-27 | cif/ Adding structures of 7021700 via cif-deposit CGI script. |
7021700.cif |
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Users of the data should acknowledge the original authors of the
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